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Article: Examination of the A-band short-time photodissociation dynamics of the equatorial conformer of iodocyclohexane

TitleExamination of the A-band short-time photodissociation dynamics of the equatorial conformer of iodocyclohexane
Authors
Issue Date1998
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett
Citation
Chemical Physics Letters, 1998, v. 296 n. 1-2, p. 173-182 How to Cite?
AbstractAn A-band resonance Raman spectrum of iodocyclohexane in acetonitrile solution was obtained and a resonance Raman intensity analysis was done to investigate the short-time photodissociation dynamics of equatorial iodocyclohexane. The C-I bond length changes suggest that the cyclohexyl radical receives substantial internal excitation. Comparison of equatorial iodocyclohexane with the A-band short-time photodissociation of several non-cyclic iodoalkanes indicates that the geometry of the C-I bond relative to the plane of the α-, β-, and γ-carbon atoms of the cyclohexyl group is important in determining the degree of internal excitation of the cyclohexy photofragment.
Persistent Identifierhttp://hdl.handle.net/10722/70105
ISSN
2015 Impact Factor: 1.86
2015 SCImago Journal Rankings: 0.757
References

 

DC FieldValueLanguage
dc.contributor.authorZheng, Xen_HK
dc.contributor.authorPhillips, DLen_HK
dc.date.accessioned2010-09-06T06:19:46Z-
dc.date.available2010-09-06T06:19:46Z-
dc.date.issued1998en_HK
dc.identifier.citationChemical Physics Letters, 1998, v. 296 n. 1-2, p. 173-182en_HK
dc.identifier.issn0009-2614en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70105-
dc.description.abstractAn A-band resonance Raman spectrum of iodocyclohexane in acetonitrile solution was obtained and a resonance Raman intensity analysis was done to investigate the short-time photodissociation dynamics of equatorial iodocyclohexane. The C-I bond length changes suggest that the cyclohexyl radical receives substantial internal excitation. Comparison of equatorial iodocyclohexane with the A-band short-time photodissociation of several non-cyclic iodoalkanes indicates that the geometry of the C-I bond relative to the plane of the α-, β-, and γ-carbon atoms of the cyclohexyl group is important in determining the degree of internal excitation of the cyclohexy photofragment.en_HK
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cpletten_HK
dc.relation.ispartofChemical Physics Lettersen_HK
dc.rightsChemical Physics Letters. Copyright © Elsevier BV.en_HK
dc.titleExamination of the A-band short-time photodissociation dynamics of the equatorial conformer of iodocyclohexaneen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0009-2614&volume=296&spage=173&epage=182&date=1998&atitle=Examination+of+the+A-band+short-time+photodissociation+dynamics+of+the+equatorial+conformer+of+iodocyclohexaneen_HK
dc.identifier.emailPhillips, DL:phillips@hku.hken_HK
dc.identifier.authorityPhillips, DL=rp00770en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.scopuseid_2-s2.0-0040098176en_HK
dc.identifier.hkuros40162en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0040098176&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume296en_HK
dc.identifier.issue1-2en_HK
dc.identifier.spage173en_HK
dc.identifier.epage182en_HK
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridZheng, X=7404090253en_HK
dc.identifier.scopusauthoridPhillips, DL=7404519365en_HK

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