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Article: The molecular structure of [Os3Rh4(µ3-η1:η1:η1-C6H5CH3)(CO)13]: A face-capping bonding mode for arenes in organometallic clusters

TitleThe molecular structure of [Os3Rh4(µ3-η1:η1:η1-C6H5CH3)(CO)13]: A face-capping bonding mode for arenes in organometallic clusters
Authors
KeywordsChemical bonds
Molecular structure
Rhodium
Toluene
Osmium compounds
Issue Date2003
PublisherWiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home
Citation
Angewandte Chemie (International Edition), 2003, v. 42 n. 17, p. 1935-1937 How to Cite?
AbstractRhodium gets a new flat cap: A novel face-capping mode of toluene on the title {Os3Rh4} cluster is observed (see structure; Os blue, Rh green, C gray, O red, H white). The cluster is obtained from the reaction of [Os3Rh(μ-H)3(CO)12] with toluene in the presence of an excess amount of 4-vinylphenol under reflux for 2 h. The new cluster has relatively short metal–metal bonds and an electron count of only 92, which is four electrons less than expected.
Persistent Identifierhttp://hdl.handle.net/10722/70192
ISSN
2015 Impact Factor: 11.709
2015 SCImago Journal Rankings: 6.229
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorLau, JPKen_HK
dc.contributor.authorLin, ZYen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:20:35Z-
dc.date.available2010-09-06T06:20:35Z-
dc.date.issued2003en_HK
dc.identifier.citationAngewandte Chemie (International Edition), 2003, v. 42 n. 17, p. 1935-1937en_HK
dc.identifier.issn1433-7851en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70192-
dc.description.abstractRhodium gets a new flat cap: A novel face-capping mode of toluene on the title {Os3Rh4} cluster is observed (see structure; Os blue, Rh green, C gray, O red, H white). The cluster is obtained from the reaction of [Os3Rh(μ-H)3(CO)12] with toluene in the presence of an excess amount of 4-vinylphenol under reflux for 2 h. The new cluster has relatively short metal–metal bonds and an electron count of only 92, which is four electrons less than expected.-
dc.languageengen_HK
dc.publisherWiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/homeen_HK
dc.relation.ispartofAngewandte Chemie (International Edition)en_HK
dc.subjectChemical bonds-
dc.subjectMolecular structure-
dc.subjectRhodium-
dc.subjectToluene-
dc.subjectOsmium compounds-
dc.titleThe molecular structure of [Os3Rh4(µ3-η1:η1:η1-C6H5CH3)(CO)13]: A face-capping bonding mode for arenes in organometallic clustersen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1433-7851&volume=42&spage=1935&epage=1937&date=2003&atitle=The+molecular+structure+of+[Os3Rh4(m3-h1:h1:h1-C6H5CH3)(CO)13]:+A+face-capping+bonding+mode+for+arenes+in+organometallic+clustersen_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1002/anie.200250519-
dc.identifier.pmid12730973-
dc.identifier.scopuseid_2-s2.0-0038215539-
dc.identifier.hkuros82689en_HK
dc.identifier.volume42-
dc.identifier.issue17-
dc.identifier.spage1935-
dc.identifier.epage1937-
dc.identifier.isiWOS:000182901700007-
dc.publisher.placeGermany-

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