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Article: First enantioselective syntheses of (+)- and (-)-wilforonide by using chiral auxiliaries derived from the same chiral source

TitleFirst enantioselective syntheses of (+)- and (-)-wilforonide by using chiral auxiliaries derived from the same chiral source
Authors
Issue Date2001
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/orlef7/index.html
Citation
Organic Letters, 2001, v. 3 n. 12, p. 1785-1788 How to Cite?
Abstract(formula presented) The first enantioselective syntheses of both (+)-wilforonide (>98% ee) and (-)-wilforonide (>98% ee) have been accomplished by employing chiral auxiliaries derived from the same chiral source, (R)-pulegone. The bicyclic skeleton of wilforonide was constructed by using Mn(III)-based oxidative radical cyclization reactions of chiral β-keto esters. The absolute configuration of natural wilforonide has been established to be (5aR,9aR).
Persistent Identifierhttp://hdl.handle.net/10722/69911
ISSN
2015 Impact Factor: 6.732
2015 SCImago Journal Rankings: 3.187
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorYang, Den_HK
dc.contributor.authorXu, Men_HK
dc.date.accessioned2010-09-06T06:17:58Z-
dc.date.available2010-09-06T06:17:58Z-
dc.date.issued2001en_HK
dc.identifier.citationOrganic Letters, 2001, v. 3 n. 12, p. 1785-1788en_HK
dc.identifier.issn1523-7060en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69911-
dc.description.abstract(formula presented) The first enantioselective syntheses of both (+)-wilforonide (>98% ee) and (-)-wilforonide (>98% ee) have been accomplished by employing chiral auxiliaries derived from the same chiral source, (R)-pulegone. The bicyclic skeleton of wilforonide was constructed by using Mn(III)-based oxidative radical cyclization reactions of chiral β-keto esters. The absolute configuration of natural wilforonide has been established to be (5aR,9aR).en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/orlef7/index.htmlen_HK
dc.relation.ispartofOrganic Lettersen_HK
dc.titleFirst enantioselective syntheses of (+)- and (-)-wilforonide by using chiral auxiliaries derived from the same chiral sourceen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1523-7060&volume=3&issue=12&spage=1785&epage=1788&date=2001&atitle=First+Enantioselective+Syntheses+of+(+)-+and+(-)-Wilforonide+by+Using+Chiral+Auxiliaries+Derived+from+the+Same+Chiral+Sourceen_HK
dc.identifier.emailYang, D:yangdan@hku.hken_HK
dc.identifier.authorityYang, D=rp00825en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ol015722pen_HK
dc.identifier.scopuseid_2-s2.0-0035859356en_HK
dc.identifier.hkuros58726en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0035859356&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume3en_HK
dc.identifier.issue12en_HK
dc.identifier.spage1785en_HK
dc.identifier.epage1788en_HK
dc.identifier.isiWOS:000169247100001-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridYang, D=7404800756en_HK
dc.identifier.scopusauthoridXu, M=15729771700en_HK

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