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Article: Resonance Raman study of the A-band short-time photodissociation dynamics of 2-iodothiophene

TitleResonance Raman study of the A-band short-time photodissociation dynamics of 2-iodothiophene
Authors
Issue Date2006
PublisherAmerican Institute of Physics. The Journal's web site is located at http://jcp.aip.org/jcp/staff.jsp
Citation
Journal Of Chemical Physics, 2006, v. 125 n. 5, article no. 054510 How to Cite?
AbstractResonance Raman spectra were obtained for 2-iodothiophene in cyclohexane solution with excitation wavelengths in resonance with the A-band absorption spectrum. These resonance Raman spectra indicate that the Franck-Condon region photodissociation dynamics have multidimensional character with motion mainly along the nominal symmetric C=C stretch of the thienyl ring and accompanied by a moderate amount of motion along the nominal symmetric CSC stretch, the nominal antisymmetric CSC stretch, and the nominal C-I stretch vibrational modes. A preliminary resonance Raman intensity analysis was done for the A-band resonance Raman spectra of 2-iodothiophene. These results were compared to previous results for related iodobenzene and iodoalkane molecules that also contain a C-I chromophore and the similarities and differences in the short-time photodissociation dynamics were discussed. © 2006 American Institute of Physics.
Persistent Identifierhttp://hdl.handle.net/10722/69639
ISSN
2015 Impact Factor: 2.894
2015 SCImago Journal Rankings: 0.959
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorZhu, HLen_HK
dc.contributor.authorLiu, Jen_HK
dc.contributor.authorZheng, Xen_HK
dc.contributor.authorPhillips, DLen_HK
dc.date.accessioned2010-09-06T06:15:30Z-
dc.date.available2010-09-06T06:15:30Z-
dc.date.issued2006en_HK
dc.identifier.citationJournal Of Chemical Physics, 2006, v. 125 n. 5, article no. 054510en_HK
dc.identifier.issn0021-9606en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69639-
dc.description.abstractResonance Raman spectra were obtained for 2-iodothiophene in cyclohexane solution with excitation wavelengths in resonance with the A-band absorption spectrum. These resonance Raman spectra indicate that the Franck-Condon region photodissociation dynamics have multidimensional character with motion mainly along the nominal symmetric C=C stretch of the thienyl ring and accompanied by a moderate amount of motion along the nominal symmetric CSC stretch, the nominal antisymmetric CSC stretch, and the nominal C-I stretch vibrational modes. A preliminary resonance Raman intensity analysis was done for the A-band resonance Raman spectra of 2-iodothiophene. These results were compared to previous results for related iodobenzene and iodoalkane molecules that also contain a C-I chromophore and the similarities and differences in the short-time photodissociation dynamics were discussed. © 2006 American Institute of Physics.en_HK
dc.languageengen_HK
dc.publisherAmerican Institute of Physics. The Journal's web site is located at http://jcp.aip.org/jcp/staff.jspen_HK
dc.relation.ispartofJournal of Chemical Physicsen_HK
dc.rightsJournal of Chemical Physics. Copyright © American Institute of Physics.en_HK
dc.rightsCreative Commons: Attribution 3.0 Hong Kong License-
dc.titleResonance Raman study of the A-band short-time photodissociation dynamics of 2-iodothiopheneen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0021-9606&volume=125&spage=054510&epage=1 &date=2006&atitle=Resonance+Raman+Study+of+The++a-band+Short-time+Photodissociation+Dynamics+Of+2-iodothiopheneen_HK
dc.identifier.emailPhillips, DL:phillips@hku.hken_HK
dc.identifier.authorityPhillips, DL=rp00770en_HK
dc.description.naturepublished_or_final_version-
dc.identifier.doi10.1063/1.2236118en_HK
dc.identifier.scopuseid_2-s2.0-33746930802en_HK
dc.identifier.hkuros133762en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-33746930802&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume125en_HK
dc.identifier.issue5en_HK
dc.identifier.spagearticle no. 054510-
dc.identifier.epagearticle no. 054510-
dc.identifier.isiWOS:000239573100034-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridZhu, HL=8712040400en_HK
dc.identifier.scopusauthoridLiu, J=26643543000en_HK
dc.identifier.scopusauthoridZheng, X=7404090253en_HK
dc.identifier.scopusauthoridPhillips, DL=7404519365en_HK

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