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Article: Metal-directed assembly of polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes

TitleMetal-directed assembly of polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes
Authors
KeywordsFerrocenyl amines
Macrocyclic molecular boxes
Metal-directed assembly
Issue Date2001
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem
Citation
Journal Of Organometallic Chemistry, 2001, v. 637-639, p. 89-93 How to Cite?
AbstractNovel redox-active polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes (10a-c), (11) and (12a-c) are synthesised by reaction of the respective ferrocenyl secondary amines, namely, N,N′-bis(ferrocenemethyl)-1,3-bis(aminomethyl)benzene (4), 1,1′-bis(benzylaminomethyl)ferrocene (8) and 1,1′-bis((ferrocenylmethyl)aminomethyl)ferrocene (9) with carbon disulfide, potassium hydroxide and transition metal (zinc, copper, nickel) acetate in high yields (52-82%) and characterised by spectroscopic and electrochemical techniques. The single-crystal X-ray structure of 10a shows that each zinc atom is in tetrahedral geometry, being bonded to two dithiocarbamate ligands with Zn-S distances 2.32(1)-2.44(1) Å. © 2001 Elsevier Science B.V.
Persistent Identifierhttp://hdl.handle.net/10722/69662
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLai, SWen_HK
dc.contributor.authorDrew, MGBen_HK
dc.contributor.authorBeer, PDen_HK
dc.date.accessioned2010-09-06T06:15:43Z-
dc.date.available2010-09-06T06:15:43Z-
dc.date.issued2001en_HK
dc.identifier.citationJournal Of Organometallic Chemistry, 2001, v. 637-639, p. 89-93en_HK
dc.identifier.issn0022-328Xen_HK
dc.identifier.urihttp://hdl.handle.net/10722/69662-
dc.description.abstractNovel redox-active polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes (10a-c), (11) and (12a-c) are synthesised by reaction of the respective ferrocenyl secondary amines, namely, N,N′-bis(ferrocenemethyl)-1,3-bis(aminomethyl)benzene (4), 1,1′-bis(benzylaminomethyl)ferrocene (8) and 1,1′-bis((ferrocenylmethyl)aminomethyl)ferrocene (9) with carbon disulfide, potassium hydroxide and transition metal (zinc, copper, nickel) acetate in high yields (52-82%) and characterised by spectroscopic and electrochemical techniques. The single-crystal X-ray structure of 10a shows that each zinc atom is in tetrahedral geometry, being bonded to two dithiocarbamate ligands with Zn-S distances 2.32(1)-2.44(1) Å. © 2001 Elsevier Science B.V.en_HK
dc.languageengen_HK
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchemen_HK
dc.relation.ispartofJournal of Organometallic Chemistryen_HK
dc.subjectFerrocenyl aminesen_HK
dc.subjectMacrocyclic molecular boxesen_HK
dc.subjectMetal-directed assemblyen_HK
dc.titleMetal-directed assembly of polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-328X&volume=637-639&spage=89&epage=93&date=2001&atitle=Metal-directed+assembly+of+polyferrocenyl+transition+metal+dithiocarbamate+macrocyclic+molecular+boxesen_HK
dc.identifier.emailLai, SW: swlai@hku.hken_HK
dc.identifier.authorityLai, SW=rp00717en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0022-328X(01)00972-Xen_HK
dc.identifier.scopuseid_2-s2.0-0035803708en_HK
dc.identifier.hkuros73903en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0035803708&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume637-639en_HK
dc.identifier.spage89en_HK
dc.identifier.epage93en_HK
dc.identifier.isiWOS:000172577800013-
dc.publisher.placeSwitzerlanden_HK
dc.identifier.scopusauthoridLai, SW=7402937200en_HK
dc.identifier.scopusauthoridDrew, MGB=35426195700en_HK
dc.identifier.scopusauthoridBeer, PD=7006012072en_HK

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