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Article: Synthesis, Characterization, X-ray Structural Analysis and Study of Oxidative Properties of Propyltriphenylphosphonium Bromochromate

TitleSynthesis, Characterization, X-ray Structural Analysis and Study of Oxidative Properties of Propyltriphenylphosphonium Bromochromate
Authors
Ghammamy, SBaghy, MRWong, WTMehrani, KMaleki, S
Issue Date2007
PublisherSpringer Verlag Dordrecht. The Journal's web site is located at http://springerlink.metapress.com/openurl.asp?genre=journal&issn=0340-4285
Citation
Transition Metal Chemistry , 2007, v. 32 , p. 257-261 How to Cite?
DOI: http://dx.doi.org/10.1007/s11243-006-0162-6
AbstractThe complex of propyltriphenylphosphonium bromochromate(VI), PrPh3P[CrO3Br] is easily synthesized in nearly quantitative yield using a direct reaction of chromium(VI) oxide and propyltriphenylphosphonium bromide. This compound is a versatile reagent for the efficient and selective oxidation of organic substrates, in particular for alcohols to their corresponding aldehydes or ketones, under mild conditions. This compound was characterized by IR, UV/Visible, 13C-n.m.r. and 1H-n.m.r. techniques. It crystallized in the monoclinic form and its crystal and molecular structure have been determined by X-ray crystallography.
Persistent Identifierhttp://hdl.handle.net/10722/70074
ISSN
0340-4285
2023 Impact Factor: 1.6
2023 SCImago Journal Rankings: 0.229
ISI Accession Number ID
WOS:000244890600020

 

DC FieldValueLanguage
dc.contributor.authorGhammamy, Sen_HK
dc.contributor.authorBaghy, MRen_HK
dc.contributor.authorWong, WTen_HK
dc.contributor.authorMehrani, Ken_HK
dc.contributor.authorMaleki, Sen_HK
dc.date.accessioned2010-09-06T06:19:28Z-
dc.date.available2010-09-06T06:19:28Z-
dc.date.issued2007en_HK
dc.identifier.citationTransition Metal Chemistry , 2007, v. 32 , p. 257-261en_HK
dc.identifier.issn0340-4285en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70074-
dc.description.abstractThe complex of propyltriphenylphosphonium bromochromate(VI), PrPh3P[CrO3Br] is easily synthesized in nearly quantitative yield using a direct reaction of chromium(VI) oxide and propyltriphenylphosphonium bromide. This compound is a versatile reagent for the efficient and selective oxidation of organic substrates, in particular for alcohols to their corresponding aldehydes or ketones, under mild conditions. This compound was characterized by IR, UV/Visible, 13C-n.m.r. and 1H-n.m.r. techniques. It crystallized in the monoclinic form and its crystal and molecular structure have been determined by X-ray crystallography.-
dc.languageengen_HK
dc.publisherSpringer Verlag Dordrecht. The Journal's web site is located at http://springerlink.metapress.com/openurl.asp?genre=journal&issn=0340-4285en_HK
dc.relation.ispartofTransition Metal Chemistryen_HK
dc.titleSynthesis, Characterization, X-ray Structural Analysis and Study of Oxidative Properties of Propyltriphenylphosphonium Bromochromateen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0340-4285&volume=32 &spage=257&epage=261&date=2007&atitle=Synthesis,+Characterization,+X-ray+Structural+Analysis+and+Study+of+Oxidative+Properties+of+Propyltriphenylphosphonium+Bromochromate+en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1007/s11243-006-0162-6-
dc.identifier.scopuseid_2-s2.0-33947171143-
dc.identifier.hkuros127614en_HK
dc.identifier.isiWOS:000244890600020-
dc.identifier.citeulike1225681-
dc.identifier.issnl0340-4285-

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