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Article: Synthesis and copolymerization reaction of a triosmium alkylidyne carbonyl cluster [Os3(μ-H)2(CO)9(μ3-CNC5H4-CH=CH2)]

TitleSynthesis and copolymerization reaction of a triosmium alkylidyne carbonyl cluster [Os3(μ-H)2(CO)9(μ3-CNC5H4-CH=CH2)]
Authors
Wong, WTWong, WYYip, CW
KeywordsMLCT transition.
polyvinylpyridine
Triosmium alkylidyne carbonyl clusters
Issue Date1995
PublisherSpringer New York LLC. The Journal's web site is located at http://springerlink.metapress.com/openurl.asp?genre=journal&issn=1040-7278
Citation
Journal of Cluster Science, 1995, v. 6 n. 2, p. 311-317 How to Cite?
DOI: http://dx.doi.org/10.1007/BF01169698
AbstractA neutral triosmium alkylidyne carbonyl cluster containing the 4-vinylpyridine (4vpy) moiety [Os3(µ-H)2(CO)9(µ3-CNC5H4-CH=CH2)] (1) has been prepared as red crystalline solids in good yield. Monomer (1) was copolymerized with styrene in the presence of α,α'-azobis(isobutyronitrile) (AIBN) in chloroform at 60°C and a polymer-immobilized alkylidyne cluster of osmium was obtained. To compare the spectroscopic properties with the copolymers, a structurally similar repeating unit of the copolymers, [Os3(µ-H)2(CO)9(µ-3-CNC5H4-CH2CH3)I](2), has also been synthesized and characterized.
Persistent Identifierhttp://hdl.handle.net/10722/69707
ISSN
1040-7278
2023 Impact Factor: 2.7
2023 SCImago Journal Rankings: 0.504

 

DC FieldValueLanguage
dc.contributor.authorWong, WTen_HK
dc.contributor.authorWong, WYen_HK
dc.contributor.authorYip, CW-
dc.date.accessioned2010-09-06T06:16:07Z-
dc.date.available2010-09-06T06:16:07Z-
dc.date.issued1995en_HK
dc.identifier.citationJournal of Cluster Science, 1995, v. 6 n. 2, p. 311-317en_HK
dc.identifier.issn1040-7278en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69707-
dc.description.abstractA neutral triosmium alkylidyne carbonyl cluster containing the 4-vinylpyridine (4vpy) moiety [Os3(µ-H)2(CO)9(µ3-CNC5H4-CH=CH2)] (1) has been prepared as red crystalline solids in good yield. Monomer (1) was copolymerized with styrene in the presence of α,α'-azobis(isobutyronitrile) (AIBN) in chloroform at 60°C and a polymer-immobilized alkylidyne cluster of osmium was obtained. To compare the spectroscopic properties with the copolymers, a structurally similar repeating unit of the copolymers, [Os3(µ-H)2(CO)9(µ-3-CNC5H4-CH2CH3)I](2), has also been synthesized and characterized.-
dc.languageengen_HK
dc.publisherSpringer New York LLC. The Journal's web site is located at http://springerlink.metapress.com/openurl.asp?genre=journal&issn=1040-7278en_HK
dc.relation.ispartofJournal of Cluster Scienceen_HK
dc.rightsThe original publication is available at www.springerlink.com-
dc.subjectMLCT transition.-
dc.subjectpolyvinylpyridine-
dc.subjectTriosmium alkylidyne carbonyl clusters-
dc.titleSynthesis and copolymerization reaction of a triosmium alkylidyne carbonyl cluster [Os3(μ-H)2(CO)9(μ3-CNC5H4-CH=CH2)]en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1040-7278&volume=6&spage=311&epage=317&date=1995&atitle=Synthesis+and+copolymerization+reaction+of+a+triosmium+alkylidyne+carbonyl+cluster+[Os3(m-H)2(CO)9(m3-CNC5H4CH=CH2)]en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1007/BF01169698-
dc.identifier.scopuseid_2-s2.0-34249759199-
dc.identifier.hkuros14523en_HK
dc.identifier.volume6-
dc.identifier.issue2-
dc.identifier.spage311-
dc.identifier.epage317-
dc.publisher.placeUnited States-
dc.identifier.issnl1040-7278-

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