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Article: A novel route to titanium compounds containing cyclopentadienyl ligands with bromoethyl substituents; molecular structure of [(η5-C5H4CH2CH2Br)TiBr(µ-O)]4

TitleA novel route to titanium compounds containing cyclopentadienyl ligands with bromoethyl substituents; molecular structure of [(η5-C5H4CH2CH2Br)TiBr(µ-O)]4
Authors
KeywordsTitanium
Bromoethyl
Cyclopentadienyl
Crystal structures
Issue Date1999
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/inoche
Citation
Inorganic Chemistry Communications, 1999, v. 2 n. 9, p. 396-398 How to Cite?
AbstractCompounds (η5-C5H4CH2CH2OCH3)TiCl3, (η5-C5H4CH2CH2OCH3)2TiCl2 and (η5-C5H4CH2CH2OCH3)(η5-C5H5)TiCl2 react with BBr3 to give a high yield of titanium compounds containing cyclopentadienyl ligands with bromoethyl substituents, (η5-C5H4CH2CH2Br)TiBr3 (1), (η5-C5H4CH2CH2Br)2TiBr2 (3) and (η5-C5H4CH2CH2Br)(η5-C5H5)TiBr2 (4), respectively. Hydrolysis of 1 in the presence of tert-butylamine affords cyclo-[(η5-C5H4CH2CH2Br)TiBr(μ-O)]4 (2) in quantitative yield. The molecular structure of 2 was determined by X-ray diffraction.
Persistent Identifierhttp://hdl.handle.net/10722/69797
ISSN
2015 Impact Factor: 1.762
2015 SCImago Journal Rankings: 0.489
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorZheng, Len_HK
dc.contributor.authorHuang, Jen_HK
dc.contributor.authorQian, Yen_HK
dc.contributor.authorChan, ASCen_HK
dc.contributor.authorLeung, KSYen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:16:56Z-
dc.date.available2010-09-06T06:16:56Z-
dc.date.issued1999en_HK
dc.identifier.citationInorganic Chemistry Communications, 1999, v. 2 n. 9, p. 396-398en_HK
dc.identifier.issn1387-7003en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69797-
dc.description.abstractCompounds (η5-C5H4CH2CH2OCH3)TiCl3, (η5-C5H4CH2CH2OCH3)2TiCl2 and (η5-C5H4CH2CH2OCH3)(η5-C5H5)TiCl2 react with BBr3 to give a high yield of titanium compounds containing cyclopentadienyl ligands with bromoethyl substituents, (η5-C5H4CH2CH2Br)TiBr3 (1), (η5-C5H4CH2CH2Br)2TiBr2 (3) and (η5-C5H4CH2CH2Br)(η5-C5H5)TiBr2 (4), respectively. Hydrolysis of 1 in the presence of tert-butylamine affords cyclo-[(η5-C5H4CH2CH2Br)TiBr(μ-O)]4 (2) in quantitative yield. The molecular structure of 2 was determined by X-ray diffraction.-
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/inocheen_HK
dc.relation.ispartofInorganic Chemistry Communicationsen_HK
dc.rightsInorganic Chemistry Communications. Copyright © Elsevier BV.en_HK
dc.subjectTitanium-
dc.subjectBromoethyl-
dc.subjectCyclopentadienyl-
dc.subjectCrystal structures-
dc.titleA novel route to titanium compounds containing cyclopentadienyl ligands with bromoethyl substituents; molecular structure of [(η5-C5H4CH2CH2Br)TiBr(µ-O)]4en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1387-7003&volume=2&spage=396&epage=398&date=1999&atitle=A+novel+route+to+titanium+compounds+containing+cyclopentadienyl+ligands+with+bromoethyl+substituents;+molecular+structure+of+[(h5-C5H4CH2CH2Br)TiBr(m-O)]4en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1016/S1387-7003(99)00103-3-
dc.identifier.hkuros53654en_HK
dc.identifier.volume2-
dc.identifier.issue9-
dc.identifier.spage396-
dc.identifier.epage398-
dc.identifier.isiWOS:000083162600005-
dc.publisher.placeNetherlands-

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