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Article: Chiral bipyridine-copper(II) complex. Crystal structure and catalytic activity in asymmetric cyclopropanation

TitleChiral bipyridine-copper(II) complex. Crystal structure and catalytic activity in asymmetric cyclopropanation
Authors
Kwong, HLLee, WSNg, HFChiu, WHWong, WT
Issue Date1998
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal Of The Chemical Society - Dalton Transactions, 1998 n. 6, p. 1043-1046 How to Cite?
DOI: http://dx.doi.org/10.1039/A706754B
AbstractA chiral bipyridine-copper(II) complex has been prepared and its crystal structure determined. The structure involves a CuN 2Cl 2 compressed tetrahedral stereochemistry. Chiral bipyridine complexes of copper-(I) and -(II) triflate are active catalysts for asymmetric cyclopropanation of alkenes with enantiomeric excesses up to 92%.
Persistent Identifierhttp://hdl.handle.net/10722/69675
ISSN
0300-9246
ISI Accession Number ID
WOS:000072775400028
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorKwong, HLen_HK
dc.contributor.authorLee, WSen_HK
dc.contributor.authorNg, HFen_HK
dc.contributor.authorChiu, WHen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:15:49Z-
dc.date.available2010-09-06T06:15:49Z-
dc.date.issued1998en_HK
dc.identifier.citationJournal Of The Chemical Society - Dalton Transactions, 1998 n. 6, p. 1043-1046en_HK
dc.identifier.issn0300-9246en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69675-
dc.description.abstractA chiral bipyridine-copper(II) complex has been prepared and its crystal structure determined. The structure involves a CuN 2Cl 2 compressed tetrahedral stereochemistry. Chiral bipyridine complexes of copper-(I) and -(II) triflate are active catalysts for asymmetric cyclopropanation of alkenes with enantiomeric excesses up to 92%.en_HK
dc.languageengen_HK
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_HK
dc.relation.ispartofJournal of the Chemical Society - Dalton Transactionsen_HK
dc.titleChiral bipyridine-copper(II) complex. Crystal structure and catalytic activity in asymmetric cyclopropanationen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1472-7773&volume=&spage=1043&epage=1046&date=1998&atitle=Chiral+bipyridine-copper(II)+complex.+Crystal+structure+and+catalytic+activity+in+asymmetric+cyclopropanationen_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/A706754B-
dc.identifier.scopuseid_2-s2.0-33748486436en_HK
dc.identifier.hkuros32562en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-33748486436&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.issue6en_HK
dc.identifier.spage1043en_HK
dc.identifier.epage1046en_HK
dc.identifier.isiWOS:000072775400028-
dc.identifier.scopusauthoridKwong, HL=35569416300en_HK
dc.identifier.scopusauthoridLee, WS=7407089119en_HK
dc.identifier.scopusauthoridNg, HF=14521353600en_HK
dc.identifier.scopusauthoridChiu, WH=7201503487en_HK
dc.identifier.scopusauthoridWong, WT=7403973084en_HK
dc.identifier.issnl0300-9246-

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