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Article: Metal complexes of chiral binaphthyl Schiff-base ligands and their application in stereoselective organic transformations
Title | Metal complexes of chiral binaphthyl Schiff-base ligands and their application in stereoselective organic transformations |
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Authors | |
Keywords | Asymmetric catalysis Binaphthyl Schiff-base ligands Chiral metal complexes Structure elucidation |
Issue Date | 2003 |
Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ccr |
Citation | Coordination Chemistry Reviews, 2003, v. 242 n. 1-2, p. 97-113 How to Cite? |
Abstract | Condensations of aromatic aldehydes with 2,2′-diamino-1,1′ -binaphthyl or 2-amino-2′-hydroxy-1,1′-binaphthyl afford various chiral binaphthyl Schiff-base ligands, the most common of which are potentially tetradentate with a N2O2 donor set. The chiral binaphthyl Schiff-base ligands have been shown to form stable complexes with metal ions of AI(III), Ti(IV), Cr(III), Mn(II)/Mn(III), Fe(II)/Fe(III), Co(II)ICo(III), Ni(II), Cu(II), Zn(II), Y(III), Zr(IV), Ru(II), and Pd(II); some of such complexes have been characterized by X-ray crystallography. Catalytic studies reveal that these types of chiral metal complexes are active catalysts for stereoselective organic transformations including hydroxylation of styrene, aldol reactions, alkene epoxidation, trimethylsilylcyanation of aldehydes, desymmetrization of meso-N-sulfonylaziridine, Baeyer-Villiger oxidation of aryl cyclobutanone, Diels-Alder reactions of 1,2-dihydropyridine, and ring-opening polymerization of lactide. © 2003 Elsevier B.V. All rights reserved. |
Persistent Identifier | http://hdl.handle.net/10722/69995 |
ISSN | 2023 Impact Factor: 20.3 2023 SCImago Journal Rankings: 4.145 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
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dc.contributor.author | Che, CM | en_HK |
dc.contributor.author | Huang, JS | en_HK |
dc.date.accessioned | 2010-09-06T06:18:44Z | - |
dc.date.available | 2010-09-06T06:18:44Z | - |
dc.date.issued | 2003 | en_HK |
dc.identifier.citation | Coordination Chemistry Reviews, 2003, v. 242 n. 1-2, p. 97-113 | en_HK |
dc.identifier.issn | 0010-8545 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/69995 | - |
dc.description.abstract | Condensations of aromatic aldehydes with 2,2′-diamino-1,1′ -binaphthyl or 2-amino-2′-hydroxy-1,1′-binaphthyl afford various chiral binaphthyl Schiff-base ligands, the most common of which are potentially tetradentate with a N2O2 donor set. The chiral binaphthyl Schiff-base ligands have been shown to form stable complexes with metal ions of AI(III), Ti(IV), Cr(III), Mn(II)/Mn(III), Fe(II)/Fe(III), Co(II)ICo(III), Ni(II), Cu(II), Zn(II), Y(III), Zr(IV), Ru(II), and Pd(II); some of such complexes have been characterized by X-ray crystallography. Catalytic studies reveal that these types of chiral metal complexes are active catalysts for stereoselective organic transformations including hydroxylation of styrene, aldol reactions, alkene epoxidation, trimethylsilylcyanation of aldehydes, desymmetrization of meso-N-sulfonylaziridine, Baeyer-Villiger oxidation of aryl cyclobutanone, Diels-Alder reactions of 1,2-dihydropyridine, and ring-opening polymerization of lactide. © 2003 Elsevier B.V. All rights reserved. | en_HK |
dc.language | eng | en_HK |
dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ccr | en_HK |
dc.relation.ispartof | Coordination Chemistry Reviews | en_HK |
dc.rights | Coordination Chemistry Reviews. Copyright © Elsevier BV. | en_HK |
dc.subject | Asymmetric catalysis | en_HK |
dc.subject | Binaphthyl Schiff-base ligands | en_HK |
dc.subject | Chiral metal complexes | en_HK |
dc.subject | Structure elucidation | en_HK |
dc.title | Metal complexes of chiral binaphthyl Schiff-base ligands and their application in stereoselective organic transformations | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0010-8545&volume=242&spage=97&epage=113&date=2003&atitle=Metal+complexes+of+chiral+binaphthyl+schiff-base+ligands+and+their+application+in+stereoselective+organic+transformations | en_HK |
dc.identifier.email | Che, CM:cmche@hku.hk | en_HK |
dc.identifier.email | Huang, JS:jshuang@hkucc.hku.hk | en_HK |
dc.identifier.authority | Che, CM=rp00670 | en_HK |
dc.identifier.authority | Huang, JS=rp00709 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/S0010-8545(03)00065-1 | en_HK |
dc.identifier.scopus | eid_2-s2.0-0043287709 | en_HK |
dc.identifier.hkuros | 90403 | en_HK |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0043287709&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 242 | en_HK |
dc.identifier.issue | 1-2 | en_HK |
dc.identifier.spage | 97 | en_HK |
dc.identifier.epage | 113 | en_HK |
dc.identifier.isi | WOS:000185166600009 | - |
dc.publisher.place | Netherlands | en_HK |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_HK |
dc.identifier.scopusauthorid | Huang, JS=7407192639 | en_HK |
dc.identifier.issnl | 0010-8545 | - |