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Article: Luminescent properties of carbon-rich starburst gold(I) acetylide complexes. Crystal structure of [TEE][Au(PCy3)]4 ([TEE]H4 = tetraethynylethene)

TitleLuminescent properties of carbon-rich starburst gold(I) acetylide complexes. Crystal structure of [TEE][Au(PCy3)]4 ([TEE]H4 = tetraethynylethene)
Authors
KeywordsAcetylide
Cross-conjugation
Fluorescence
Gold
Phosphorescence
Issue Date2003
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem
Citation
Journal Of Organometallic Chemistry, 2003, v. 670 n. 1-2, p. 11-16 How to Cite?
AbstractTwo carbon-rich starburst gold(I) acetylide complexes [TEE][Au(PCy 3)] 4 (3, [TEE]H 4 = tetraethynylethene) and [TEB][Au(PCy 3)] 3 (6, [TEB]H 3 = 1,3,5-triethynylbenzene) were prepared and their UV-vis absorption, emission and excitation spectra have been recorded. In fluid CH 2Cl 2 solutions, 3 exhibits prompt 1(ππ*) fluorescence with λ 0-0 and λ max at 413 and 428 nm, respectively, while 6 displays 3(ππ*) phosphorescence with λ 0-0 and λ max at 446 and 479 nm, respectively. The crystal structure of 3· CH 2Cl 2 has been determined. © 2002 Elsevier Science B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/70136
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLu, Wen_HK
dc.contributor.authorZhu, Nen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2010-09-06T06:20:03Z-
dc.date.available2010-09-06T06:20:03Z-
dc.date.issued2003en_HK
dc.identifier.citationJournal Of Organometallic Chemistry, 2003, v. 670 n. 1-2, p. 11-16en_HK
dc.identifier.issn0022-328Xen_HK
dc.identifier.urihttp://hdl.handle.net/10722/70136-
dc.description.abstractTwo carbon-rich starburst gold(I) acetylide complexes [TEE][Au(PCy 3)] 4 (3, [TEE]H 4 = tetraethynylethene) and [TEB][Au(PCy 3)] 3 (6, [TEB]H 3 = 1,3,5-triethynylbenzene) were prepared and their UV-vis absorption, emission and excitation spectra have been recorded. In fluid CH 2Cl 2 solutions, 3 exhibits prompt 1(ππ*) fluorescence with λ 0-0 and λ max at 413 and 428 nm, respectively, while 6 displays 3(ππ*) phosphorescence with λ 0-0 and λ max at 446 and 479 nm, respectively. The crystal structure of 3· CH 2Cl 2 has been determined. © 2002 Elsevier Science B.V. All rights reserved.en_HK
dc.languageengen_HK
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchemen_HK
dc.relation.ispartofJournal of Organometallic Chemistryen_HK
dc.subjectAcetylideen_HK
dc.subjectCross-conjugationen_HK
dc.subjectFluorescenceen_HK
dc.subjectGolden_HK
dc.subjectPhosphorescenceen_HK
dc.titleLuminescent properties of carbon-rich starburst gold(I) acetylide complexes. Crystal structure of [TEE][Au(PCy3)]4 ([TEE]H4 = tetraethynylethene)en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-328X&volume=670&spage=11&epage=16&date=2003&atitle=Luminescent+properties+of+carbon-rich+starburst+gold(I)+acetylide+complexes.++Crystal+structure+of+[TEE][Au(PCY3)]4+([TEE]H4+=+tetraethynylethene)en_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.emailChe, CM: cmche@hku.hken_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0022-328X(02)02063-6en_HK
dc.identifier.scopuseid_2-s2.0-0037451013en_HK
dc.identifier.hkuros83827en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0037451013&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume670en_HK
dc.identifier.issue1-2en_HK
dc.identifier.spage11en_HK
dc.identifier.epage16en_HK
dc.identifier.isiWOS:000181779200003-
dc.publisher.placeSwitzerlanden_HK
dc.identifier.scopusauthoridLu, W=55277832700en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK

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