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Article: Highly selective intra- and intermolecular coupling reactions of diazo compounds to form cis-alkenes using a ruthenium porphyrin catalyst

TitleHighly selective intra- and intermolecular coupling reactions of diazo compounds to form cis-alkenes using a ruthenium porphyrin catalyst
Authors
Issue Date2004
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/orlef7/index.html
Citation
Organic Letters, 2004, v. 6 n. 10, p. 1621-1623 How to Cite?
Abstract[Ru(2,6-Cl2TPP)(CO)] catalyzed intramolecular coupling reactions of bisdiazoacetates and intermolecular coupling reactions of monodiazoacetates to afford the coupling products in up to 76% and 93% yields, respectively. Only the cis isomers were obtained from the reactions. Employing such a ruthenium-catalyzed coupling reaction of a diazo compound as a key step allowed the synthesis of Patulolide B in 67% yield with a ratio of >40:1 against its trans isomer.
Persistent Identifierhttp://hdl.handle.net/10722/69833
ISSN
2015 Impact Factor: 6.732
2015 SCImago Journal Rankings: 3.187
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLi, GYen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2010-09-06T06:17:15Z-
dc.date.available2010-09-06T06:17:15Z-
dc.date.issued2004en_HK
dc.identifier.citationOrganic Letters, 2004, v. 6 n. 10, p. 1621-1623en_HK
dc.identifier.issn1523-7060en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69833-
dc.description.abstract[Ru(2,6-Cl2TPP)(CO)] catalyzed intramolecular coupling reactions of bisdiazoacetates and intermolecular coupling reactions of monodiazoacetates to afford the coupling products in up to 76% and 93% yields, respectively. Only the cis isomers were obtained from the reactions. Employing such a ruthenium-catalyzed coupling reaction of a diazo compound as a key step allowed the synthesis of Patulolide B in 67% yield with a ratio of >40:1 against its trans isomer.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/orlef7/index.htmlen_HK
dc.relation.ispartofOrganic Lettersen_HK
dc.titleHighly selective intra- and intermolecular coupling reactions of diazo compounds to form cis-alkenes using a ruthenium porphyrin catalysten_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1523-7060&volume=6&spage=1621&epage=1623&date=2004&atitle=Highly+selective+intra-+and+intermolecular+coupling+reactions+of+diazo+compounds+to+form+cis-alkenes+using+a+ruthenium+porphyrin+catalysten_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ol049626aen_HK
dc.identifier.scopuseid_2-s2.0-2542569635en_HK
dc.identifier.hkuros94178en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-2542569635&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume6en_HK
dc.identifier.issue10en_HK
dc.identifier.spage1621en_HK
dc.identifier.epage1623en_HK
dc.identifier.isiWOS:000221278500026-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridLi, GY=15765581300en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK

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