File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1016/S0022-328X(02)02063-6
- Scopus: eid_2-s2.0-0037451013
- WOS: WOS:000181779200003
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: Luminescent properties of carbon-rich starburst gold(I) acetylide complexes. Crystal structure of [TEE][Au(PCy3)]4 ([TEE]H4 = tetraethynylethene)
Title | Luminescent properties of carbon-rich starburst gold(I) acetylide complexes. Crystal structure of [TEE][Au(PCy3)]4 ([TEE]H4 = tetraethynylethene) |
---|---|
Authors | |
Keywords | Acetylide Cross-conjugation Fluorescence Gold Phosphorescence |
Issue Date | 2003 |
Publisher | Elsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem |
Citation | Journal Of Organometallic Chemistry, 2003, v. 670 n. 1-2, p. 11-16 How to Cite? |
Abstract | Two carbon-rich starburst gold(I) acetylide complexes [TEE][Au(PCy 3)] 4 (3, [TEE]H 4 = tetraethynylethene) and [TEB][Au(PCy 3)] 3 (6, [TEB]H 3 = 1,3,5-triethynylbenzene) were prepared and their UV-vis absorption, emission and excitation spectra have been recorded. In fluid CH 2Cl 2 solutions, 3 exhibits prompt 1(ππ*) fluorescence with λ 0-0 and λ max at 413 and 428 nm, respectively, while 6 displays 3(ππ*) phosphorescence with λ 0-0 and λ max at 446 and 479 nm, respectively. The crystal structure of 3· CH 2Cl 2 has been determined. © 2002 Elsevier Science B.V. All rights reserved. |
Persistent Identifier | http://hdl.handle.net/10722/70136 |
ISSN | 2023 Impact Factor: 2.1 2023 SCImago Journal Rankings: 0.359 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lu, W | en_HK |
dc.contributor.author | Zhu, N | en_HK |
dc.contributor.author | Che, CM | en_HK |
dc.date.accessioned | 2010-09-06T06:20:03Z | - |
dc.date.available | 2010-09-06T06:20:03Z | - |
dc.date.issued | 2003 | en_HK |
dc.identifier.citation | Journal Of Organometallic Chemistry, 2003, v. 670 n. 1-2, p. 11-16 | en_HK |
dc.identifier.issn | 0022-328X | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/70136 | - |
dc.description.abstract | Two carbon-rich starburst gold(I) acetylide complexes [TEE][Au(PCy 3)] 4 (3, [TEE]H 4 = tetraethynylethene) and [TEB][Au(PCy 3)] 3 (6, [TEB]H 3 = 1,3,5-triethynylbenzene) were prepared and their UV-vis absorption, emission and excitation spectra have been recorded. In fluid CH 2Cl 2 solutions, 3 exhibits prompt 1(ππ*) fluorescence with λ 0-0 and λ max at 413 and 428 nm, respectively, while 6 displays 3(ππ*) phosphorescence with λ 0-0 and λ max at 446 and 479 nm, respectively. The crystal structure of 3· CH 2Cl 2 has been determined. © 2002 Elsevier Science B.V. All rights reserved. | en_HK |
dc.language | eng | en_HK |
dc.publisher | Elsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem | en_HK |
dc.relation.ispartof | Journal of Organometallic Chemistry | en_HK |
dc.subject | Acetylide | en_HK |
dc.subject | Cross-conjugation | en_HK |
dc.subject | Fluorescence | en_HK |
dc.subject | Gold | en_HK |
dc.subject | Phosphorescence | en_HK |
dc.title | Luminescent properties of carbon-rich starburst gold(I) acetylide complexes. Crystal structure of [TEE][Au(PCy3)]4 ([TEE]H4 = tetraethynylethene) | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-328X&volume=670&spage=11&epage=16&date=2003&atitle=Luminescent+properties+of+carbon-rich+starburst+gold(I)+acetylide+complexes.++Crystal+structure+of+[TEE][Au(PCY3)]4+([TEE]H4+=+tetraethynylethene) | en_HK |
dc.identifier.email | Zhu, N: nzhu@hkucc.hku.hk | en_HK |
dc.identifier.email | Che, CM: cmche@hku.hk | en_HK |
dc.identifier.authority | Zhu, N=rp00845 | en_HK |
dc.identifier.authority | Che, CM=rp00670 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/S0022-328X(02)02063-6 | en_HK |
dc.identifier.scopus | eid_2-s2.0-0037451013 | en_HK |
dc.identifier.hkuros | 83827 | en_HK |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0037451013&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 670 | en_HK |
dc.identifier.issue | 1-2 | en_HK |
dc.identifier.spage | 11 | en_HK |
dc.identifier.epage | 16 | en_HK |
dc.identifier.isi | WOS:000181779200003 | - |
dc.publisher.place | Switzerland | en_HK |
dc.identifier.scopusauthorid | Lu, W=55277832700 | en_HK |
dc.identifier.scopusauthorid | Zhu, N=7201449530 | en_HK |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_HK |
dc.identifier.issnl | 0022-328X | - |