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Article: Metal-directed assembly of polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes
Title | Metal-directed assembly of polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes |
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Authors | |
Keywords | Ferrocenyl amines Macrocyclic molecular boxes Metal-directed assembly |
Issue Date | 2001 |
Publisher | Elsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem |
Citation | Journal Of Organometallic Chemistry, 2001, v. 637-639, p. 89-93 How to Cite? |
Abstract | Novel redox-active polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes (10a-c), (11) and (12a-c) are synthesised by reaction of the respective ferrocenyl secondary amines, namely, N,N′-bis(ferrocenemethyl)-1,3-bis(aminomethyl)benzene (4), 1,1′-bis(benzylaminomethyl)ferrocene (8) and 1,1′-bis((ferrocenylmethyl)aminomethyl)ferrocene (9) with carbon disulfide, potassium hydroxide and transition metal (zinc, copper, nickel) acetate in high yields (52-82%) and characterised by spectroscopic and electrochemical techniques. The single-crystal X-ray structure of 10a shows that each zinc atom is in tetrahedral geometry, being bonded to two dithiocarbamate ligands with Zn-S distances 2.32(1)-2.44(1) Å. © 2001 Elsevier Science B.V. |
Persistent Identifier | http://hdl.handle.net/10722/69662 |
ISSN | 2023 Impact Factor: 2.1 2023 SCImago Journal Rankings: 0.359 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
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dc.contributor.author | Lai, SW | en_HK |
dc.contributor.author | Drew, MGB | en_HK |
dc.contributor.author | Beer, PD | en_HK |
dc.date.accessioned | 2010-09-06T06:15:43Z | - |
dc.date.available | 2010-09-06T06:15:43Z | - |
dc.date.issued | 2001 | en_HK |
dc.identifier.citation | Journal Of Organometallic Chemistry, 2001, v. 637-639, p. 89-93 | en_HK |
dc.identifier.issn | 0022-328X | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/69662 | - |
dc.description.abstract | Novel redox-active polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes (10a-c), (11) and (12a-c) are synthesised by reaction of the respective ferrocenyl secondary amines, namely, N,N′-bis(ferrocenemethyl)-1,3-bis(aminomethyl)benzene (4), 1,1′-bis(benzylaminomethyl)ferrocene (8) and 1,1′-bis((ferrocenylmethyl)aminomethyl)ferrocene (9) with carbon disulfide, potassium hydroxide and transition metal (zinc, copper, nickel) acetate in high yields (52-82%) and characterised by spectroscopic and electrochemical techniques. The single-crystal X-ray structure of 10a shows that each zinc atom is in tetrahedral geometry, being bonded to two dithiocarbamate ligands with Zn-S distances 2.32(1)-2.44(1) Å. © 2001 Elsevier Science B.V. | en_HK |
dc.language | eng | en_HK |
dc.publisher | Elsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem | en_HK |
dc.relation.ispartof | Journal of Organometallic Chemistry | en_HK |
dc.subject | Ferrocenyl amines | en_HK |
dc.subject | Macrocyclic molecular boxes | en_HK |
dc.subject | Metal-directed assembly | en_HK |
dc.title | Metal-directed assembly of polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-328X&volume=637-639&spage=89&epage=93&date=2001&atitle=Metal-directed+assembly+of+polyferrocenyl+transition+metal+dithiocarbamate+macrocyclic+molecular+boxes | en_HK |
dc.identifier.email | Lai, SW: swlai@hku.hk | en_HK |
dc.identifier.authority | Lai, SW=rp00717 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/S0022-328X(01)00972-X | en_HK |
dc.identifier.scopus | eid_2-s2.0-0035803708 | en_HK |
dc.identifier.hkuros | 73903 | en_HK |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0035803708&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 637-639 | en_HK |
dc.identifier.spage | 89 | en_HK |
dc.identifier.epage | 93 | en_HK |
dc.identifier.isi | WOS:000172577800013 | - |
dc.publisher.place | Switzerland | en_HK |
dc.identifier.scopusauthorid | Lai, SW=7402937200 | en_HK |
dc.identifier.scopusauthorid | Drew, MGB=35426195700 | en_HK |
dc.identifier.scopusauthorid | Beer, PD=7006012072 | en_HK |
dc.identifier.issnl | 0022-328X | - |