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Article: Novel manganese complex as an efficient catalyst for the isobutyraldehyde-mediated epoxidation of cyclic alkenes with dioxygen

TitleNovel manganese complex as an efficient catalyst for the isobutyraldehyde-mediated epoxidation of cyclic alkenes with dioxygen
Authors
KeywordsCyclic alkene
Dioxygen
Epoxidation
Manganese complex
N,O ligands
Issue Date2005
PublisherWiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.wiley.com/bw/journal.asp?ref=1615-4150
Citation
Advanced Synthesis And Catalysis, 2005, v. 347 n. 1, p. 45-49 How to Cite?
AbstractThe highly efficient oxidation of cyclic alkenes was realized using a novel manganese complex as catalyst and molecular oxygen as oxidant in the presence of isobutyraldehyde. The reaction of 2-pyridinecarboxylic acid with p-toluidine gave the corresponding amide in good yield. A manganese complex bearing this ligand was highly active in isobutyraldehyde-mediated epoxidation of cyclic alkenes using molecular oxygen as oxidant, and up to and over 99.9% conversion of the substrate and 99% yield of the epoxide were obtained for the epoxidation of norbornylene. © 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Persistent Identifierhttp://hdl.handle.net/10722/69826
ISSN
2015 Impact Factor: 6.453
2015 SCImago Journal Rankings: 2.729
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorQi, JYen_HK
dc.contributor.authorLi, YMen_HK
dc.contributor.authorZhou, ZYen_HK
dc.contributor.authorChe, CMen_HK
dc.contributor.authorYeung, CHen_HK
dc.contributor.authorChan, ASCen_HK
dc.date.accessioned2010-09-06T06:17:11Z-
dc.date.available2010-09-06T06:17:11Z-
dc.date.issued2005en_HK
dc.identifier.citationAdvanced Synthesis And Catalysis, 2005, v. 347 n. 1, p. 45-49en_HK
dc.identifier.issn1615-4150en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69826-
dc.description.abstractThe highly efficient oxidation of cyclic alkenes was realized using a novel manganese complex as catalyst and molecular oxygen as oxidant in the presence of isobutyraldehyde. The reaction of 2-pyridinecarboxylic acid with p-toluidine gave the corresponding amide in good yield. A manganese complex bearing this ligand was highly active in isobutyraldehyde-mediated epoxidation of cyclic alkenes using molecular oxygen as oxidant, and up to and over 99.9% conversion of the substrate and 99% yield of the epoxide were obtained for the epoxidation of norbornylene. © 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en_HK
dc.languageengen_HK
dc.publisherWiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.wiley.com/bw/journal.asp?ref=1615-4150en_HK
dc.relation.ispartofAdvanced Synthesis and Catalysisen_HK
dc.subjectCyclic alkeneen_HK
dc.subjectDioxygenen_HK
dc.subjectEpoxidationen_HK
dc.subjectManganese complexen_HK
dc.subjectN,O ligandsen_HK
dc.titleNovel manganese complex as an efficient catalyst for the isobutyraldehyde-mediated epoxidation of cyclic alkenes with dioxygenen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1615-4150&volume=347&spage=45&epage=49&date=2005&atitle=Novel+manganese+complex+as+an+efficient+catalyst+for+the+isobutyraldehyde-mediated+epoxidation+of+cyclic+alkenes+with+dioxygenen_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/adsc.200404224en_HK
dc.identifier.scopuseid_2-s2.0-14644407422en_HK
dc.identifier.hkuros105839en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-14644407422&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume347en_HK
dc.identifier.issue1en_HK
dc.identifier.spage45en_HK
dc.identifier.epage49en_HK
dc.identifier.isiWOS:000226776100004-
dc.publisher.placeGermanyen_HK
dc.identifier.scopusauthoridQi, JY=7201522090en_HK
dc.identifier.scopusauthoridLi, YM=26021357200en_HK
dc.identifier.scopusauthoridZhou, ZY=7406096262en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.scopusauthoridYeung, CH=7201354141en_HK
dc.identifier.scopusauthoridChan, ASC=7403168230en_HK

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