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Article: A further test of the Boublik et al. equations for binary hard sphere mixtures

TitleA further test of the Boublik et al. equations for binary hard sphere mixtures
Authors
Issue Date1996
PublisherTaylor & Francis Ltd. The Journal's web site is located at http://www.tandf.co.uk/journals/titles/00268976.asp
Citation
Molecular Physics, 1996, v. 88 n. 5, p. 1237-1248 How to Cite?
AbstractThe Boublik-Mansoori-Carnahan-Starling-Leland (BMCSL) equation of state is examined for binary hard sphere mixtures. It is argued that this equation of state is reliable for a large diameter ratio. Monte Carlo (MC) simulations are performed for many states, some of high density and large diameter ratio. At moderate densities away from the solid-liquid transition, the MC results show reasonably good agreement with the BMCSL's prediction of the compressibility factor. This confirms the earlier findings of Jackson et al. for the validity of BMCSL in the liquid phase. The failure of the BMCSL prediction in some states is due to proximity to the solid-liquid transition and not due to the large diameter ratio. The individual pair distribution functions predicted by the BMCSL in all cases, however, can be poor, especially, for a pair of large spheres at very low concentration. Comparison of the MC distribution functions and those predicted by several theories are made.
Persistent Identifierhttp://hdl.handle.net/10722/69762
ISSN
2015 Impact Factor: 1.837
2015 SCImago Journal Rankings: 0.781
References

 

DC FieldValueLanguage
dc.contributor.authorYau, DHLen_HK
dc.contributor.authorChan, KYen_HK
dc.contributor.authorHenderson, Den_HK
dc.date.accessioned2010-09-06T06:16:36Z-
dc.date.available2010-09-06T06:16:36Z-
dc.date.issued1996en_HK
dc.identifier.citationMolecular Physics, 1996, v. 88 n. 5, p. 1237-1248en_HK
dc.identifier.issn0026-8976en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69762-
dc.description.abstractThe Boublik-Mansoori-Carnahan-Starling-Leland (BMCSL) equation of state is examined for binary hard sphere mixtures. It is argued that this equation of state is reliable for a large diameter ratio. Monte Carlo (MC) simulations are performed for many states, some of high density and large diameter ratio. At moderate densities away from the solid-liquid transition, the MC results show reasonably good agreement with the BMCSL's prediction of the compressibility factor. This confirms the earlier findings of Jackson et al. for the validity of BMCSL in the liquid phase. The failure of the BMCSL prediction in some states is due to proximity to the solid-liquid transition and not due to the large diameter ratio. The individual pair distribution functions predicted by the BMCSL in all cases, however, can be poor, especially, for a pair of large spheres at very low concentration. Comparison of the MC distribution functions and those predicted by several theories are made.en_HK
dc.languageengen_HK
dc.publisherTaylor & Francis Ltd. The Journal's web site is located at http://www.tandf.co.uk/journals/titles/00268976.aspen_HK
dc.relation.ispartofMolecular Physicsen_HK
dc.titleA further test of the Boublik et al. equations for binary hard sphere mixturesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0026-8976&volume=88&issue=5&spage=1237&epage=1248&date=1996&atitle=A+further+test+of+the+Boublik+et+al.+equations+for+binary+hard+sphere+mixturesen_HK
dc.identifier.emailChan, KY:hrsccky@hku.hken_HK
dc.identifier.authorityChan, KY=rp00662en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.scopuseid_2-s2.0-2542620056en_HK
dc.identifier.hkuros21640en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-2542620056&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume88en_HK
dc.identifier.issue5en_HK
dc.identifier.spage1237en_HK
dc.identifier.epage1248en_HK
dc.publisher.placeUnited Kingdomen_HK
dc.identifier.scopusauthoridYau, DHL=7004652273en_HK
dc.identifier.scopusauthoridChan, KY=7406034142en_HK
dc.identifier.scopusauthoridHenderson, D=7402988756en_HK

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