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Article: A novel, highly electrical conducting, single-component molecular material: [Ag2(ophen)2] (Hophen = 1H-[1,10]phenanthrolin-2-one)

TitleA novel, highly electrical conducting, single-component molecular material: [Ag2(ophen)2] (Hophen = 1H-[1,10]phenanthrolin-2-one)
Authors
Issue Date2003
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.html
Citation
Journal Of The American Chemical Society, 2003, v. 125 n. 23, p. 6882-6883 How to Cite?
AbstractThis communication describes a highly conducting, single-component molecular material [Ag2(ophen)2] (Hophen = 1H-[1,10]phenanthrolin-2-one) based on very strong off-set π-π stacking interactions with an unusually short ring-to-ring distance of ca. 3.15 Å between adjacent molecules and silver(I)-π interactions with the Ag⋯C contact of 3.082 Å between adjacent molecules. The title compound, having a room-temperature conductivity of 14 S cm-1, is structurally different from both the known conducting single-component molecular materials of transition-metal complexes with sulfur-containing π-delocalized dithiolene ligands and the known conducting multicomponent organosilver(I) materials. Copyright © 2003 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/69725
ISSN
2015 Impact Factor: 13.038
2015 SCImago Journal Rankings: 7.123
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorZheng, SLen_HK
dc.contributor.authorZhang, JPen_HK
dc.contributor.authorWong, WTen_HK
dc.contributor.authorChen, XMen_HK
dc.date.accessioned2010-09-06T06:16:17Z-
dc.date.available2010-09-06T06:16:17Z-
dc.date.issued2003en_HK
dc.identifier.citationJournal Of The American Chemical Society, 2003, v. 125 n. 23, p. 6882-6883en_HK
dc.identifier.issn0002-7863en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69725-
dc.description.abstractThis communication describes a highly conducting, single-component molecular material [Ag2(ophen)2] (Hophen = 1H-[1,10]phenanthrolin-2-one) based on very strong off-set π-π stacking interactions with an unusually short ring-to-ring distance of ca. 3.15 Å between adjacent molecules and silver(I)-π interactions with the Ag⋯C contact of 3.082 Å between adjacent molecules. The title compound, having a room-temperature conductivity of 14 S cm-1, is structurally different from both the known conducting single-component molecular materials of transition-metal complexes with sulfur-containing π-delocalized dithiolene ligands and the known conducting multicomponent organosilver(I) materials. Copyright © 2003 American Chemical Society.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.htmlen_HK
dc.relation.ispartofJournal of the American Chemical Societyen_HK
dc.titleA novel, highly electrical conducting, single-component molecular material: [Ag2(ophen)2] (Hophen = 1H-[1,10]phenanthrolin-2-one)en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0002-7863&volume=125&issue=23&spage=6882&epage=6883&date=2003&atitle=A+novel,+highly+electrical+conducting,+single-component+molecular+material:+[Ag2(ophen)2]+(Hophen+=+1H-[1,10]phenanthrolin-2-one)en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ja029097aen_HK
dc.identifier.scopuseid_2-s2.0-0038277004en_HK
dc.identifier.hkuros82672en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0038277004&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume125en_HK
dc.identifier.issue23en_HK
dc.identifier.spage6882en_HK
dc.identifier.epage6883en_HK
dc.identifier.isiWOS:000183359300021-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridZheng, SL=7403146210en_HK
dc.identifier.scopusauthoridZhang, JP=12546226200en_HK
dc.identifier.scopusauthoridWong, WT=7403973084en_HK
dc.identifier.scopusauthoridChen, XM=36014536300en_HK

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