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Article: Luminescent polynuclear metal acetylides

TitleLuminescent polynuclear metal acetylides
Authors
KeywordsAcetylides
Copper(I)
Gold(I)
Luminescence
Photoredox
Platinum(II)
Rhenium(I)
Silver(I)
Issue Date1999
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem
Citation
Journal Of Organometallic Chemistry, 1999, v. 578 n. 1-2, p. 3-30 How to Cite?
AbstractThe photophysical and photochemical studies of polynuclear copper(I), silver(I), gold(I), rhenium(I) and platinum(II) acetylide complexes are reviewed. Based on the highly flexible bonding modes of the acetylides and the various coordination geometry of these metal centres, a number of polynuclear copper(I), silver(I), gold(I), rhenium(I) and platinum(II) acetylide complexes with very different molecular structures have been synthesized and characterized. These organometallic complexes also exhibit rich and remarkable photophysical and photochemical properties which are unique to the presence of the acetylide ligand. The fundamental understanding on the photophysical and photochemical properties of these luminescent organometallic complexes would lead to the production of novel luminescent materials and represent model systems in the development of light-emitting diodes, new materials with non-linear optical properties and liquid crystalline properties. In this review article, particular attention is focused on the electronic absorption spectroscopy, photoluminescence behaviour, excited-state assignments and photochemical properties of this class of luminescent acetylide complexes. © 1999 Elsevier Science S.A. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/69753
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_HK
dc.contributor.authorLo, KKWen_HK
dc.contributor.authorWong, KMCen_HK
dc.date.accessioned2010-09-06T06:16:31Z-
dc.date.available2010-09-06T06:16:31Z-
dc.date.issued1999en_HK
dc.identifier.citationJournal Of Organometallic Chemistry, 1999, v. 578 n. 1-2, p. 3-30en_HK
dc.identifier.issn0022-328Xen_HK
dc.identifier.urihttp://hdl.handle.net/10722/69753-
dc.description.abstractThe photophysical and photochemical studies of polynuclear copper(I), silver(I), gold(I), rhenium(I) and platinum(II) acetylide complexes are reviewed. Based on the highly flexible bonding modes of the acetylides and the various coordination geometry of these metal centres, a number of polynuclear copper(I), silver(I), gold(I), rhenium(I) and platinum(II) acetylide complexes with very different molecular structures have been synthesized and characterized. These organometallic complexes also exhibit rich and remarkable photophysical and photochemical properties which are unique to the presence of the acetylide ligand. The fundamental understanding on the photophysical and photochemical properties of these luminescent organometallic complexes would lead to the production of novel luminescent materials and represent model systems in the development of light-emitting diodes, new materials with non-linear optical properties and liquid crystalline properties. In this review article, particular attention is focused on the electronic absorption spectroscopy, photoluminescence behaviour, excited-state assignments and photochemical properties of this class of luminescent acetylide complexes. © 1999 Elsevier Science S.A. All rights reserved.en_HK
dc.languageengen_HK
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchemen_HK
dc.relation.ispartofJournal of Organometallic Chemistryen_HK
dc.subjectAcetylidesen_HK
dc.subjectCopper(I)en_HK
dc.subjectGold(I)en_HK
dc.subjectLuminescenceen_HK
dc.subjectPhotoredoxen_HK
dc.subjectPlatinum(II)en_HK
dc.subjectRhenium(I)en_HK
dc.subjectSilver(I)en_HK
dc.titleLuminescent polynuclear metal acetylidesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-328X&volume=578&spage=3&epage=30&date=1999&atitle=Luminescent+polynuclear+metal+acetylidesen_HK
dc.identifier.emailYam, VWW:wwyam@hku.hken_HK
dc.identifier.emailWong, KMC:wongmc@hku.hken_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.identifier.authorityWong, KMC=rp00809en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0022-328X(98)01106-1-
dc.identifier.scopuseid_2-s2.0-0003120297en_HK
dc.identifier.hkuros43440en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0003120297&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume578en_HK
dc.identifier.issue1-2en_HK
dc.identifier.spage3en_HK
dc.identifier.epage30en_HK
dc.identifier.isiWOS:000080412600002-
dc.publisher.placeSwitzerlanden_HK
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK
dc.identifier.scopusauthoridLo, KKW=26032181200en_HK
dc.identifier.scopusauthoridWong, KMC=8061067200en_HK

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