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Article: A new self-assembled copper(I) complex of 2-thioxo-5H-1,3-dithiolo[4,5-b][1,4]dithiepin-6(7H)-one showing three-dimensional supramolecular networks

TitleA new self-assembled copper(I) complex of 2-thioxo-5H-1,3-dithiolo[4,5-b][1,4]dithiepin-6(7H)-one showing three-dimensional supramolecular networks
Authors
KeywordsCopper complexes
Crystal structures
Polymeric complexes
Thione complexes
Issue Date1999
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ica
Citation
Inorganica Chimica Acta, 1999, v. 292 n. 1, p. 117-120 How to Cite?
AbstractThe synthesis and structural characterization of a supramolecular copper(I) complex of 2-thioxo-1,3-dithiolo[4,5-b][1,4]dithiepin-6(7H)-one are described. The complex crystallized in the orthorhombic space group Pna21 with the cell dimensions a=12.9124(2), b=20.7944(2), c=4.4457(1) Å, V=1193.70(3) Å3 and Z=4. The structure was refined to a final agreement factor R=0.0295. The C6H4OS5Cu units are connected by bridging iodide atoms to form a ladder structure. The CuCu separation is 2.9884(9) Å, and the short SS and SI contacts interchain lead to a novel three-dimensional network. © 1999 Elsevier Science S.A.
Persistent Identifierhttp://hdl.handle.net/10722/69864
ISSN
2015 Impact Factor: 1.918
2015 SCImago Journal Rankings: 0.584
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorZuo, JLen_HK
dc.contributor.authorBai, JFen_HK
dc.contributor.authorShen, Zen_HK
dc.contributor.authorYou, XZen_HK
dc.contributor.authorFun, HKen_HK
dc.contributor.authorChinnakali, Ken_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2010-09-06T06:17:32Z-
dc.date.available2010-09-06T06:17:32Z-
dc.date.issued1999en_HK
dc.identifier.citationInorganica Chimica Acta, 1999, v. 292 n. 1, p. 117-120en_HK
dc.identifier.issn0020-1693en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69864-
dc.description.abstractThe synthesis and structural characterization of a supramolecular copper(I) complex of 2-thioxo-1,3-dithiolo[4,5-b][1,4]dithiepin-6(7H)-one are described. The complex crystallized in the orthorhombic space group Pna21 with the cell dimensions a=12.9124(2), b=20.7944(2), c=4.4457(1) Å, V=1193.70(3) Å3 and Z=4. The structure was refined to a final agreement factor R=0.0295. The C6H4OS5Cu units are connected by bridging iodide atoms to form a ladder structure. The CuCu separation is 2.9884(9) Å, and the short SS and SI contacts interchain lead to a novel three-dimensional network. © 1999 Elsevier Science S.A.en_HK
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/icaen_HK
dc.relation.ispartofInorganica Chimica Actaen_HK
dc.rightsInorganica Chimica Acta. Copyright © Elsevier BV.en_HK
dc.subjectCopper complexesen_HK
dc.subjectCrystal structuresen_HK
dc.subjectPolymeric complexesen_HK
dc.subjectThione complexesen_HK
dc.titleA new self-assembled copper(I) complex of 2-thioxo-5H-1,3-dithiolo[4,5-b][1,4]dithiepin-6(7H)-one showing three-dimensional supramolecular networksen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0020-1693&volume=292&spage=117&epage=120&date=1999&atitle=A+new+self-assembled+copper(I)+complex+of+2-thioxo-5H-1,3-dithiolo[4,5-b][1,4]dithiepin-6(7H)-one+showing+three-dimensional+supramolecular+networksen_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0020-1693(99)00155-3-
dc.identifier.scopuseid_2-s2.0-0039442522en_HK
dc.identifier.hkuros53167en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0039442522&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume292en_HK
dc.identifier.issue1en_HK
dc.identifier.spage117en_HK
dc.identifier.epage120en_HK
dc.identifier.isiWOS:000082226700016-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridZuo, JL=7202871908en_HK
dc.identifier.scopusauthoridBai, JF=7403129290en_HK
dc.identifier.scopusauthoridShen, Z=13606179000en_HK
dc.identifier.scopusauthoridYou, XZ=36072101800en_HK
dc.identifier.scopusauthoridFun, HK=34975048300en_HK
dc.identifier.scopusauthoridChinnakali, K=7004369632en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK

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