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- Publisher Website: 10.1002/1099-0682(200102)2001:2<511::AID-EJIC511>3.0.CO;2-U
- Scopus: eid_2-s2.0-0035144622
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Article: Synthesis, Characterisation and Electrochemical Behaviour of Rhodium(III) Complexes Containing 1,2-Naphthoquinone-2-oxime and Formation of Imine Complexes through N-O Bond Cleavage
| Title | Synthesis, Characterisation and Electrochemical Behaviour of Rhodium(III) Complexes Containing 1,2-Naphthoquinone-2-oxime and Formation of Imine Complexes through N-O Bond Cleavage |
|---|---|
| Authors | |
| Keywords | Rhodium N ligands Electrochemistry |
| Issue Date | 2001 |
| Publisher | Wiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.eurjic.org |
| Citation | European Journal of Inorganic Chemistry, 2001, v. 2001 n. 2, p. 511-520 How to Cite? |
| Abstract | The new rhodium(III) complexes [Rh(η2-nqo)L2Cl2] (1a−1d) and [Rh(η2-nqo)2LCl] (2b−2d) [1a, L = PPh3; 1b,2b, L = pyridine (py); 1c,2c, L = 4-phenylpyridine (ppy); 1d,2d, L = 4-acetylpyridine (apy)] have been prepared by treatment of the reaction mixture of RhCl3·3H2O and 1,2-naphthoquinone-2-oxime (nqo) in ethanol by P or N donor ligands. Cyclic voltammetric studies show that the new complexes display an irreversible metal-localised two-electron reduction from RhIII to RhI, accompanied by the loss of the chloride ligands. The 1,2-naphthoquinone-2-imine (nqi) complexes [Rh(η2-nqo)(η2-nqi)Cl2]·L (3b−3d) (3b, L = py; 3c, L = ppy; 3d, L = apy), [Rh(η2-nqo)(η2-nqi)Cl2] (4) and [Rh(η2-nqo)2(nqi)Cl] (5) were obtained by deoxygenation of the oxime group in which N−O bond cleavage is observed. The molecular structures of 1a, 2b, 4 and 5 were established by single crystal X-ray analyses. |
| Persistent Identifier | http://hdl.handle.net/10722/69734 |
| ISSN | 2023 Impact Factor: 2.2 2023 SCImago Journal Rankings: 0.481 |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Liu, XX | en_HK |
| dc.contributor.author | Wong, WT | en_HK |
| dc.date.accessioned | 2010-09-06T06:16:21Z | - |
| dc.date.available | 2010-09-06T06:16:21Z | - |
| dc.date.issued | 2001 | en_HK |
| dc.identifier.citation | European Journal of Inorganic Chemistry, 2001, v. 2001 n. 2, p. 511-520 | en_HK |
| dc.identifier.issn | 1434-1948 | en_HK |
| dc.identifier.uri | http://hdl.handle.net/10722/69734 | - |
| dc.description.abstract | The new rhodium(III) complexes [Rh(η2-nqo)L2Cl2] (1a−1d) and [Rh(η2-nqo)2LCl] (2b−2d) [1a, L = PPh3; 1b,2b, L = pyridine (py); 1c,2c, L = 4-phenylpyridine (ppy); 1d,2d, L = 4-acetylpyridine (apy)] have been prepared by treatment of the reaction mixture of RhCl3·3H2O and 1,2-naphthoquinone-2-oxime (nqo) in ethanol by P or N donor ligands. Cyclic voltammetric studies show that the new complexes display an irreversible metal-localised two-electron reduction from RhIII to RhI, accompanied by the loss of the chloride ligands. The 1,2-naphthoquinone-2-imine (nqi) complexes [Rh(η2-nqo)(η2-nqi)Cl2]·L (3b−3d) (3b, L = py; 3c, L = ppy; 3d, L = apy), [Rh(η2-nqo)(η2-nqi)Cl2] (4) and [Rh(η2-nqo)2(nqi)Cl] (5) were obtained by deoxygenation of the oxime group in which N−O bond cleavage is observed. The molecular structures of 1a, 2b, 4 and 5 were established by single crystal X-ray analyses. | - |
| dc.language | eng | en_HK |
| dc.publisher | Wiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.eurjic.org | en_HK |
| dc.relation.ispartof | European Journal of Inorganic Chemistry | en_HK |
| dc.subject | Rhodium | - |
| dc.subject | N ligands | - |
| dc.subject | Electrochemistry | - |
| dc.title | Synthesis, Characterisation and Electrochemical Behaviour of Rhodium(III) Complexes Containing 1,2-Naphthoquinone-2-oxime and Formation of Imine Complexes through N-O Bond Cleavage | en_HK |
| dc.type | Article | en_HK |
| dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1434-1948&volume=&spage=511&epage=520&date=2001&atitle=Synthesis,+Characterisation+and+Electrochemical+Behaviour+of+Rhodium(III)+Complexes+Containing+1,2-Naphthoquinone-2-oxime+and+Formation+of+Imine+Complexes+through+N-O+Bond+Cleavage | en_HK |
| dc.identifier.email | Wong, WT: wtwong@hku.hk | en_HK |
| dc.identifier.authority | Wong, WT=rp00811 | en_HK |
| dc.identifier.doi | 10.1002/1099-0682(200102)2001:2<511::AID-EJIC511>3.0.CO;2-U | - |
| dc.identifier.scopus | eid_2-s2.0-0035144622 | - |
| dc.identifier.hkuros | 56705 | en_HK |
| dc.identifier.volume | 2001 | - |
| dc.identifier.issue | 2 | - |
| dc.identifier.spage | 511 | - |
| dc.identifier.epage | 520 | - |
| dc.publisher.place | Germany | - |
| dc.identifier.issnl | 1434-1948 | - |