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Article: Transient resonance Raman and density functional theory investigation of CH3I -I produced from ultraviolet photolysis of iodomethane in the solution phase

TitleTransient resonance Raman and density functional theory investigation of CH3I -I produced from ultraviolet photolysis of iodomethane in the solution phase
Authors
Issue Date2001
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett
Citation
Chemical Physics Letters, 2001, v. 349 n. 3-4, p. 291-298 How to Cite?
AbstractTransient resonance Raman spectra are reported for the CH3I-I species formed after ultraviolet photolysis of iodomethane in cyclohexane and acetonitrile solvents. The spectra display most of their Raman intensity in the overtone progression of the nominal I-I stretch mode and the C-I stretch fundamental. Density functional theory calculations were done for the CH3I-I species to help better understand its properties. We compare our results for the CH3I-I species to those previously reported for CH2I-I and find that the C-I-I geometry significantly influences the perturbation of the C-I bond and the chemical reactivity of the complex species. © 2001 Elsevier Science B.V.
Persistent Identifierhttp://hdl.handle.net/10722/70044
ISSN
2015 Impact Factor: 1.86
2015 SCImago Journal Rankings: 0.757
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLi, YLen_HK
dc.contributor.authorLee Phillips, Den_HK
dc.date.accessioned2010-09-06T06:19:11Z-
dc.date.available2010-09-06T06:19:11Z-
dc.date.issued2001en_HK
dc.identifier.citationChemical Physics Letters, 2001, v. 349 n. 3-4, p. 291-298en_HK
dc.identifier.issn0009-2614en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70044-
dc.description.abstractTransient resonance Raman spectra are reported for the CH3I-I species formed after ultraviolet photolysis of iodomethane in cyclohexane and acetonitrile solvents. The spectra display most of their Raman intensity in the overtone progression of the nominal I-I stretch mode and the C-I stretch fundamental. Density functional theory calculations were done for the CH3I-I species to help better understand its properties. We compare our results for the CH3I-I species to those previously reported for CH2I-I and find that the C-I-I geometry significantly influences the perturbation of the C-I bond and the chemical reactivity of the complex species. © 2001 Elsevier Science B.V.en_HK
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cpletten_HK
dc.relation.ispartofChemical Physics Lettersen_HK
dc.rightsChemical Physics Letters. Copyright © Elsevier BV.en_HK
dc.titleTransient resonance Raman and density functional theory investigation of CH3I -I produced from ultraviolet photolysis of iodomethane in the solution phaseen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0009-2614&volume=349&spage=291&epage=298&date=2001&atitle=Transient+resonance+Raman+and+density+functional+theory+investigation+of+CH3I-I+produced+from+ultraviolet+photolysis+of+iodomethane+in+the+solution+phaseen_HK
dc.identifier.emailLee Phillips, D:phillips@hku.hken_HK
dc.identifier.authorityLee Phillips, D=rp00770en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0009-2614(01)01197-6en_HK
dc.identifier.scopuseid_2-s2.0-0000661112en_HK
dc.identifier.hkuros73843en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0000661112&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume349en_HK
dc.identifier.issue3-4en_HK
dc.identifier.spage291en_HK
dc.identifier.epage298en_HK
dc.identifier.isiWOS:000172595600020-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridLi, YL=27168456500en_HK
dc.identifier.scopusauthoridLee Phillips, D=7404519365en_HK

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