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Article: Pd(II)-catalyzed enantioselective oxidative tandem cyclization reactions. Synthesis of indolines through C-N and C-C bond formation

TitlePd(II)-catalyzed enantioselective oxidative tandem cyclization reactions. Synthesis of indolines through C-N and C-C bond formation
Authors
Yip, KTYang, MLaw, KLZhu, NYYang, D
Issue Date2006
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.html
Citation
Journal Of The American Chemical Society, 2006, v. 128 n. 10, p. 3130-3131 How to Cite?
DOI: http://dx.doi.org/10.1021/ja060291x
AbstractWe have developed an efficient Pd(II)-catalyzed enantioselective oxidative tandem cyclization strategy using molecular oxygen as a green oxidant for the double 5-exo-trig cyclizations of N-(2-allylaryl) amides to afford a variety of indolines in good yields without the formation of undesired monocyclization products. By employing Pd(TFA) 2/(-)-sparteine as the chiral catalyst, we obtained tandem cyclization products with high enantioselectivity (up to 91% ee). Copyright © 2006 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/69822
ISSN
0002-7863
2023 Impact Factor: 14.4
2023 SCImago Journal Rankings: 5.489
ISI Accession Number ID
WOS:000236035100012
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorYip, KTen_HK
dc.contributor.authorYang, Men_HK
dc.contributor.authorLaw, KLen_HK
dc.contributor.authorZhu, NYen_HK
dc.contributor.authorYang, Den_HK
dc.date.accessioned2010-09-06T06:17:09Z-
dc.date.available2010-09-06T06:17:09Z-
dc.date.issued2006en_HK
dc.identifier.citationJournal Of The American Chemical Society, 2006, v. 128 n. 10, p. 3130-3131en_HK
dc.identifier.issn0002-7863en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69822-
dc.description.abstractWe have developed an efficient Pd(II)-catalyzed enantioselective oxidative tandem cyclization strategy using molecular oxygen as a green oxidant for the double 5-exo-trig cyclizations of N-(2-allylaryl) amides to afford a variety of indolines in good yields without the formation of undesired monocyclization products. By employing Pd(TFA) 2/(-)-sparteine as the chiral catalyst, we obtained tandem cyclization products with high enantioselectivity (up to 91% ee). Copyright © 2006 American Chemical Society.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.htmlen_HK
dc.relation.ispartofJournal of the American Chemical Societyen_HK
dc.titlePd(II)-catalyzed enantioselective oxidative tandem cyclization reactions. Synthesis of indolines through C-N and C-C bond formationen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0002-7863&volume=128&spage=3130&epage=3131&date=2006&atitle=Pd(II)-catalyzed+enantioselective+oxidative+tandem+cyclization+reactions.+Synthesis+of+Indolines+through+C-N+and+C-C+bond+formationen_HK
dc.identifier.emailYip, KT: billyyip@graduate.hku.hken_HK
dc.identifier.emailZhu, NY: nzhu@hkucc.hku.hken_HK
dc.identifier.emailYang, D: yangdan@hku.hken_HK
dc.identifier.authorityYip, KT=rp00832en_HK
dc.identifier.authorityZhu, NY=rp00845en_HK
dc.identifier.authorityYang, D=rp00825en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ja060291xen_HK
dc.identifier.pmid16522078-
dc.identifier.scopuseid_2-s2.0-33644933443en_HK
dc.identifier.hkuros117567en_HK
dc.identifier.hkuros148575-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-33644933443&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume128en_HK
dc.identifier.issue10en_HK
dc.identifier.spage3130en_HK
dc.identifier.epage3131en_HK
dc.identifier.isiWOS:000236035100012-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridYip, KT=10440172200en_HK
dc.identifier.scopusauthoridYang, M=8984637400en_HK
dc.identifier.scopusauthoridLaw, KL=7202563094en_HK
dc.identifier.scopusauthoridZhu, NY=7201449530en_HK
dc.identifier.scopusauthoridYang, D=7404800756en_HK
dc.identifier.issnl0002-7863-

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