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Article: Synthesis, characterisation and co-polymerisation of ruthenium 1,2-naphthoquinone-1-oxime complexes containing 4-vinylpyridine ligands
Title | Synthesis, characterisation and co-polymerisation of ruthenium 1,2-naphthoquinone-1-oxime complexes containing 4-vinylpyridine ligands |
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Authors | |
Keywords | 1,2-Naphthoquinone-1-oxime complexes Copolymerisation Ruthenium complexes |
Issue Date | 2001 |
Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ica |
Citation | Inorganica Chimica Acta, 2001, v. 312 n. 1-2, p. 231-238 How to Cite? |
Abstract | Ruthenium 1,2-naphthoquinone-1-oxime (1-nqoH) complexes cis,cis-[Ru{η 2-N(O)C 10H 6O} 2 (CO)(vpy)] (3) and trans,cis-[Ru{η 2-N(O)C 10H 6 O} 2(CO)(vpy)] (4) were synthesised by substituted decarbonylation reactions of dicarbonyl complexes cis,cis-[Ru{η 2-N(O)C 10H 6 O} 2(CO) 2] (1) and trans,cis-[Ru{η 2-N(O)C 10H 6 O} 2(CO) 2] (2), respectively. In addition, a dipyridine product trans,trans-[Ru{η 2-N(O)C 10H 6 O} 2(vpy) 2] (5) was also obtained in both reaction routes as the result of a ligand rearrangement during the substitution process of the second carbonyl ligand. The molecular structure of 3 was established by X-ray analysis. Co-polymerisation reactions were conducted on 3 with styrene as the co-monomer. The metal-containing moieties maintain the coordination geometry of the starting monomer 3 on the carbon-backbone chain. © 2001 Elsevier Science B.V. |
Persistent Identifier | http://hdl.handle.net/10722/70067 |
ISSN | 2023 Impact Factor: 2.7 2023 SCImago Journal Rankings: 0.386 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
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dc.contributor.author | Liu, XX | en_HK |
dc.contributor.author | Wong, WT | en_HK |
dc.date.accessioned | 2010-09-06T06:19:24Z | - |
dc.date.available | 2010-09-06T06:19:24Z | - |
dc.date.issued | 2001 | en_HK |
dc.identifier.citation | Inorganica Chimica Acta, 2001, v. 312 n. 1-2, p. 231-238 | en_HK |
dc.identifier.issn | 0020-1693 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/70067 | - |
dc.description.abstract | Ruthenium 1,2-naphthoquinone-1-oxime (1-nqoH) complexes cis,cis-[Ru{η 2-N(O)C 10H 6O} 2 (CO)(vpy)] (3) and trans,cis-[Ru{η 2-N(O)C 10H 6 O} 2(CO)(vpy)] (4) were synthesised by substituted decarbonylation reactions of dicarbonyl complexes cis,cis-[Ru{η 2-N(O)C 10H 6 O} 2(CO) 2] (1) and trans,cis-[Ru{η 2-N(O)C 10H 6 O} 2(CO) 2] (2), respectively. In addition, a dipyridine product trans,trans-[Ru{η 2-N(O)C 10H 6 O} 2(vpy) 2] (5) was also obtained in both reaction routes as the result of a ligand rearrangement during the substitution process of the second carbonyl ligand. The molecular structure of 3 was established by X-ray analysis. Co-polymerisation reactions were conducted on 3 with styrene as the co-monomer. The metal-containing moieties maintain the coordination geometry of the starting monomer 3 on the carbon-backbone chain. © 2001 Elsevier Science B.V. | en_HK |
dc.language | eng | en_HK |
dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ica | en_HK |
dc.relation.ispartof | Inorganica Chimica Acta | en_HK |
dc.rights | Inorganica Chimica Acta. Copyright © Elsevier BV. | en_HK |
dc.subject | 1,2-Naphthoquinone-1-oxime complexes | en_HK |
dc.subject | Copolymerisation | en_HK |
dc.subject | Ruthenium complexes | en_HK |
dc.title | Synthesis, characterisation and co-polymerisation of ruthenium 1,2-naphthoquinone-1-oxime complexes containing 4-vinylpyridine ligands | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0020-1693&volume=312&spage=231&epage=238&date=2001&atitle=Synthesis,+characterisation+and+co-polymerisation+of+ruthenium+1,2-naphthoquinone-1-oxime+complexes+containing+4-vinylpyridine+ligands | en_HK |
dc.identifier.email | Wong, WT: wtwong@hku.hk | en_HK |
dc.identifier.authority | Wong, WT=rp00811 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/S0020-1693(00)00337-6 | en_HK |
dc.identifier.scopus | eid_2-s2.0-0035966449 | en_HK |
dc.identifier.hkuros | 56704 | en_HK |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0035966449&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 312 | en_HK |
dc.identifier.issue | 1-2 | en_HK |
dc.identifier.spage | 231 | en_HK |
dc.identifier.epage | 238 | en_HK |
dc.identifier.isi | WOS:000167092700030 | - |
dc.publisher.place | Netherlands | en_HK |
dc.identifier.scopusauthorid | Liu, XX=22958433500 | en_HK |
dc.identifier.scopusauthorid | Wong, WT=7403973084 | en_HK |
dc.identifier.issnl | 0020-1693 | - |