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- Publisher Website: 10.1021/om9901832
- Scopus: eid_2-s2.0-0001672515
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Article: Synthesis and electrochemical properties of C5H-bridged bimetallic iron, ruthenium, and osmium complexes
| Title | Synthesis and electrochemical properties of C5H-bridged bimetallic iron, ruthenium, and osmium complexes |
|---|---|
| Authors | |
| Issue Date | 1999 |
| Publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallics |
| Citation | Organometallics, 1999, v. 18 n. 22, p. 4552-4557 How to Cite? |
| Abstract | Treatment of [CpOs(PPh3)2]BF4 in THF with 0.5 equiv of HC≡CCH(OH)C≡CH followed by Al2O3 gave the C5H-bridged compound [Cp(PPh3)2Os==C=C==CHC COs(PPh3)2Cp]BF4. The analogous iron complex [Cp(dppe)Fe==C==C==CHC≡CFe(dppe)Cp]BPh4 has been prepared similarly. The structure of [Cp(PPh3)2Os==C==C==CHC≡COs(PPh3)2Cp]BF4 has been confirmed by X-ray diffraction. The electrochemical properties of [Cp(dppe)Fe==C==C==CHC≡CFe(dppe)Cp]BPh4, [Cp(PPh3)2Ru==C==C==CHC≡CRu(PPh3)2Cp]BF4, and [Cp(PPh3)2Os==C==C==CHC≡COs(PPh3)2Cp]BF4 have been studied by cyclic voltammetry. |
| Persistent Identifier | http://hdl.handle.net/10722/69697 |
| ISSN | 2023 Impact Factor: 2.5 2023 SCImago Journal Rankings: 0.654 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Xia, HP | en_HK |
| dc.contributor.author | Ng, WS | en_HK |
| dc.contributor.author | Ye, JS | en_HK |
| dc.contributor.author | Li, XY | en_HK |
| dc.contributor.author | Wong, WT | en_HK |
| dc.contributor.author | Lin, Z | en_HK |
| dc.contributor.author | Yang, C | en_HK |
| dc.contributor.author | Jia, G | en_HK |
| dc.date.accessioned | 2010-09-06T06:16:01Z | - |
| dc.date.available | 2010-09-06T06:16:01Z | - |
| dc.date.issued | 1999 | en_HK |
| dc.identifier.citation | Organometallics, 1999, v. 18 n. 22, p. 4552-4557 | en_HK |
| dc.identifier.issn | 0276-7333 | en_HK |
| dc.identifier.uri | http://hdl.handle.net/10722/69697 | - |
| dc.description.abstract | Treatment of [CpOs(PPh3)2]BF4 in THF with 0.5 equiv of HC≡CCH(OH)C≡CH followed by Al2O3 gave the C5H-bridged compound [Cp(PPh3)2Os==C=C==CHC COs(PPh3)2Cp]BF4. The analogous iron complex [Cp(dppe)Fe==C==C==CHC≡CFe(dppe)Cp]BPh4 has been prepared similarly. The structure of [Cp(PPh3)2Os==C==C==CHC≡COs(PPh3)2Cp]BF4 has been confirmed by X-ray diffraction. The electrochemical properties of [Cp(dppe)Fe==C==C==CHC≡CFe(dppe)Cp]BPh4, [Cp(PPh3)2Ru==C==C==CHC≡CRu(PPh3)2Cp]BF4, and [Cp(PPh3)2Os==C==C==CHC≡COs(PPh3)2Cp]BF4 have been studied by cyclic voltammetry. | - |
| dc.language | eng | en_HK |
| dc.publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallics | en_HK |
| dc.relation.ispartof | Organometallics | en_HK |
| dc.title | Synthesis and electrochemical properties of C5H-bridged bimetallic iron, ruthenium, and osmium complexes | en_HK |
| dc.type | Article | en_HK |
| dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0276-7333&volume=18&spage=4552&epage=4557&date=1999&atitle=Synthesis+and+electrochemical+properties+of+C5H-bridged+bimetallic+iron,+ruthenium,+and+osmium+complexes | en_HK |
| dc.identifier.email | Wong, WT: wtwong@hku.hk | en_HK |
| dc.identifier.authority | Wong, WT=rp00811 | en_HK |
| dc.identifier.doi | 10.1021/om9901832 | - |
| dc.identifier.scopus | eid_2-s2.0-0001672515 | - |
| dc.identifier.hkuros | 53764 | en_HK |
| dc.identifier.isi | WOS:000083654700015 | - |
| dc.identifier.issnl | 0276-7333 | - |