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- Publisher Website: 10.1002/anie.200250519
- Scopus: eid_2-s2.0-0038215539
- PMID: 12730973
- WOS: WOS:000182901700007
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Article: The molecular structure of [Os3Rh4(µ3-η1:η1:η1-C6H5CH3)(CO)13]: A face-capping bonding mode for arenes in organometallic clusters
Title | The molecular structure of [Os3Rh4(µ3-η1:η1:η1-C6H5CH3)(CO)13]: A face-capping bonding mode for arenes in organometallic clusters |
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Authors | |
Keywords | Chemical bonds Molecular structure Rhodium Toluene Osmium compounds |
Issue Date | 2003 |
Publisher | Wiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home |
Citation | Angewandte Chemie (International Edition), 2003, v. 42 n. 17, p. 1935-1937 How to Cite? |
Abstract | Rhodium gets a new flat cap: A novel face-capping mode of toluene on the title {Os3Rh4} cluster is observed (see structure; Os blue, Rh green, C gray, O red, H white). The cluster is obtained from the reaction of [Os3Rh(μ-H)3(CO)12] with toluene in the presence of an excess amount of 4-vinylphenol under reflux for 2 h. The new cluster has relatively short metal–metal bonds and an electron count of only 92, which is four electrons less than expected. |
Persistent Identifier | http://hdl.handle.net/10722/70192 |
ISSN | 2023 Impact Factor: 16.1 2023 SCImago Journal Rankings: 5.300 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Lau, JPK | en_HK |
dc.contributor.author | Lin, ZY | en_HK |
dc.contributor.author | Wong, WT | en_HK |
dc.date.accessioned | 2010-09-06T06:20:35Z | - |
dc.date.available | 2010-09-06T06:20:35Z | - |
dc.date.issued | 2003 | en_HK |
dc.identifier.citation | Angewandte Chemie (International Edition), 2003, v. 42 n. 17, p. 1935-1937 | en_HK |
dc.identifier.issn | 1433-7851 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/70192 | - |
dc.description.abstract | Rhodium gets a new flat cap: A novel face-capping mode of toluene on the title {Os3Rh4} cluster is observed (see structure; Os blue, Rh green, C gray, O red, H white). The cluster is obtained from the reaction of [Os3Rh(μ-H)3(CO)12] with toluene in the presence of an excess amount of 4-vinylphenol under reflux for 2 h. The new cluster has relatively short metal–metal bonds and an electron count of only 92, which is four electrons less than expected. | - |
dc.language | eng | en_HK |
dc.publisher | Wiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home | en_HK |
dc.relation.ispartof | Angewandte Chemie (International Edition) | en_HK |
dc.subject | Chemical bonds | - |
dc.subject | Molecular structure | - |
dc.subject | Rhodium | - |
dc.subject | Toluene | - |
dc.subject | Osmium compounds | - |
dc.title | The molecular structure of [Os3Rh4(µ3-η1:η1:η1-C6H5CH3)(CO)13]: A face-capping bonding mode for arenes in organometallic clusters | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1433-7851&volume=42&spage=1935&epage=1937&date=2003&atitle=The+molecular+structure+of+[Os3Rh4(m3-h1:h1:h1-C6H5CH3)(CO)13]:+A+face-capping+bonding+mode+for+arenes+in+organometallic+clusters | en_HK |
dc.identifier.email | Wong, WT: wtwong@hku.hk | en_HK |
dc.identifier.authority | Wong, WT=rp00811 | en_HK |
dc.identifier.doi | 10.1002/anie.200250519 | - |
dc.identifier.pmid | 12730973 | - |
dc.identifier.scopus | eid_2-s2.0-0038215539 | - |
dc.identifier.hkuros | 82689 | en_HK |
dc.identifier.volume | 42 | - |
dc.identifier.issue | 17 | - |
dc.identifier.spage | 1935 | - |
dc.identifier.epage | 1937 | - |
dc.identifier.isi | WOS:000182901700007 | - |
dc.publisher.place | Germany | - |
dc.identifier.issnl | 1433-7851 | - |