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Article: Chiral zinc(II) bipyridine complex. Crystal structure and catalytic activity in asymmetric allylation reaction
Title | Chiral zinc(II) bipyridine complex. Crystal structure and catalytic activity in asymmetric allylation reaction |
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Authors | |
Issue Date | 1999 |
Publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/njc |
Citation | New Journal Of Chemistry, 1999, v. 23 n. 6, p. 629-632 How to Cite? |
Abstract | A chiral bipyridine zinc(II) complex, Zn(L)Cl2 (L = chiral bipyridine), has been prepared and characterized by usual spectroscopic means and X-ray crystallography. Reaction of Zn(L)Cl2 with AgCF3SO3 gave Zn(L)(CF3SO3)2 in situ; this complex is an active catalyst for allylation of aldehydes with enantiomeric excesses up to 60%. |
Persistent Identifier | http://hdl.handle.net/10722/69813 |
ISSN | 2023 Impact Factor: 2.7 2023 SCImago Journal Rankings: 0.521 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
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dc.contributor.author | Kwong, HL | en_HK |
dc.contributor.author | Lau, KM | en_HK |
dc.contributor.author | Lee, WS | en_HK |
dc.contributor.author | Wong, WT | en_HK |
dc.date.accessioned | 2010-09-06T06:17:04Z | - |
dc.date.available | 2010-09-06T06:17:04Z | - |
dc.date.issued | 1999 | en_HK |
dc.identifier.citation | New Journal Of Chemistry, 1999, v. 23 n. 6, p. 629-632 | en_HK |
dc.identifier.issn | 1144-0546 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/69813 | - |
dc.description.abstract | A chiral bipyridine zinc(II) complex, Zn(L)Cl2 (L = chiral bipyridine), has been prepared and characterized by usual spectroscopic means and X-ray crystallography. Reaction of Zn(L)Cl2 with AgCF3SO3 gave Zn(L)(CF3SO3)2 in situ; this complex is an active catalyst for allylation of aldehydes with enantiomeric excesses up to 60%. | en_HK |
dc.language | eng | en_HK |
dc.publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/njc | en_HK |
dc.relation.ispartof | New Journal of Chemistry | en_HK |
dc.title | Chiral zinc(II) bipyridine complex. Crystal structure and catalytic activity in asymmetric allylation reaction | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1144-0546&volume=23&spage=629&epage=632&date=1999&atitle=Chiral+zinc(II)+bipyridine+complex.++Crystal+structure+and+catalytic+activity+in+asymmetric+allylation+reaction | en_HK |
dc.identifier.email | Wong, WT: wtwong@hku.hk | en_HK |
dc.identifier.authority | Wong, WT=rp00811 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1039/a902177i | en_HK |
dc.identifier.scopus | eid_2-s2.0-0032813641 | en_HK |
dc.identifier.hkuros | 45441 | en_HK |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0032813641&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 23 | en_HK |
dc.identifier.issue | 6 | en_HK |
dc.identifier.spage | 629 | en_HK |
dc.identifier.epage | 632 | en_HK |
dc.identifier.isi | WOS:000080800000012 | - |
dc.publisher.place | United Kingdom | en_HK |
dc.identifier.scopusauthorid | Kwong, HL=35569416300 | en_HK |
dc.identifier.scopusauthorid | Lau, KM=7401560048 | en_HK |
dc.identifier.scopusauthorid | Lee, WS=7407089119 | en_HK |
dc.identifier.scopusauthorid | Wong, WT=7403973084 | en_HK |
dc.identifier.issnl | 1144-0546 | - |