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Article: Hydrothermal preparation of novel Cd(II) coordination polymers employing 5-(4-pyridyl)tetrazolate as a bridging ligand

TitleHydrothermal preparation of novel Cd(II) coordination polymers employing 5-(4-pyridyl)tetrazolate as a bridging ligand
Authors
Issue Date2002
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 2002, v. 41 n. 25, p. 6544-6546 How to Cite?
AbstractThe reaction of 4-cyanopyridine with NaN3 in the presence of H2O and a Lewis acid (CdCl2) affords a novel 3D pillared-layered fluorescent and phosphorescent coordination polymer Cd3(OH)2Cl2(4-PTZ)2 (4-PTZ = 5-(4-pyridyl)tetrazolate) (1) while the direct reaction of CdCl2 with H-PTZ gives the simpler species Cd(4PTZ)2(H2O)2. The solid-state structure and nature of 1 provide an indication of the type of materials that may be formed as intermediates in the Sharpless-Demko reaction for the generation of 5-substituted 1 H-tetrazoles.
Persistent Identifierhttp://hdl.handle.net/10722/69678
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorXue, Xen_HK
dc.contributor.authorWang, XSen_HK
dc.contributor.authorWang, LZen_HK
dc.contributor.authorXiong, RGen_HK
dc.contributor.authorAbrahams, BFen_HK
dc.contributor.authorYou, XZen_HK
dc.contributor.authorXue, ZLen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2010-09-06T06:15:51Z-
dc.date.available2010-09-06T06:15:51Z-
dc.date.issued2002en_HK
dc.identifier.citationInorganic Chemistry, 2002, v. 41 n. 25, p. 6544-6546en_HK
dc.identifier.issn0020-1669en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69678-
dc.description.abstractThe reaction of 4-cyanopyridine with NaN3 in the presence of H2O and a Lewis acid (CdCl2) affords a novel 3D pillared-layered fluorescent and phosphorescent coordination polymer Cd3(OH)2Cl2(4-PTZ)2 (4-PTZ = 5-(4-pyridyl)tetrazolate) (1) while the direct reaction of CdCl2 with H-PTZ gives the simpler species Cd(4PTZ)2(H2O)2. The solid-state structure and nature of 1 provide an indication of the type of materials that may be formed as intermediates in the Sharpless-Demko reaction for the generation of 5-substituted 1 H-tetrazoles.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/icen_HK
dc.relation.ispartofInorganic Chemistryen_HK
dc.titleHydrothermal preparation of novel Cd(II) coordination polymers employing 5-(4-pyridyl)tetrazolate as a bridging liganden_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0020-1669&volume=41&issue=25&spage=6544&epage=6546&date=2002&atitle=Hydrothermal+preparation+of+novel+Cd(II)+coordination+polymers+employing+5-(4-Pyridyl)tetrazolate+as+a+bridging+liganden_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ic0257118en_HK
dc.identifier.pmid12470047-
dc.identifier.scopuseid_2-s2.0-0037121864en_HK
dc.identifier.hkuros83815en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0037121864&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume41en_HK
dc.identifier.issue25en_HK
dc.identifier.spage6544en_HK
dc.identifier.epage6546en_HK
dc.identifier.isiWOS:000179797700003-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridXue, X=36456581800en_HK
dc.identifier.scopusauthoridWang, XS=36026222800en_HK
dc.identifier.scopusauthoridWang, LZ=16025889300en_HK
dc.identifier.scopusauthoridXiong, RG=7102951372en_HK
dc.identifier.scopusauthoridAbrahams, BF=35601898600en_HK
dc.identifier.scopusauthoridYou, XZ=36072101800en_HK
dc.identifier.scopusauthoridXue, ZL=7203058536en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK

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