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Article: Enantioselective epoxidation of trans-disubstituted alkenes by D2-symmetric chiral dioxoruthenium(VI) porphyrins

TitleEnantioselective epoxidation of trans-disubstituted alkenes by D2-symmetric chiral dioxoruthenium(VI) porphyrins
Authors
Issue Date1999
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Chemical Communications, 1999 n. 5, p. 409-410 How to Cite?
AbstractA series of D2-symmetric chiral trans-dioxoruthenium(VI) porphyrins can effect enantioselective epoxidation of trans-β-methylstyrene in up to 70% ee, and 76% ee is attained for the oxidation of cinnamyl chloride; the facial selection for the trans-alkenes epoxidation is explained by a 'head-on approach' model.
Persistent Identifierhttp://hdl.handle.net/10722/70030
ISSN
2015 Impact Factor: 6.567
2015 SCImago Journal Rankings: 2.771
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorZhang, Ren_HK
dc.contributor.authorYu, WYen_HK
dc.contributor.authorLai, TSen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2010-09-06T06:19:03Z-
dc.date.available2010-09-06T06:19:03Z-
dc.date.issued1999en_HK
dc.identifier.citationChemical Communications, 1999 n. 5, p. 409-410en_HK
dc.identifier.issn1359-7345en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70030-
dc.description.abstractA series of D2-symmetric chiral trans-dioxoruthenium(VI) porphyrins can effect enantioselective epoxidation of trans-β-methylstyrene in up to 70% ee, and 76% ee is attained for the oxidation of cinnamyl chloride; the facial selection for the trans-alkenes epoxidation is explained by a 'head-on approach' model.en_HK
dc.languageengen_HK
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_HK
dc.relation.ispartofChemical Communicationsen_HK
dc.titleEnantioselective epoxidation of trans-disubstituted alkenes by D2-symmetric chiral dioxoruthenium(VI) porphyrinsen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1359-7345&volume=&spage=409&epage=410&date=1999&atitle=Enantioselective+epoxidation+of+trans-disubstituted+alkenes+by+D2-symmetric+chiral+dioxoruthenium(VI)+porphyrinsen_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/A808776H-
dc.identifier.scopuseid_2-s2.0-0033531451en_HK
dc.identifier.hkuros40280en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0033531451&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.issue5en_HK
dc.identifier.spage409en_HK
dc.identifier.epage410en_HK
dc.identifier.isiWOS:000079097200005-
dc.publisher.placeUnited Kingdomen_HK
dc.identifier.scopusauthoridZhang, R=7404865969en_HK
dc.identifier.scopusauthoridYu, WY=7403913673en_HK
dc.identifier.scopusauthoridLai, TS=7202203490en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK

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