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Article: Trans-[OsIII(salen)(CN)2]-: A new paramagnetic building block for the construction of molecule-based magnetic materials
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TitleTrans-[OsIII(salen)(CN)2]-: A new paramagnetic building block for the construction of molecule-based magnetic materials
 
AuthorsGuo, JF4
Yeung, WF4
Lau, PH4
Wang, XT3
Gao, S3
Wong, WT1
Chui, SSY1
Che, CM1
Wong, WY2
Lau, TC4
 
Issue Date2010
 
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
 
CitationInorganic Chemistry, 2010, v. 49 n. 4, p. 1607-1614 [How to Cite?]
DOI: http://dx.doi.org/10.1021/ic9020178
 
AbstractA novel dicyanoosmium(III) complex, trans-Ph4P[Os III(salen)(CN)2]* CH2Cl2 * H2O (1; Ph4 P+ = tetraphenylphosphonium cation, salen2-=N, N′-ethylenebis(salicylideneaminato) dianion), has been synthesized and structurally characterized. Reactions of 1 with [Cu(Me3tacn)(H2O)2](ClO4) 2 (Me3tacn=1, 4, 7-trimethyl-1, 4, 7-triazacyclononane) under different conditions produce the 1-D ferromagnetic zigzag chains [Os(salen)(CN)2]2[Cu(Me3tacn)] * CH 3OH (2) and [Os(salen)(CN)2][Cu(Me3tacn)] * ClO4 (3). © 2010 American Chemical Society.
 
ISSN0020-1669
2013 Impact Factor: 4.794
 
DOIhttp://dx.doi.org/10.1021/ic9020178
 
ISI Accession Number IDWOS:000274240700050
Funding AgencyGrant Number
National Natural Science Foundation of ChinaNSFC 20831160505
National Basic Research Program of China2009CB929403
Council of Hong Kong Joint Research SchemeN_CityU 107/08
City University of Hong KongSRG 7002319
Funding Information:

The work described in this paper wits supported by grants from the National Natural Science Foundation of China (NSFC 20831160505), the National Basic Research Program of China (2009CB929403), the Research Grants Council of Hong Kong Joint Research Scheme (N_CityU 107/08), and the City University of Hong Kong (SRG 7002319).

 
ReferencesReferences in Scopus
 
DC FieldValue
dc.contributor.authorGuo, JF
 
dc.contributor.authorYeung, WF
 
dc.contributor.authorLau, PH
 
dc.contributor.authorWang, XT
 
dc.contributor.authorGao, S
 
dc.contributor.authorWong, WT
 
dc.contributor.authorChui, SSY
 
dc.contributor.authorChe, CM
 
dc.contributor.authorWong, WY
 
dc.contributor.authorLau, TC
 
dc.date.accessioned2010-09-06T06:16:15Z
 
dc.date.available2010-09-06T06:16:15Z
 
dc.date.issued2010
 
dc.description.abstractA novel dicyanoosmium(III) complex, trans-Ph4P[Os III(salen)(CN)2]* CH2Cl2 * H2O (1; Ph4 P+ = tetraphenylphosphonium cation, salen2-=N, N′-ethylenebis(salicylideneaminato) dianion), has been synthesized and structurally characterized. Reactions of 1 with [Cu(Me3tacn)(H2O)2](ClO4) 2 (Me3tacn=1, 4, 7-trimethyl-1, 4, 7-triazacyclononane) under different conditions produce the 1-D ferromagnetic zigzag chains [Os(salen)(CN)2]2[Cu(Me3tacn)] * CH 3OH (2) and [Os(salen)(CN)2][Cu(Me3tacn)] * ClO4 (3). © 2010 American Chemical Society.
 
dc.description.natureLink_to_subscribed_fulltext
 
dc.identifier.citationInorganic Chemistry, 2010, v. 49 n. 4, p. 1607-1614 [How to Cite?]
DOI: http://dx.doi.org/10.1021/ic9020178
 
dc.identifier.doihttp://dx.doi.org/10.1021/ic9020178
 
dc.identifier.epage1614
 
dc.identifier.hkuros168984
 
dc.identifier.isiWOS:000274240700050
Funding AgencyGrant Number
National Natural Science Foundation of ChinaNSFC 20831160505
National Basic Research Program of China2009CB929403
Council of Hong Kong Joint Research SchemeN_CityU 107/08
City University of Hong KongSRG 7002319
Funding Information:

The work described in this paper wits supported by grants from the National Natural Science Foundation of China (NSFC 20831160505), the National Basic Research Program of China (2009CB929403), the Research Grants Council of Hong Kong Joint Research Scheme (N_CityU 107/08), and the City University of Hong Kong (SRG 7002319).

 
dc.identifier.issn0020-1669
2013 Impact Factor: 4.794
 
dc.identifier.issue4
 
dc.identifier.openurl
 
dc.identifier.pmid20067236
 
dc.identifier.scopuseid_2-s2.0-77249091300
 
dc.identifier.spage1607
 
dc.identifier.urihttp://hdl.handle.net/10722/69723
 
dc.identifier.volume49
 
dc.languageeng
 
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
 
dc.publisher.placeUnited States
 
dc.relation.ispartofInorganic Chemistry
 
dc.relation.referencesReferences in Scopus
 
dc.titleTrans-[OsIII(salen)(CN)2]-: A new paramagnetic building block for the construction of molecule-based magnetic materials
 
dc.typeArticle
 
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Author Affiliations
  1. The University of Hong Kong
  2. Hong Kong Baptist University
  3. College of Chemistry and Molecular Engineering, Peking University
  4. City University of Hong Kong