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Article: Trans-[OsIII(salen)(CN)2]-: A new paramagnetic building block for the construction of molecule-based magnetic materials

TitleTrans-[OsIII(salen)(CN)2]-: A new paramagnetic building block for the construction of molecule-based magnetic materials
Authors
Issue Date2010
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 2010, v. 49 n. 4, p. 1607-1614 How to Cite?
AbstractA novel dicyanoosmium(III) complex, trans-Ph4P[Os III(salen)(CN)2]* CH2Cl2 * H2O (1; Ph4 P+ = tetraphenylphosphonium cation, salen2-=N, N′-ethylenebis(salicylideneaminato) dianion), has been synthesized and structurally characterized. Reactions of 1 with [Cu(Me3tacn)(H2O)2](ClO4) 2 (Me3tacn=1, 4, 7-trimethyl-1, 4, 7-triazacyclononane) under different conditions produce the 1-D ferromagnetic zigzag chains [Os(salen)(CN)2]2[Cu(Me3tacn)] * CH 3OH (2) and [Os(salen)(CN)2][Cu(Me3tacn)] * ClO4 (3). © 2010 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/69723
ISSN
2014 Impact Factor: 4.762
2014 SCImago Journal Rankings: 1.681
ISI Accession Number ID
Funding AgencyGrant Number
National Natural Science Foundation of ChinaNSFC 20831160505
National Basic Research Program of China2009CB929403
Council of Hong Kong Joint Research SchemeN_CityU 107/08
City University of Hong KongSRG 7002319
Funding Information:

The work described in this paper wits supported by grants from the National Natural Science Foundation of China (NSFC 20831160505), the National Basic Research Program of China (2009CB929403), the Research Grants Council of Hong Kong Joint Research Scheme (N_CityU 107/08), and the City University of Hong Kong (SRG 7002319).

References

 

DC FieldValueLanguage
dc.contributor.authorGuo, JFen_HK
dc.contributor.authorYeung, WFen_HK
dc.contributor.authorLau, PHen_HK
dc.contributor.authorWang, XTen_HK
dc.contributor.authorGao, Sen_HK
dc.contributor.authorWong, WTen_HK
dc.contributor.authorChui, SSYen_HK
dc.contributor.authorChe, CMen_HK
dc.contributor.authorWong, WYen_HK
dc.contributor.authorLau, TCen_HK
dc.date.accessioned2010-09-06T06:16:15Z-
dc.date.available2010-09-06T06:16:15Z-
dc.date.issued2010en_HK
dc.identifier.citationInorganic Chemistry, 2010, v. 49 n. 4, p. 1607-1614en_HK
dc.identifier.issn0020-1669en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69723-
dc.description.abstractA novel dicyanoosmium(III) complex, trans-Ph4P[Os III(salen)(CN)2]* CH2Cl2 * H2O (1; Ph4 P+ = tetraphenylphosphonium cation, salen2-=N, N′-ethylenebis(salicylideneaminato) dianion), has been synthesized and structurally characterized. Reactions of 1 with [Cu(Me3tacn)(H2O)2](ClO4) 2 (Me3tacn=1, 4, 7-trimethyl-1, 4, 7-triazacyclononane) under different conditions produce the 1-D ferromagnetic zigzag chains [Os(salen)(CN)2]2[Cu(Me3tacn)] * CH 3OH (2) and [Os(salen)(CN)2][Cu(Me3tacn)] * ClO4 (3). © 2010 American Chemical Society.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/icen_HK
dc.relation.ispartofInorganic Chemistryen_HK
dc.titleTrans-[OsIII(salen)(CN)2]-: A new paramagnetic building block for the construction of molecule-based magnetic materialsen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0020-1669&volume=49&spage=1607&epage=1614&date=2010&atitle=trans-[OsIII(salen)(CN)2]__:+A+New+Paramagnetic+Building+Block+for+the+Construction+of+Molecule-Based+Magnetic+Materialsen_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.emailChui, SSY: chuissy@hkucc.hku.hken_HK
dc.identifier.emailChe, CM: cmche@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.authorityChui, SSY=rp00686en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ic9020178en_HK
dc.identifier.pmid20067236-
dc.identifier.scopuseid_2-s2.0-77249091300en_HK
dc.identifier.hkuros168984en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-77249091300&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume49en_HK
dc.identifier.issue4en_HK
dc.identifier.spage1607en_HK
dc.identifier.epage1614en_HK
dc.identifier.isiWOS:000274240700050-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridGuo, JF=8900778400en_HK
dc.identifier.scopusauthoridYeung, WF=7102370789en_HK
dc.identifier.scopusauthoridLau, PH=15921593400en_HK
dc.identifier.scopusauthoridWang, XT=23096076800en_HK
dc.identifier.scopusauthoridGao, S=7403257903en_HK
dc.identifier.scopusauthoridWong, WT=7403973084en_HK
dc.identifier.scopusauthoridChui, SSY=8297453100en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.scopusauthoridWong, WY=7403972153en_HK
dc.identifier.scopusauthoridLau, TC=7102222310en_HK

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