Article: Trans-[OsIII(salen)(CN)2]-: A new paramagnetic building block for the construction of molecule-based magnetic materials

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TitleTrans-[OsIII(salen)(CN)2]-: A new paramagnetic building block for the construction of molecule-based magnetic materials
AuthorsGuo, JF2
Yeung, WF2
Lau, PH2
Wang, XT4
Gao, S4
Wong, WT1
Chui, SSY1
Che, CM1
Wong, WY3
Lau, TC2
Issue Date2010
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
CitationInorganic Chemistry, 2010, v. 49 n. 4, p. 1607-1614 [How to Cite?]
DOI: http://dx.doi.org/10.1021/ic9020178
AbstractA novel dicyanoosmium(III) complex, trans-Ph4P[Os III(salen)(CN)2]* CH2Cl2 * H2O (1; Ph4 P+ = tetraphenylphosphonium cation, salen2-=N, N′-ethylenebis(salicylideneaminato) dianion), has been synthesized and structurally characterized. Reactions of 1 with [Cu(Me3tacn)(H2O)2](ClO4) 2 (Me3tacn=1, 4, 7-trimethyl-1, 4, 7-triazacyclononane) under different conditions produce the 1-D ferromagnetic zigzag chains [Os(salen)(CN)2]2[Cu(Me3tacn)] * CH 3OH (2) and [Os(salen)(CN)2][Cu(Me3tacn)] * ClO4 (3). © 2010 American Chemical Society.
ISSN0020-1669
2011 Impact Factor: 4.601
2011 SCImago Journal Rankings: 0.315
DOIhttp://dx.doi.org/10.1021/ic9020178
ReferencesReferences in Scopus
DC Field
Value
dc.contributor.authorGuo, JF
dc.contributor.authorYeung, WF
dc.contributor.authorLau, PH
dc.contributor.authorWang, XT
dc.contributor.authorGao, S
dc.contributor.authorWong, WT
dc.contributor.authorChui, SSY
dc.contributor.authorChe, CM
dc.contributor.authorWong, WY
dc.contributor.authorLau, TC
dc.date.accessioned2010-09-06T06:16:15Z
dc.date.available2010-09-06T06:16:15Z
dc.date.issued2010
dc.description.abstractA novel dicyanoosmium(III) complex, trans-Ph4P[Os III(salen)(CN)2]* CH2Cl2 * H2O (1; Ph4 P+ = tetraphenylphosphonium cation, salen2-=N, N′-ethylenebis(salicylideneaminato) dianion), has been synthesized and structurally characterized. Reactions of 1 with [Cu(Me3tacn)(H2O)2](ClO4) 2 (Me3tacn=1, 4, 7-trimethyl-1, 4, 7-triazacyclononane) under different conditions produce the 1-D ferromagnetic zigzag chains [Os(salen)(CN)2]2[Cu(Me3tacn)] * CH 3OH (2) and [Os(salen)(CN)2][Cu(Me3tacn)] * ClO4 (3). © 2010 American Chemical Society.
dc.description.natureLink_to_subscribed_fulltext
dc.identifier.citationInorganic Chemistry, 2010, v. 49 n. 4, p. 1607-1614 [How to Cite?]
DOI: http://dx.doi.org/10.1021/ic9020178
dc.identifier.doihttp://dx.doi.org/10.1021/ic9020178
dc.identifier.epage1614
dc.identifier.hkuros168984
dc.identifier.isiWOS:000274240700050
Funding AgencyGrant Number
National Natural Science Foundation of ChinaNSFC 20831160505
National Basic Research Program of China2009CB929403
Council of Hong Kong Joint Research SchemeN_CityU 107/08
City University of Hong KongSRG 7002319
Funding Information:

The work described in this paper wits supported by grants from the National Natural Science Foundation of China (NSFC 20831160505), the National Basic Research Program of China (2009CB929403), the Research Grants Council of Hong Kong Joint Research Scheme (N_CityU 107/08), and the City University of Hong Kong (SRG 7002319).

dc.identifier.issn0020-1669
2011 Impact Factor: 4.601
2011 SCImago Journal Rankings: 0.315
dc.identifier.issue4
dc.identifier.openurl
dc.identifier.pmid20067236
dc.identifier.scopuseid_2-s2.0-77249091300
dc.identifier.spage1607
dc.identifier.urihttp://hdl.handle.net/10722/69723
dc.identifier.volume49
dc.languageeng
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
dc.publisher.placeUnited States
dc.relation.ispartofInorganic Chemistry
dc.relation.referencesReferences in Scopus
dc.titleTrans-[OsIII(salen)(CN)2]-: A new paramagnetic building block for the construction of molecule-based magnetic materials
dc.typeArticle
Author Affiliations
  1. The University of Hong Kong
  2. City University of Hong Kong
  3. Hong Kong Baptist University
  4. College of Chemistry and Molecular Engineering, Peking University