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Article: tert-Butylhydroperoxide epoxidation of alkenes catalysed by ruthenium complex of 1,4,7-trimethyl-1,4,7-triazacyclononane

Titletert-Butylhydroperoxide epoxidation of alkenes catalysed by ruthenium complex of 1,4,7-trimethyl-1,4,7-triazacyclononane
Authors
KeywordsAlkene epoxidation
Catalyst
Oxidation
Ruthenium
Issue Date1996
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/molcata
Citation
Journal Of Molecular Catalysis A: Chemical, 1996, v. 113 n. 1-2, p. 311-319 How to Cite?
AbstractThe complex [Ru(III)(Me3tacn)(OH2)2(CF3CO2)](CF3CO2)2 (Me3tacn = 1,4,7-trimethyl-1,4,7-triazacyclononane, CF3CO2 = trifluoroacetate) is an effective catalyst for the oxidation of organic substrates by tert- butylhydroperoxide. It exhibits high activity and selectivity for alkene epoxidation under mild conditions. A heterolytic O-O cleavage mechanism and an alkylperoxoruthenium(VI) active intermediate are suggested for the catalytic alkene epoxidation.
Persistent Identifierhttp://hdl.handle.net/10722/69929
ISSN
2015 Impact Factor: 3.958
2015 SCImago Journal Rankings: 1.072
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorCheng, WCen_HK
dc.contributor.authorFung, WHen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2010-09-06T06:18:08Z-
dc.date.available2010-09-06T06:18:08Z-
dc.date.issued1996en_HK
dc.identifier.citationJournal Of Molecular Catalysis A: Chemical, 1996, v. 113 n. 1-2, p. 311-319en_HK
dc.identifier.issn1381-1169en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69929-
dc.description.abstractThe complex [Ru(III)(Me3tacn)(OH2)2(CF3CO2)](CF3CO2)2 (Me3tacn = 1,4,7-trimethyl-1,4,7-triazacyclononane, CF3CO2 = trifluoroacetate) is an effective catalyst for the oxidation of organic substrates by tert- butylhydroperoxide. It exhibits high activity and selectivity for alkene epoxidation under mild conditions. A heterolytic O-O cleavage mechanism and an alkylperoxoruthenium(VI) active intermediate are suggested for the catalytic alkene epoxidation.en_HK
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/molcataen_HK
dc.relation.ispartofJournal of Molecular Catalysis A: Chemicalen_HK
dc.subjectAlkene epoxidationen_HK
dc.subjectCatalysten_HK
dc.subjectOxidationen_HK
dc.subjectRutheniumen_HK
dc.titletert-Butylhydroperoxide epoxidation of alkenes catalysed by ruthenium complex of 1,4,7-trimethyl-1,4,7-triazacyclononaneen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-2828&volume=113&spage=311&epage=319&date=1996&atitle=tert-Butylhydroperoxide+epoxidation+of+alkenes+catalysed+by+ruthenium+complex+of+1,4,7-trimethyl-1,4,7-triazacyclononaneen_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S1381-1169(96)00146-Xen_HK
dc.identifier.scopuseid_2-s2.0-0030602004en_HK
dc.identifier.hkuros22010en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0030602004&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume113en_HK
dc.identifier.issue1-2en_HK
dc.identifier.spage311en_HK
dc.identifier.epage319en_HK
dc.identifier.isiWOS:A1996VV53000030-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridCheng, WC=7402169293en_HK
dc.identifier.scopusauthoridFung, WH=7102150303en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK

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