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Article: Synthesis and photosensitizing properties of conjugated polymers that contain chlorotricarbonyl bis(phenylimino)acenaphthene rhenium(I) complexes

TitleSynthesis and photosensitizing properties of conjugated polymers that contain chlorotricarbonyl bis(phenylimino)acenaphthene rhenium(I) complexes
Authors
KeywordsConjugated polymers
Photovoltaic
Rhenium
Issue Date2005
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ccr
Citation
Coordination Chemistry Reviews, 2005, v. 249 n. 13-14, p. 1351-1359 How to Cite?
AbstractA series of poly(p-phenylenevinylene)s that contain chlorotricarbonyl bis(phenylimino)acenaphthene rhenium(I) complexes on the conjugated main chain was synthesized by the palladium catalyzed coupling reaction. The chloride ligand could be displaced by the iodide generated in situ during the polymerization reaction. The ligand displacement reaction was studied by synthesizing two model compounds, whose structures were confirmed by X-ray crystallography. The metal content in the polymers could be adjusted by varying the monomer feed ratio in the polymerization. The photosensitizing properties of these metal-containing polymers were studied, and it was found that the photocurrent response was dependent on the metal content in the polymers. Multilayered photovoltaic devices were fabricated, and their properties were studied by irradiation with simulated solar light. Typical power conversion efficiencies for these devices were measured to be 0.06%, with a fill factor of approximately 0.2. © 2004 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/69827
ISSN
2015 Impact Factor: 12.994
2015 SCImago Journal Rankings: 4.100
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorWai, KCen_HK
dc.contributor.authorHui, CSen_HK
dc.contributor.authorMan, KYKen_HK
dc.contributor.authorKai, WCen_HK
dc.contributor.authorHei, LWen_HK
dc.contributor.authorZhu, Nen_HK
dc.contributor.authorDjurišić, ABen_HK
dc.date.accessioned2010-09-06T06:17:12Z-
dc.date.available2010-09-06T06:17:12Z-
dc.date.issued2005en_HK
dc.identifier.citationCoordination Chemistry Reviews, 2005, v. 249 n. 13-14, p. 1351-1359en_HK
dc.identifier.issn0010-8545en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69827-
dc.description.abstractA series of poly(p-phenylenevinylene)s that contain chlorotricarbonyl bis(phenylimino)acenaphthene rhenium(I) complexes on the conjugated main chain was synthesized by the palladium catalyzed coupling reaction. The chloride ligand could be displaced by the iodide generated in situ during the polymerization reaction. The ligand displacement reaction was studied by synthesizing two model compounds, whose structures were confirmed by X-ray crystallography. The metal content in the polymers could be adjusted by varying the monomer feed ratio in the polymerization. The photosensitizing properties of these metal-containing polymers were studied, and it was found that the photocurrent response was dependent on the metal content in the polymers. Multilayered photovoltaic devices were fabricated, and their properties were studied by irradiation with simulated solar light. Typical power conversion efficiencies for these devices were measured to be 0.06%, with a fill factor of approximately 0.2. © 2004 Elsevier B.V. All rights reserved.en_HK
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ccren_HK
dc.relation.ispartofCoordination Chemistry Reviewsen_HK
dc.rightsCoordination Chemistry Reviews. Copyright © Elsevier BV.en_HK
dc.subjectConjugated polymersen_HK
dc.subjectPhotovoltaicen_HK
dc.subjectRheniumen_HK
dc.titleSynthesis and photosensitizing properties of conjugated polymers that contain chlorotricarbonyl bis(phenylimino)acenaphthene rhenium(I) complexesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0010-8545&volume=249&spage=1351&epage=1359&date=2005&atitle=Synthesis+and+photosensitizing+properties+of+conjugated+polymers+that+contain+chlorotricarbonyl+bis(phenylimino)acenaphthene+rhenium(I)+complexesen_HK
dc.identifier.emailWai, KC: waichan@hku.hken_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.emailDjurišić, AB: dalek@hku.hken_HK
dc.identifier.authorityWai, KC=rp00667en_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.identifier.authorityDjurišić, AB=rp00690en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.ccr.2004.10.006en_HK
dc.identifier.scopuseid_2-s2.0-23044450760en_HK
dc.identifier.hkuros99302en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-23044450760&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume249en_HK
dc.identifier.issue13-14en_HK
dc.identifier.spage1351en_HK
dc.identifier.epage1359en_HK
dc.identifier.isiWOS:000231398600007-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridWai, KC=13310083000en_HK
dc.identifier.scopusauthoridHui, CS=7202876912en_HK
dc.identifier.scopusauthoridMan, KYK=8051698900en_HK
dc.identifier.scopusauthoridKai, WC=8682616000en_HK
dc.identifier.scopusauthoridHei, LW=8682616100en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK
dc.identifier.scopusauthoridDjurišić, AB=7004904830en_HK

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