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Article: Synthesis, characterisation and co-polymerisation of ruthenium 1,2-naphthoquinone-1-oxime complexes containing 4-vinylpyridine ligands

TitleSynthesis, characterisation and co-polymerisation of ruthenium 1,2-naphthoquinone-1-oxime complexes containing 4-vinylpyridine ligands
Authors
Keywords1,2-Naphthoquinone-1-oxime complexes
Copolymerisation
Ruthenium complexes
Issue Date2001
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ica
Citation
Inorganica Chimica Acta, 2001, v. 312 n. 1-2, p. 231-238 How to Cite?
AbstractRuthenium 1,2-naphthoquinone-1-oxime (1-nqoH) complexes cis,cis-[Ru{η 2-N(O)C 10H 6O} 2 (CO)(vpy)] (3) and trans,cis-[Ru{η 2-N(O)C 10H 6 O} 2(CO)(vpy)] (4) were synthesised by substituted decarbonylation reactions of dicarbonyl complexes cis,cis-[Ru{η 2-N(O)C 10H 6 O} 2(CO) 2] (1) and trans,cis-[Ru{η 2-N(O)C 10H 6 O} 2(CO) 2] (2), respectively. In addition, a dipyridine product trans,trans-[Ru{η 2-N(O)C 10H 6 O} 2(vpy) 2] (5) was also obtained in both reaction routes as the result of a ligand rearrangement during the substitution process of the second carbonyl ligand. The molecular structure of 3 was established by X-ray analysis. Co-polymerisation reactions were conducted on 3 with styrene as the co-monomer. The metal-containing moieties maintain the coordination geometry of the starting monomer 3 on the carbon-backbone chain. © 2001 Elsevier Science B.V.
Persistent Identifierhttp://hdl.handle.net/10722/70067
ISSN
2015 Impact Factor: 1.918
2015 SCImago Journal Rankings: 0.584
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLiu, XXen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:19:24Z-
dc.date.available2010-09-06T06:19:24Z-
dc.date.issued2001en_HK
dc.identifier.citationInorganica Chimica Acta, 2001, v. 312 n. 1-2, p. 231-238en_HK
dc.identifier.issn0020-1693en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70067-
dc.description.abstractRuthenium 1,2-naphthoquinone-1-oxime (1-nqoH) complexes cis,cis-[Ru{η 2-N(O)C 10H 6O} 2 (CO)(vpy)] (3) and trans,cis-[Ru{η 2-N(O)C 10H 6 O} 2(CO)(vpy)] (4) were synthesised by substituted decarbonylation reactions of dicarbonyl complexes cis,cis-[Ru{η 2-N(O)C 10H 6 O} 2(CO) 2] (1) and trans,cis-[Ru{η 2-N(O)C 10H 6 O} 2(CO) 2] (2), respectively. In addition, a dipyridine product trans,trans-[Ru{η 2-N(O)C 10H 6 O} 2(vpy) 2] (5) was also obtained in both reaction routes as the result of a ligand rearrangement during the substitution process of the second carbonyl ligand. The molecular structure of 3 was established by X-ray analysis. Co-polymerisation reactions were conducted on 3 with styrene as the co-monomer. The metal-containing moieties maintain the coordination geometry of the starting monomer 3 on the carbon-backbone chain. © 2001 Elsevier Science B.V.en_HK
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/icaen_HK
dc.relation.ispartofInorganica Chimica Actaen_HK
dc.rightsInorganica Chimica Acta. Copyright © Elsevier BV.en_HK
dc.subject1,2-Naphthoquinone-1-oxime complexesen_HK
dc.subjectCopolymerisationen_HK
dc.subjectRuthenium complexesen_HK
dc.titleSynthesis, characterisation and co-polymerisation of ruthenium 1,2-naphthoquinone-1-oxime complexes containing 4-vinylpyridine ligandsen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0020-1693&volume=312&spage=231&epage=238&date=2001&atitle=Synthesis,+characterisation+and+co-polymerisation+of+ruthenium+1,2-naphthoquinone-1-oxime+complexes+containing+4-vinylpyridine+ligandsen_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0020-1693(00)00337-6en_HK
dc.identifier.scopuseid_2-s2.0-0035966449en_HK
dc.identifier.hkuros56704en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0035966449&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume312en_HK
dc.identifier.issue1-2en_HK
dc.identifier.spage231en_HK
dc.identifier.epage238en_HK
dc.identifier.isiWOS:000167092700030-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridLiu, XX=22958433500en_HK
dc.identifier.scopusauthoridWong, WT=7403973084en_HK

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