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Article: Iridium insertion to triosmium cluster containing unsaturated Os-Os bonds

TitleIridium insertion to triosmium cluster containing unsaturated Os-Os bonds
Authors
KeywordsClusters
Cyclopentadienyl
Iridium
Osmium
Issue Date2008
PublisherSpringer New York LLC. The Journal's web site is located at http://springerlink.metapress.com/openurl.asp?genre=journal&issn=1040-7278
Citation
Journal Of Cluster Science, 2008, v. 19 n. 1, p. 133-145 How to Cite?
AbstractTreatment of the triosmium hydrido cluster, [Os3(μ-H) 2(CO)10], with one equivalent of [IrCp*Cl 2]2 (Cp*= pentamethylcyclopentadiene) in refluxing THF afforded four osmium-iridium clusters, including [Os3Ir 2(μ-CO)(μ-H)2(CO)9(Cp*) 2] (1), [Os3IrCp*(μ-H)3(μ-Cl)(CO) 9] (2), [Os3IrCp*(μ-H)(μ-Cl)(μ-CO)(CO) 9] (3) and [Os2IrCp*(μ-H)(μ-Cl)(CO) 7] (4), in moderate yields. The reactivity of complex 3 with hydrogen, carbon monoxide, and thallium hexafluorophosphate was studied. Complex 4 was found to react with [Os3(μ-H)2(CO)10] to give 2 and 3. All of the new compounds were characterized by conventional spectroscopic methods and single-crystal X-ray analysis. © 2007 Springer Science+Business Media, LLC.
Persistent Identifierhttp://hdl.handle.net/10722/69876
ISSN
2015 Impact Factor: 1.664
2015 SCImago Journal Rankings: 0.416
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLee, YBen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:17:38Z-
dc.date.available2010-09-06T06:17:38Z-
dc.date.issued2008en_HK
dc.identifier.citationJournal Of Cluster Science, 2008, v. 19 n. 1, p. 133-145en_HK
dc.identifier.issn1040-7278en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69876-
dc.description.abstractTreatment of the triosmium hydrido cluster, [Os3(μ-H) 2(CO)10], with one equivalent of [IrCp*Cl 2]2 (Cp*= pentamethylcyclopentadiene) in refluxing THF afforded four osmium-iridium clusters, including [Os3Ir 2(μ-CO)(μ-H)2(CO)9(Cp*) 2] (1), [Os3IrCp*(μ-H)3(μ-Cl)(CO) 9] (2), [Os3IrCp*(μ-H)(μ-Cl)(μ-CO)(CO) 9] (3) and [Os2IrCp*(μ-H)(μ-Cl)(CO) 7] (4), in moderate yields. The reactivity of complex 3 with hydrogen, carbon monoxide, and thallium hexafluorophosphate was studied. Complex 4 was found to react with [Os3(μ-H)2(CO)10] to give 2 and 3. All of the new compounds were characterized by conventional spectroscopic methods and single-crystal X-ray analysis. © 2007 Springer Science+Business Media, LLC.en_HK
dc.languageengen_HK
dc.publisherSpringer New York LLC. The Journal's web site is located at http://springerlink.metapress.com/openurl.asp?genre=journal&issn=1040-7278en_HK
dc.relation.ispartofJournal of Cluster Scienceen_HK
dc.subjectClustersen_HK
dc.subjectCyclopentadienylen_HK
dc.subjectIridiumen_HK
dc.subjectOsmiumen_HK
dc.titleIridium insertion to triosmium cluster containing unsaturated Os-Os bondsen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1040-7278&volume=19&spage=133&epage=145&date=2008&atitle=Iridium+Insertion+to+Triosmium+Cluster+Containing+Unsaturated+Os-Os+Bonds+en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1007/s10876-007-0159-0en_HK
dc.identifier.scopuseid_2-s2.0-40549083773en_HK
dc.identifier.hkuros142018en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-40549083773&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume19en_HK
dc.identifier.issue1en_HK
dc.identifier.spage133en_HK
dc.identifier.epage145en_HK
dc.identifier.isiWOS:000253896300010-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridLee, YB=23009409400en_HK
dc.identifier.scopusauthoridWong, WT=7403973084en_HK

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