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Article: Short-time photodissociation dynamics of chloroiodomethane in solution from resonance Raman spectroscopy

TitleShort-time photodissociation dynamics of chloroiodomethane in solution from resonance Raman spectroscopy
Authors
Issue Date1995
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett
Citation
Chemical Physics Letters, 1995, v. 241 n. 4, p. 267-274 How to Cite?
AbstractResonance Raman and preresonance Raman spectra of chloroiodomethane in cyclohexane solution have been obtained at excitation wavelengths of 282, 309, 320, 342, 355, and 532 nm. The 282 nm spectrum is in resonance with the directly dissociative A-state absorption band of chloroiodomethane. We observe a large degree of Raman intensity in the C-1 stretch overtone progression as well as combination bands of the C-Cl stretch mode with the C-1 stretch overtones indicating that most of the initial photodissociation dynamics in the Franck-Condon region involves the C-1 stretch motion as well as some C-Cl stretch motion. © 1995.
Persistent Identifierhttp://hdl.handle.net/10722/69728
ISSN
2015 Impact Factor: 1.86
2015 SCImago Journal Rankings: 0.757
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorPhillips, DLen_HK
dc.contributor.authorWai Ming Kwoken_HK
dc.date.accessioned2010-09-06T06:16:18Z-
dc.date.available2010-09-06T06:16:18Z-
dc.date.issued1995en_HK
dc.identifier.citationChemical Physics Letters, 1995, v. 241 n. 4, p. 267-274en_HK
dc.identifier.issn0009-2614en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69728-
dc.description.abstractResonance Raman and preresonance Raman spectra of chloroiodomethane in cyclohexane solution have been obtained at excitation wavelengths of 282, 309, 320, 342, 355, and 532 nm. The 282 nm spectrum is in resonance with the directly dissociative A-state absorption band of chloroiodomethane. We observe a large degree of Raman intensity in the C-1 stretch overtone progression as well as combination bands of the C-Cl stretch mode with the C-1 stretch overtones indicating that most of the initial photodissociation dynamics in the Franck-Condon region involves the C-1 stretch motion as well as some C-Cl stretch motion. © 1995.en_HK
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cpletten_HK
dc.relation.ispartofChemical Physics Lettersen_HK
dc.rightsChemical Physics Letters. Copyright © Elsevier BV.en_HK
dc.titleShort-time photodissociation dynamics of chloroiodomethane in solution from resonance Raman spectroscopyen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0009-2614&volume=241&spage=267&epage=274&date=1995&atitle=Short+time+photodissociation+dynamics+of+chloroiodomethane+in+solution+from+resonance+Raman+spectroscopyen_HK
dc.identifier.emailPhillips, DL:phillips@hku.hken_HK
dc.identifier.authorityPhillips, DL=rp00770en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/0009-2614(95)00594-T-
dc.identifier.scopuseid_2-s2.0-0038909420en_HK
dc.identifier.hkuros8610en_HK
dc.identifier.volume241en_HK
dc.identifier.issue4en_HK
dc.identifier.spage267en_HK
dc.identifier.epage274en_HK
dc.identifier.isiWOS:A1995RL96600001-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridPhillips, DL=7404519365en_HK
dc.identifier.scopusauthoridWai Ming Kwok=35299981100en_HK

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