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Article: The fourth and fifth virial coefficients of an additive hard sphere mixture from the Henderson-Chan formulae

TitleThe fourth and fifth virial coefficients of an additive hard sphere mixture from the Henderson-Chan formulae
Authors
Issue Date1998
PublisherTaylor & Francis Ltd. The Journal's web site is located at http://www.tandf.co.uk/journals/titles/00268976.asp
Citation
Molecular Physics, 1998, v. 94 n. 2, p. 253-255 How to Cite?
AbstractThe fourth and fifth virial coefficients of an additive hard sphere mixture, predicted from our recent formulae, are compared with the values calculated by Saija et al. and Enciso et al. Our formulae are supported by recent simulation and theoretical results. The Saija et al. and Enciso et al. values are calculated from what are purported to be exact formulae but differ drastically. In particular, Saija et al. claim that the fifth virial coefficient can be negative whereas Enciso et al. question this result. Our estimates agree closely with the results of Enciso et al. and the estimates of Boublik and Mansouri et al. This does not mean that the Boublik and Mansoori et al. equation of state is accurate under all circumstances, as our formulae lead to rather different results, including demixing, when the large spheres are present in small concentrations.
Persistent Identifierhttp://hdl.handle.net/10722/70102
ISSN
2015 Impact Factor: 1.837
2015 SCImago Journal Rankings: 0.781
References

 

DC FieldValueLanguage
dc.contributor.authorHenderson, Den_HK
dc.contributor.authorChan, KYen_HK
dc.date.accessioned2010-09-06T06:19:44Z-
dc.date.available2010-09-06T06:19:44Z-
dc.date.issued1998en_HK
dc.identifier.citationMolecular Physics, 1998, v. 94 n. 2, p. 253-255en_HK
dc.identifier.issn0026-8976en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70102-
dc.description.abstractThe fourth and fifth virial coefficients of an additive hard sphere mixture, predicted from our recent formulae, are compared with the values calculated by Saija et al. and Enciso et al. Our formulae are supported by recent simulation and theoretical results. The Saija et al. and Enciso et al. values are calculated from what are purported to be exact formulae but differ drastically. In particular, Saija et al. claim that the fifth virial coefficient can be negative whereas Enciso et al. question this result. Our estimates agree closely with the results of Enciso et al. and the estimates of Boublik and Mansouri et al. This does not mean that the Boublik and Mansoori et al. equation of state is accurate under all circumstances, as our formulae lead to rather different results, including demixing, when the large spheres are present in small concentrations.en_HK
dc.languageengen_HK
dc.publisherTaylor & Francis Ltd. The Journal's web site is located at http://www.tandf.co.uk/journals/titles/00268976.aspen_HK
dc.relation.ispartofMolecular Physicsen_HK
dc.titleThe fourth and fifth virial coefficients of an additive hard sphere mixture from the Henderson-Chan formulaeen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0026-8976&volume=94&issue=2&spage=253&epage=255&date=1998&atitle=The+fourth+and+fifth+virial+coefficients+of+an+additive+hard+sphere+mixture+from+the+Henderson+-+Chan+formulaeen_HK
dc.identifier.emailChan, KY:hrsccky@hku.hken_HK
dc.identifier.authorityChan, KY=rp00662en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.scopuseid_2-s2.0-0343295395en_HK
dc.identifier.hkuros32300en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0343295395&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume94en_HK
dc.identifier.issue2en_HK
dc.identifier.spage253en_HK
dc.identifier.epage255en_HK
dc.publisher.placeUnited Kingdomen_HK
dc.identifier.scopusauthoridHenderson, D=7402988756en_HK
dc.identifier.scopusauthoridChan, KY=7406034142en_HK

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