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Article: Synthesis and Characterization of a Two-dimensional Manganese Coordination Polymer

TitleSynthesis and Characterization of a Two-dimensional Manganese Coordination Polymer
一個錳的二維配位聚合物的合成及其物質
Authors
KeywordsManganese complexes
Coordination polymers
Magnetic properties
Crystal structures
Issue Date2008
PublisherChinese Chemical Society (中國化學會). The Journal's web site is located at http://wjhxxb.periodicals.net.cn/
Citation
Chinese journal of Inorganic Chemistry, 2008, v. 24 n. 4, p. 610-614 How to Cite?
無機化學學報, 2008, v. 24 n. 4, p. 610-614 How to Cite?
AbstractSlow evaporation of the reaction mixture of ligand 2-(1H-imidazol-1-yl)acetic acid (Hiaa), 2,2′-bipyridine, NaOH, and Mn(ClO4)2•6H2O in water/ethanol affords a complex {[Mn(iaa)(2,2′-bipyridine)(H2O)](ClO4)}n (1). Single crystal structure determination reveals that 1 is a novel two-dimensional dinuclear manganese coordination polymer. The local coordination environment around manganese ions is a distorted octahedron. Every manganese ion coordinates with three ligands, while each ligand acts as a bridge linking three Mn ions. Magnetic studies suggest a weak antiferromagnetic coupling interaction between two Mn(II) ions. CCDC: 668269.
本文用2-咪唑乙酸(Hiaa),2,2′-聯吡啶,氫氧化鈉和六水合高氯酸錳在水和乙醇中反應合成了1個二維配位化合物{[Mn(iaa)(2,2′-bipyridine)(H2O)](ClO4)}n(1)。單晶結構表明化合物1是1個新穎的二維雙核錳配位聚合物,錳離子的配位構型為扭曲的八面體。每一個錳離子與3個配體配位,而每個配體與3個錳離子橋連。磁性研究表明1中Mn(Ⅱ)離子間存在弱的反鐵磁偶合作用。
Persistent Identifierhttp://hdl.handle.net/10722/69650
ISSN
2015 Impact Factor: 0.488
2015 SCImago Journal Rankings: 0.161

 

DC FieldValueLanguage
dc.contributor.authorLiu, YJen_HK
dc.contributor.authorZuo, JLen_HK
dc.contributor.authorChe, CMen_HK
dc.contributor.authorLi, YZen_HK
dc.date.accessioned2010-09-06T06:15:36Z-
dc.date.available2010-09-06T06:15:36Z-
dc.date.issued2008en_HK
dc.identifier.citationChinese journal of Inorganic Chemistry, 2008, v. 24 n. 4, p. 610-614en_HK
dc.identifier.citation無機化學學報, 2008, v. 24 n. 4, p. 610-614-
dc.identifier.issn1001-4861-
dc.identifier.urihttp://hdl.handle.net/10722/69650-
dc.description.abstractSlow evaporation of the reaction mixture of ligand 2-(1H-imidazol-1-yl)acetic acid (Hiaa), 2,2′-bipyridine, NaOH, and Mn(ClO4)2•6H2O in water/ethanol affords a complex {[Mn(iaa)(2,2′-bipyridine)(H2O)](ClO4)}n (1). Single crystal structure determination reveals that 1 is a novel two-dimensional dinuclear manganese coordination polymer. The local coordination environment around manganese ions is a distorted octahedron. Every manganese ion coordinates with three ligands, while each ligand acts as a bridge linking three Mn ions. Magnetic studies suggest a weak antiferromagnetic coupling interaction between two Mn(II) ions. CCDC: 668269.-
dc.description.abstract本文用2-咪唑乙酸(Hiaa),2,2′-聯吡啶,氫氧化鈉和六水合高氯酸錳在水和乙醇中反應合成了1個二維配位化合物{[Mn(iaa)(2,2′-bipyridine)(H2O)](ClO4)}n(1)。單晶結構表明化合物1是1個新穎的二維雙核錳配位聚合物,錳離子的配位構型為扭曲的八面體。每一個錳離子與3個配體配位,而每個配體與3個錳離子橋連。磁性研究表明1中Mn(Ⅱ)離子間存在弱的反鐵磁偶合作用。-
dc.languageengen_HK
dc.publisherChinese Chemical Society (中國化學會). The Journal's web site is located at http://wjhxxb.periodicals.net.cn/-
dc.relation.ispartofChinese journal of Inorganic Chemistryen_HK
dc.relation.ispartof無機化學學報-
dc.subjectManganese complexes-
dc.subjectCoordination polymers-
dc.subjectMagnetic properties-
dc.subjectCrystal structures-
dc.titleSynthesis and Characterization of a Two-dimensional Manganese Coordination Polymeren_HK
dc.title一個錳的二維配位聚合物的合成及其物質zh_HK
dc.typeArticleen_HK
dc.identifier.emailLiu, YJ: liuyujuan2002@163.comen_HK
dc.identifier.emailChe, CM: cmche@hku.hken_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.scopuseid_2-s2.0-42649142991-
dc.identifier.hkuros143019en_HK
dc.identifier.volume24-
dc.identifier.issue4-
dc.identifier.spage610-
dc.identifier.epage614-
dc.publisher.placeChina-
dc.customcontrol.immutablecsl 130626-

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