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Article: Tosylimido complexes of tungsten(VI)

TitleTosylimido complexes of tungsten(VI)
Authors
KeywordsComplexes
Tosylimido
Tungsten(VI)
Issue Date1998
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly
Citation
Polyhedron, 1998, v. 17 n. 4, p. 457-461 How to Cite?
AbstractTreatment of W(CO)6 with N,N-dichloro-p-toluenesulfonamide affords [W(NTs)2Cl2]x 1, which reacts with bipy (2,2′-bipyridine) to give the adduct W(NTs)2Cl2(bipy) 2. The average W - N(imido), W - Cl and W - N (bipy) distances are 1.782, 2.352 and 2.284 Å, respectively. Reaction of [W(NTs)2Cl2]n with NaTp [Tp = hydrido(trispyrazolyl)borate] gives TpW(NTs)2Cl 4. These tungsten(VI) tosylimido complexes undergo imido transfer reactions with tertiary phosphine to give W(IV) and the N-tosyl phosphinimine. © 1998 Elsevier Science Ltd. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/70040
ISSN
2015 Impact Factor: 2.108
2015 SCImago Journal Rankings: 0.592
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLeung, WHen_HK
dc.contributor.authorWu, MCen_HK
dc.contributor.authorChim, JLCen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:19:09Z-
dc.date.available2010-09-06T06:19:09Z-
dc.date.issued1998en_HK
dc.identifier.citationPolyhedron, 1998, v. 17 n. 4, p. 457-461en_HK
dc.identifier.issn0277-5387en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70040-
dc.description.abstractTreatment of W(CO)6 with N,N-dichloro-p-toluenesulfonamide affords [W(NTs)2Cl2]x 1, which reacts with bipy (2,2′-bipyridine) to give the adduct W(NTs)2Cl2(bipy) 2. The average W - N(imido), W - Cl and W - N (bipy) distances are 1.782, 2.352 and 2.284 Å, respectively. Reaction of [W(NTs)2Cl2]n with NaTp [Tp = hydrido(trispyrazolyl)borate] gives TpW(NTs)2Cl 4. These tungsten(VI) tosylimido complexes undergo imido transfer reactions with tertiary phosphine to give W(IV) and the N-tosyl phosphinimine. © 1998 Elsevier Science Ltd. All rights reserved.en_HK
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/polyen_HK
dc.relation.ispartofPolyhedronen_HK
dc.rightsPolyhedron. Copyright © Elsevier BV.en_HK
dc.subjectComplexesen_HK
dc.subjectTosylimidoen_HK
dc.subjectTungsten(VI)en_HK
dc.titleTosylimido complexes of tungsten(VI)en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0277-5387&volume=17&issue=4&spage=457&epage=461&date=1998&atitle=Tosylimido+complexes+of+tungsten(VI)en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0277-5387(97)00365-3-
dc.identifier.scopuseid_2-s2.0-0038144483en_HK
dc.identifier.hkuros32559en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0038144483&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume17en_HK
dc.identifier.issue4en_HK
dc.identifier.spage457en_HK
dc.identifier.epage461en_HK
dc.identifier.isiWOS:000072113100009-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridLeung, WH=7201504510en_HK
dc.identifier.scopusauthoridWu, MC=7405595282en_HK
dc.identifier.scopusauthoridChim, JLC=6602609380en_HK
dc.identifier.scopusauthoridWong, WT=7403973084en_HK

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