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Article: Metal complexes of chiral binaphthyl Schiff-base ligands and their application in stereoselective organic transformations

TitleMetal complexes of chiral binaphthyl Schiff-base ligands and their application in stereoselective organic transformations
Authors
KeywordsAsymmetric catalysis
Binaphthyl Schiff-base ligands
Chiral metal complexes
Structure elucidation
Issue Date2003
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ccr
Citation
Coordination Chemistry Reviews, 2003, v. 242 n. 1-2, p. 97-113 How to Cite?
AbstractCondensations of aromatic aldehydes with 2,2′-diamino-1,1′ -binaphthyl or 2-amino-2′-hydroxy-1,1′-binaphthyl afford various chiral binaphthyl Schiff-base ligands, the most common of which are potentially tetradentate with a N2O2 donor set. The chiral binaphthyl Schiff-base ligands have been shown to form stable complexes with metal ions of AI(III), Ti(IV), Cr(III), Mn(II)/Mn(III), Fe(II)/Fe(III), Co(II)ICo(III), Ni(II), Cu(II), Zn(II), Y(III), Zr(IV), Ru(II), and Pd(II); some of such complexes have been characterized by X-ray crystallography. Catalytic studies reveal that these types of chiral metal complexes are active catalysts for stereoselective organic transformations including hydroxylation of styrene, aldol reactions, alkene epoxidation, trimethylsilylcyanation of aldehydes, desymmetrization of meso-N-sulfonylaziridine, Baeyer-Villiger oxidation of aryl cyclobutanone, Diels-Alder reactions of 1,2-dihydropyridine, and ring-opening polymerization of lactide. © 2003 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/69995
ISSN
2015 Impact Factor: 12.994
2015 SCImago Journal Rankings: 4.100
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_HK
dc.contributor.authorHuang, JSen_HK
dc.date.accessioned2010-09-06T06:18:44Z-
dc.date.available2010-09-06T06:18:44Z-
dc.date.issued2003en_HK
dc.identifier.citationCoordination Chemistry Reviews, 2003, v. 242 n. 1-2, p. 97-113en_HK
dc.identifier.issn0010-8545en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69995-
dc.description.abstractCondensations of aromatic aldehydes with 2,2′-diamino-1,1′ -binaphthyl or 2-amino-2′-hydroxy-1,1′-binaphthyl afford various chiral binaphthyl Schiff-base ligands, the most common of which are potentially tetradentate with a N2O2 donor set. The chiral binaphthyl Schiff-base ligands have been shown to form stable complexes with metal ions of AI(III), Ti(IV), Cr(III), Mn(II)/Mn(III), Fe(II)/Fe(III), Co(II)ICo(III), Ni(II), Cu(II), Zn(II), Y(III), Zr(IV), Ru(II), and Pd(II); some of such complexes have been characterized by X-ray crystallography. Catalytic studies reveal that these types of chiral metal complexes are active catalysts for stereoselective organic transformations including hydroxylation of styrene, aldol reactions, alkene epoxidation, trimethylsilylcyanation of aldehydes, desymmetrization of meso-N-sulfonylaziridine, Baeyer-Villiger oxidation of aryl cyclobutanone, Diels-Alder reactions of 1,2-dihydropyridine, and ring-opening polymerization of lactide. © 2003 Elsevier B.V. All rights reserved.en_HK
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ccren_HK
dc.relation.ispartofCoordination Chemistry Reviewsen_HK
dc.rightsCoordination Chemistry Reviews. Copyright © Elsevier BV.en_HK
dc.subjectAsymmetric catalysisen_HK
dc.subjectBinaphthyl Schiff-base ligandsen_HK
dc.subjectChiral metal complexesen_HK
dc.subjectStructure elucidationen_HK
dc.titleMetal complexes of chiral binaphthyl Schiff-base ligands and their application in stereoselective organic transformationsen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0010-8545&volume=242&spage=97&epage=113&date=2003&atitle=Metal+complexes+of+chiral+binaphthyl+schiff-base+ligands+and+their+application+in+stereoselective+organic+transformationsen_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.emailHuang, JS:jshuang@hkucc.hku.hken_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.identifier.authorityHuang, JS=rp00709en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0010-8545(03)00065-1en_HK
dc.identifier.scopuseid_2-s2.0-0043287709en_HK
dc.identifier.hkuros90403en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0043287709&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume242en_HK
dc.identifier.issue1-2en_HK
dc.identifier.spage97en_HK
dc.identifier.epage113en_HK
dc.identifier.isiWOS:000185166600009-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.scopusauthoridHuang, JS=7407192639en_HK

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