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Article: Synthesis, characterization, structure and luminescence studies of dinuclear gold(I) alkynyls of bis(diphenylphosphino)alkyl- and aryl-amines
Title | Synthesis, characterization, structure and luminescence studies of dinuclear gold(I) alkynyls of bis(diphenylphosphino)alkyl- and aryl-amines |
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Authors | |
Keywords | Alkynyl ligands Gold(I) Luminescence Phosphine ligands |
Issue Date | 2006 |
Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ica |
Citation | Inorganica Chimica Acta, 2006, v. 359 n. 11, p. 3639-3648 How to Cite? |
Abstract | A series of alkynylgold(I) bis(diphenylphosphino)alkyl- and aryl-amine complexes, [{Ph2PN(R)PPh2}Au2(C{triple bond, long}CR′)2] [R = nPr, R′ = Ph (1), C6H4OMe-p (2), C6H4Me-p (3), C6H4Cl-p (4); R = C6H4OMe-p, R′ = Ph (5)], has been synthesized. The X-ray crystal structures of 1 and 2 revealed the presence of short intramolecular Au⋯Au contacts with the distances of 2.8404(8) and 3.0708(7) Å. The luminescence behavior of the complexes were studied. © 2005 Elsevier B.V. All rights reserved. |
Persistent Identifier | http://hdl.handle.net/10722/69958 |
ISSN | 2023 Impact Factor: 2.7 2023 SCImago Journal Rankings: 0.386 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Yip, SK | en_HK |
dc.contributor.author | Lam, WH | en_HK |
dc.contributor.author | Zhu, N | en_HK |
dc.contributor.author | Yam, VWW | en_HK |
dc.date.accessioned | 2010-09-06T06:18:24Z | - |
dc.date.available | 2010-09-06T06:18:24Z | - |
dc.date.issued | 2006 | en_HK |
dc.identifier.citation | Inorganica Chimica Acta, 2006, v. 359 n. 11, p. 3639-3648 | en_HK |
dc.identifier.issn | 0020-1693 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/69958 | - |
dc.description.abstract | A series of alkynylgold(I) bis(diphenylphosphino)alkyl- and aryl-amine complexes, [{Ph2PN(R)PPh2}Au2(C{triple bond, long}CR′)2] [R = nPr, R′ = Ph (1), C6H4OMe-p (2), C6H4Me-p (3), C6H4Cl-p (4); R = C6H4OMe-p, R′ = Ph (5)], has been synthesized. The X-ray crystal structures of 1 and 2 revealed the presence of short intramolecular Au⋯Au contacts with the distances of 2.8404(8) and 3.0708(7) Å. The luminescence behavior of the complexes were studied. © 2005 Elsevier B.V. All rights reserved. | en_HK |
dc.language | eng | en_HK |
dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ica | en_HK |
dc.relation.ispartof | Inorganica Chimica Acta | en_HK |
dc.rights | Inorganica Chimica Acta. Copyright © Elsevier BV. | en_HK |
dc.subject | Alkynyl ligands | en_HK |
dc.subject | Gold(I) | en_HK |
dc.subject | Luminescence | en_HK |
dc.subject | Phosphine ligands | en_HK |
dc.title | Synthesis, characterization, structure and luminescence studies of dinuclear gold(I) alkynyls of bis(diphenylphosphino)alkyl- and aryl-amines | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0020-1693&volume=359&spage=3639&epage=3648&date=2006&atitle=Synthesis,+Characterization,+Structure+and+Luminescence+Studies+of+Dinuclear+Gold(I)+Alkynyls+of+Bis(diphenylphosphino)+Alkyl-+and+Aryl-amines | en_HK |
dc.identifier.email | Lam, WH: chsue@hku.hk | en_HK |
dc.identifier.email | Zhu, N: nzhu@hkucc.hku.hk | en_HK |
dc.identifier.email | Yam, VWW: wwyam@hku.hk | en_HK |
dc.identifier.authority | Lam, WH=rp00719 | en_HK |
dc.identifier.authority | Zhu, N=rp00845 | en_HK |
dc.identifier.authority | Yam, VWW=rp00822 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/j.ica.2005.11.007 | en_HK |
dc.identifier.scopus | eid_2-s2.0-33745712276 | en_HK |
dc.identifier.hkuros | 133128 | en_HK |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-33745712276&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 359 | en_HK |
dc.identifier.issue | 11 | en_HK |
dc.identifier.spage | 3639 | en_HK |
dc.identifier.epage | 3648 | en_HK |
dc.identifier.isi | WOS:000239475800028 | - |
dc.publisher.place | Netherlands | en_HK |
dc.identifier.scopusauthorid | Yip, SK=7102133674 | en_HK |
dc.identifier.scopusauthorid | Lam, WH=26642862800 | en_HK |
dc.identifier.scopusauthorid | Zhu, N=7201449530 | en_HK |
dc.identifier.scopusauthorid | Yam, VWW=18539304700 | en_HK |
dc.identifier.issnl | 0020-1693 | - |