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Article: A practical and mild method for the highly selective conversion of terminal alkenes into aldehydes through epoxidation-isomerization with ruthenium(IV)-porphyrin catalysts

TitleA practical and mild method for the highly selective conversion of terminal alkenes into aldehydes through epoxidation-isomerization with ruthenium(IV)-porphyrin catalysts
Authors
KeywordsHomogeneous catalysis
Metalloporphyrins
N ligands
Oxidation
Ruthenium
Issue Date2004
PublisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home
Citation
Angewandte Chemie - International Edition, 2004, v. 43 n. 37, p. 4950-4954 How to Cite?
AbstractAldehydes in excellent yields were obtained from the ruthenium-porphyrin- catalyzed oxidation of various terminal alkenes with 2,6-dichloropyridine N-oxide under mild conditions. The aldehydes generated from these ruthenium-catalyzed alkene oxidations can be used in situ for olefination reactions with ethyl diazoacetate in the presence of PPh3 in a one-pot diazoacetate olefination starting from alkenes (see example).
Persistent Identifierhttp://hdl.handle.net/10722/69988
ISSN
2015 Impact Factor: 11.709
2015 SCImago Journal Rankings: 6.229
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorChen, Jen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2010-09-06T06:18:40Z-
dc.date.available2010-09-06T06:18:40Z-
dc.date.issued2004en_HK
dc.identifier.citationAngewandte Chemie - International Edition, 2004, v. 43 n. 37, p. 4950-4954en_HK
dc.identifier.issn1433-7851en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69988-
dc.description.abstractAldehydes in excellent yields were obtained from the ruthenium-porphyrin- catalyzed oxidation of various terminal alkenes with 2,6-dichloropyridine N-oxide under mild conditions. The aldehydes generated from these ruthenium-catalyzed alkene oxidations can be used in situ for olefination reactions with ethyl diazoacetate in the presence of PPh3 in a one-pot diazoacetate olefination starting from alkenes (see example).en_HK
dc.languageengen_HK
dc.publisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/homeen_HK
dc.relation.ispartofAngewandte Chemie - International Editionen_HK
dc.subjectHomogeneous catalysisen_HK
dc.subjectMetalloporphyrinsen_HK
dc.subjectN ligandsen_HK
dc.subjectOxidationen_HK
dc.subjectRutheniumen_HK
dc.titleA practical and mild method for the highly selective conversion of terminal alkenes into aldehydes through epoxidation-isomerization with ruthenium(IV)-porphyrin catalystsen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1433-7851&volume=43&spage=4950&epage=4954&date=2004&atitle=A+practical+and+mild+method+for+the+highly+selective+conversion+of+terminal+alkenes+into+aldehydes+through+epoxidation-isomerization+with+ruthenium(IV)-porphyrin+catalystsen_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.200460545en_HK
dc.identifier.scopuseid_2-s2.0-4744345859en_HK
dc.identifier.hkuros107058en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-4744345859&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume43en_HK
dc.identifier.issue37en_HK
dc.identifier.spage4950en_HK
dc.identifier.epage4954en_HK
dc.identifier.isiWOS:000224140400029-
dc.publisher.placeGermanyen_HK
dc.identifier.scopusauthoridChen, J=36047378100en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK

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