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Article: Synthesis and electrochemical properties of C5H-bridged bimetallic iron, ruthenium, and osmium complexes

TitleSynthesis and electrochemical properties of C5H-bridged bimetallic iron, ruthenium, and osmium complexes
Authors
Issue Date1999
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallics
Citation
Organometallics, 1999, v. 18 n. 22, p. 4552-4557 How to Cite?
AbstractTreatment of [CpOs(PPh3)2]BF4 in THF with 0.5 equiv of HC≡CCH(OH)C≡CH followed by Al2O3 gave the C5H-bridged compound [Cp(PPh3)2Os==C=C==CHC COs(PPh3)2Cp]BF4. The analogous iron complex [Cp(dppe)Fe==C==C==CHC≡CFe(dppe)Cp]BPh4 has been prepared similarly. The structure of [Cp(PPh3)2Os==C==C==CHC≡COs(PPh3)2Cp]BF4 has been confirmed by X-ray diffraction. The electrochemical properties of [Cp(dppe)Fe==C==C==CHC≡CFe(dppe)Cp]BPh4, [Cp(PPh3)2Ru==C==C==CHC≡CRu(PPh3)2Cp]BF4, and [Cp(PPh3)2Os==C==C==CHC≡COs(PPh3)2Cp]BF4 have been studied by cyclic voltammetry.
Persistent Identifierhttp://hdl.handle.net/10722/69697
ISSN
2015 Impact Factor: 4.186
2015 SCImago Journal Rankings: 2.043
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorXia, HPen_HK
dc.contributor.authorNg, WSen_HK
dc.contributor.authorYe, JSen_HK
dc.contributor.authorLi, XYen_HK
dc.contributor.authorWong, WTen_HK
dc.contributor.authorLin, Zen_HK
dc.contributor.authorYang, Cen_HK
dc.contributor.authorJia, Gen_HK
dc.date.accessioned2010-09-06T06:16:01Z-
dc.date.available2010-09-06T06:16:01Z-
dc.date.issued1999en_HK
dc.identifier.citationOrganometallics, 1999, v. 18 n. 22, p. 4552-4557en_HK
dc.identifier.issn0276-7333en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69697-
dc.description.abstractTreatment of [CpOs(PPh3)2]BF4 in THF with 0.5 equiv of HC≡CCH(OH)C≡CH followed by Al2O3 gave the C5H-bridged compound [Cp(PPh3)2Os==C=C==CHC COs(PPh3)2Cp]BF4. The analogous iron complex [Cp(dppe)Fe==C==C==CHC≡CFe(dppe)Cp]BPh4 has been prepared similarly. The structure of [Cp(PPh3)2Os==C==C==CHC≡COs(PPh3)2Cp]BF4 has been confirmed by X-ray diffraction. The electrochemical properties of [Cp(dppe)Fe==C==C==CHC≡CFe(dppe)Cp]BPh4, [Cp(PPh3)2Ru==C==C==CHC≡CRu(PPh3)2Cp]BF4, and [Cp(PPh3)2Os==C==C==CHC≡COs(PPh3)2Cp]BF4 have been studied by cyclic voltammetry.-
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallicsen_HK
dc.relation.ispartofOrganometallicsen_HK
dc.titleSynthesis and electrochemical properties of C5H-bridged bimetallic iron, ruthenium, and osmium complexesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0276-7333&volume=18&spage=4552&epage=4557&date=1999&atitle=Synthesis+and+electrochemical+properties+of+C5H-bridged+bimetallic+iron,+ruthenium,+and+osmium+complexesen_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1021/om9901832-
dc.identifier.scopuseid_2-s2.0-0001672515-
dc.identifier.hkuros53764en_HK
dc.identifier.isiWOS:000083654700015-

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