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Article: Solid state syntheses and crystal structures of [Cu(HOC6H4CHNNHCSNH2) (PPh3)2X] (X = I, Br)

TitleSolid state syntheses and crystal structures of [Cu(HOC6H4CHNNHCSNH2) (PPh3)2X] (X = I, Br)
Authors
KeywordsCopper(I) complexes
Crystal structures
Solid state syntheses
Spectroscopic characterization
Thiosemicarbazone complexes
Issue Date1997
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly
Citation
Polyhedron, 1997, v. 16 n. 20, p. 3499-3503 How to Cite?
AbstractThe complexes [Cu(L) (PPh3)2X] [L1 = 2-[(4-hydroxyphenyl methylene)]hydrazinecarbothioamine, X = I(I) and L2 = 2-[(2-hydroxyphenyl methylene)]hydrazinecarbothioamine, X = Br(II) were obtained by the solid state reaction of L, CuX, PPh3 and characterized by elemental analysis, IR and UV-Vis spectroscopy. The crystal structures have been determined by single crystal X-ray diffraction. The copper atom is coordinated tetrahedrally by two phosphine atoms from PPh3, one halogen atom and one sulfur atom from L acting as a monodentate ligand. In the compound (I), two molecules and two solvents MeCN molecules are in the asymmetric unit. The Cu - S bond lengths are 2.402(3) Å for molecule A and 2.376(3) Å for molecule B; respectively. In the compound (II), one solvate MeCN molecule is in the asymmetric unit ; the Cu - S bond length is 2.379(3) Å. © 1997 Elsevier Science Ltd.
Persistent Identifierhttp://hdl.handle.net/10722/69847
ISSN
2015 Impact Factor: 2.108
2015 SCImago Journal Rankings: 0.592
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorZheng, HGen_HK
dc.contributor.authorZeng, DXen_HK
dc.contributor.authorXin, XQen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:17:23Z-
dc.date.available2010-09-06T06:17:23Z-
dc.date.issued1997en_HK
dc.identifier.citationPolyhedron, 1997, v. 16 n. 20, p. 3499-3503en_HK
dc.identifier.issn0277-5387en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69847-
dc.description.abstractThe complexes [Cu(L) (PPh3)2X] [L1 = 2-[(4-hydroxyphenyl methylene)]hydrazinecarbothioamine, X = I(I) and L2 = 2-[(2-hydroxyphenyl methylene)]hydrazinecarbothioamine, X = Br(II) were obtained by the solid state reaction of L, CuX, PPh3 and characterized by elemental analysis, IR and UV-Vis spectroscopy. The crystal structures have been determined by single crystal X-ray diffraction. The copper atom is coordinated tetrahedrally by two phosphine atoms from PPh3, one halogen atom and one sulfur atom from L acting as a monodentate ligand. In the compound (I), two molecules and two solvents MeCN molecules are in the asymmetric unit. The Cu - S bond lengths are 2.402(3) Å for molecule A and 2.376(3) Å for molecule B; respectively. In the compound (II), one solvate MeCN molecule is in the asymmetric unit ; the Cu - S bond length is 2.379(3) Å. © 1997 Elsevier Science Ltd.en_HK
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/polyen_HK
dc.relation.ispartofPolyhedronen_HK
dc.rightsPolyhedron. Copyright © Elsevier BV.en_HK
dc.subjectCopper(I) complexesen_HK
dc.subjectCrystal structuresen_HK
dc.subjectSolid state synthesesen_HK
dc.subjectSpectroscopic characterizationen_HK
dc.subjectThiosemicarbazone complexesen_HK
dc.titleSolid state syntheses and crystal structures of [Cu(HOC6H4CHNNHCSNH2) (PPh3)2X] (X = I, Br)en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0277-5387&volume=16&issue=20&spage=3499&epage=3503&date=1997&atitle=Solid+state+syntheses+and+crystal+structures+of+[Cu(HOC6H4CHNNHCSNH2)(PPh3)2X]+(X+=+I,+Br)en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0277-5387(97)00129-0-
dc.identifier.scopuseid_2-s2.0-0001461583en_HK
dc.identifier.hkuros31372en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0001461583&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume16en_HK
dc.identifier.issue20en_HK
dc.identifier.spage3499en_HK
dc.identifier.epage3503en_HK
dc.identifier.isiWOS:A1997XQ92400004-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridZheng, HG=7403441387en_HK
dc.identifier.scopusauthoridZeng, DX=7102695317en_HK
dc.identifier.scopusauthoridXin, XQ=7102700870en_HK
dc.identifier.scopusauthoridWong, WT=7403973084en_HK

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