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Article: Syntheses, luminescence switching, and electrochemical studies of photochromic dithienyl-1,10-phenanthroline zinc(II) bis(thiolate) complexes

TitleSyntheses, luminescence switching, and electrochemical studies of photochromic dithienyl-1,10-phenanthroline zinc(II) bis(thiolate) complexes
Authors
Issue Date2007
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 2007, v. 46 n. 4, p. 1144-1152 How to Cite?
AbstractA series of zinc(II) diimine bis(thiolate) complexes with photochromic diarylethene-containing phenanthroline ligands was synthesized, and their photophysical and photochromic properties were studied. The X-ray crystal structures of two of these complexes have been characterized. All complexes exhibit strong 3LLCT phosphorescence at 510-620 nm in the solid state at 77 and 298 K and in EtOH-MeOH glass at 77 K. Detailed studies revealed that the absorption, emission, and electrochemical properties of the complexes could be readily switched via the photochromic ring-closing and ring-opening reactions. © 2007 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/70020
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorNgan, TWen_HK
dc.contributor.authorKo, CCen_HK
dc.contributor.authorZhu, Nen_HK
dc.contributor.authorYam, VWWen_HK
dc.date.accessioned2010-09-06T06:18:58Z-
dc.date.available2010-09-06T06:18:58Z-
dc.date.issued2007en_HK
dc.identifier.citationInorganic Chemistry, 2007, v. 46 n. 4, p. 1144-1152en_HK
dc.identifier.issn0020-1669en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70020-
dc.description.abstractA series of zinc(II) diimine bis(thiolate) complexes with photochromic diarylethene-containing phenanthroline ligands was synthesized, and their photophysical and photochromic properties were studied. The X-ray crystal structures of two of these complexes have been characterized. All complexes exhibit strong 3LLCT phosphorescence at 510-620 nm in the solid state at 77 and 298 K and in EtOH-MeOH glass at 77 K. Detailed studies revealed that the absorption, emission, and electrochemical properties of the complexes could be readily switched via the photochromic ring-closing and ring-opening reactions. © 2007 American Chemical Society.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/icen_HK
dc.relation.ispartofInorganic Chemistryen_HK
dc.titleSyntheses, luminescence switching, and electrochemical studies of photochromic dithienyl-1,10-phenanthroline zinc(II) bis(thiolate) complexesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0020-1669&volume=46&issue=4&spage=1144&epage=1152&date=2007&atitle=Syntheses,+luminescence+switching,+and+electrochemical+studies+of+photochromic+dithienyl-1,10-phenanthroline+zinc(II)+bis(thiolate)+complexesen_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.emailYam, VWW: wwyam@hku.hken_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ic061359cen_HK
dc.identifier.pmid17256839-
dc.identifier.scopuseid_2-s2.0-33847759960en_HK
dc.identifier.hkuros133120en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-33847759960&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume46en_HK
dc.identifier.issue4en_HK
dc.identifier.spage1144en_HK
dc.identifier.epage1152en_HK
dc.identifier.isiWOS:000244119300017-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridNgan, TW=16031411000en_HK
dc.identifier.scopusauthoridKo, CC=7202596455en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK

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