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Article: Synthesis and structural characterization of a triosmium carbonyl cluster containing a 9-anthracenecarbonitrile ligands derived from 9-anthraldehyde oxime

TitleSynthesis and structural characterization of a triosmium carbonyl cluster containing a 9-anthracenecarbonitrile ligands derived from 9-anthraldehyde oxime
Authors
KeywordsTriosmium carbonyl cluster
Oxime ligand
9-Anthraldehyde oxime
X-ray crystallography
Issue Date2003
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/inoche
Citation
Inorganic Chemistry Communications, 2003, v. 6, p. 713-717 How to Cite?
AbstractTreatment of [Os3(CO)11(MeCN)] with 1 equivalent of 9-anthraldehyde oxime in refluxing chloroform afforded a new triosmium cluster [Os3(CO)11(C14H9CN)] 1 in moderate yield. Dehydration of oxime and the formation of metal-bound nitrile were observed. Crystal structure analysis revealed that cluster 1 consists of a triangular metal skeleton, with the anthracenecarbonitrile ligand terminally bonded to an osmium atom. Molecular orbital calculations were carried out to gain further insight into the electronic structure of 1. Cluster 1 was also obtained in a higher yield by the reaction of [Os3(CO)11(MeCN)] with 9-anthracenecarbonitrile.
Persistent Identifierhttp://hdl.handle.net/10722/70022
ISSN
2015 Impact Factor: 1.762
2015 SCImago Journal Rankings: 0.489
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorWong, JSYen_HK
dc.contributor.authorLin, ZYen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:18:59Z-
dc.date.available2010-09-06T06:18:59Z-
dc.date.issued2003en_HK
dc.identifier.citationInorganic Chemistry Communications, 2003, v. 6, p. 713-717en_HK
dc.identifier.issn1387-7003en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70022-
dc.description.abstractTreatment of [Os3(CO)11(MeCN)] with 1 equivalent of 9-anthraldehyde oxime in refluxing chloroform afforded a new triosmium cluster [Os3(CO)11(C14H9CN)] 1 in moderate yield. Dehydration of oxime and the formation of metal-bound nitrile were observed. Crystal structure analysis revealed that cluster 1 consists of a triangular metal skeleton, with the anthracenecarbonitrile ligand terminally bonded to an osmium atom. Molecular orbital calculations were carried out to gain further insight into the electronic structure of 1. Cluster 1 was also obtained in a higher yield by the reaction of [Os3(CO)11(MeCN)] with 9-anthracenecarbonitrile.-
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/inocheen_HK
dc.relation.ispartofInorganic Chemistry Communicationsen_HK
dc.subjectTriosmium carbonyl cluster-
dc.subjectOxime ligand-
dc.subject9-Anthraldehyde oxime-
dc.subjectX-ray crystallography-
dc.titleSynthesis and structural characterization of a triosmium carbonyl cluster containing a 9-anthracenecarbonitrile ligands derived from 9-anthraldehyde oximeen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1387-7003&volume=6&spage=713&epage=717&date=2003&atitle=Synthesis+and+structural+characterization+of+a+triosmium+carbonyl+cluster+containing+a+9-anthracenecarbonitrile+ligands+derived+from+9-anthraldehyde+oximeen_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1016/S1387-7003(03)00081-9-
dc.identifier.scopuseid_2-s2.0-0038067789-
dc.identifier.hkuros76343en_HK
dc.identifier.volume6-
dc.identifier.spage713-
dc.identifier.epage717-
dc.identifier.isiWOS:000182649500024-
dc.publisher.placeNetherlands-

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