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Article: Synthesis and structural characterization of functionalized organolanthanide complexes [(η5-C5H4PPh2)2Ln(DIME)] (Ln = Eu, Yb) (DIME = diethylene glycol dimethyl ether)

TitleSynthesis and structural characterization of functionalized organolanthanide complexes [(η5-C5H4PPh2)2Ln(DIME)] (Ln = Eu, Yb) (DIME = diethylene glycol dimethyl ether)
Authors
KeywordsYtterbium
Europium
Thallium
Cyclopentadienyl
(Diphenylphosphino)cyclopentadienyl
Issue Date1996
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem
Citation
Journal of Organometallic Chemistry, 1996, v. 523 n. 1, p. 93-98 How to Cite?
AbstractThe reaction of [(diphenylphosphino)cyclopentadienyl]thallium [Tl(C5H4PPh2)] with metallic europium or ytterbium powder in THF (tetrahydrofuran) at 60°C in the presence of metallic mercury, followed by crystallization from a mixture of dimethyoxyethane and diethylene glycol dimethyl ether (DIME) (10:1), afforded [(η5-C5H4PPh2)2Eu(DIME))] 1 and [(η5-C5H4PPh2)2Yb(DIME)] 2 respectively. Crystal and molecular structures of 1 and 2 have been determined by X-ray crystallography.
Persistent Identifierhttp://hdl.handle.net/10722/69681
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorLin, Gen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:15:53Z-
dc.date.available2010-09-06T06:15:53Z-
dc.date.issued1996en_HK
dc.identifier.citationJournal of Organometallic Chemistry, 1996, v. 523 n. 1, p. 93-98en_HK
dc.identifier.issn0022-328Xen_HK
dc.identifier.urihttp://hdl.handle.net/10722/69681-
dc.description.abstractThe reaction of [(diphenylphosphino)cyclopentadienyl]thallium [Tl(C5H4PPh2)] with metallic europium or ytterbium powder in THF (tetrahydrofuran) at 60°C in the presence of metallic mercury, followed by crystallization from a mixture of dimethyoxyethane and diethylene glycol dimethyl ether (DIME) (10:1), afforded [(η5-C5H4PPh2)2Eu(DIME))] 1 and [(η5-C5H4PPh2)2Yb(DIME)] 2 respectively. Crystal and molecular structures of 1 and 2 have been determined by X-ray crystallography.-
dc.languageengen_HK
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchemen_HK
dc.relation.ispartofJournal of Organometallic Chemistryen_HK
dc.subjectYtterbium-
dc.subjectEuropium-
dc.subjectThallium-
dc.subjectCyclopentadienyl-
dc.subject(Diphenylphosphino)cyclopentadienyl-
dc.titleSynthesis and structural characterization of functionalized organolanthanide complexes [(η5-C5H4PPh2)2Ln(DIME)] (Ln = Eu, Yb) (DIME = diethylene glycol dimethyl ether)en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-328X&volume=523&spage=93&epage=98&date=1996&atitle=Synthesis+and+structural+characterization+of+functionalized+organolanthanide+complexes+[(h5-C5H4PPh2)2Ln(DIME)]+(Ln+=+Eu,+Yb)+(DIME+=+diethylene+glycol+dimethyl+ether)en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1016/0022-328X(96)06332-2-
dc.identifier.scopuseid_2-s2.0-0030568953-
dc.identifier.hkuros21870en_HK
dc.identifier.volume523-
dc.identifier.issue1-
dc.identifier.spage93-
dc.identifier.epage98-
dc.identifier.isiWOS:A1996VJ47900012-
dc.publisher.placeSwitzerland-

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