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Article: Platinum and platinum-ruthenium nanoparticles supported on ordered mesoporous carbon and their electrocatalytic performance for fuel cell reactions
Title | Platinum and platinum-ruthenium nanoparticles supported on ordered mesoporous carbon and their electrocatalytic performance for fuel cell reactions |
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Authors | |
Keywords | CMK-3 Methanol oxidation Ordered mesoporous carbon Oxygen reduction Platinum nanoparticles Platinum-ruthenium nanoparticles SBA-15 |
Issue Date | 2005 |
Publisher | Pergamon. The Journal's web site is located at http://www.elsevier.com/locate/electacta |
Citation | Electrochimica Acta, 2005, v. 50 n. 15, p. 3131-3141 How to Cite? |
Abstract | Highly ordered meso-porous carbon, denoted CMK-3 was synthesized by using mesoporous silicates, SBA-15 as the starting templating materials. The ordered mesoporous carbon was loaded with platinum and platinum-ruthenium nanoparticles using alternative synthesis techniques. The metal loaded ordered mesoporous carbon powders were characterized by transmission electron microscopy (HRTEM), energy dispersive X-ray analysis (EDX), X-ray diffraction, and nitrogen adsorption isotherm experiments. Micrometer-scale and centimeter-scale electrodes containing the mesocarbon/nanometal electrocatalysts were tested for some typical fuel cell reactions. While the nanometal/mesocarbon catalysts have well-defined and uniform properties in the nanometer scale, they have mixed electrocatalytic performance. A synthesized Pt/mesocarbon electrocatalyst outperformed a commercial electrocatalyst for oxygen reduction on a gas-diffusion electrode. The Pt-Ru/mesocarbon electrocatalyst synthesized, however, was not as effective for methanol oxidation. © 2005 Elsevier Ltd. All rights reserved. |
Persistent Identifier | http://hdl.handle.net/10722/69634 |
ISSN | 2023 Impact Factor: 5.5 2023 SCImago Journal Rankings: 1.159 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Ding, J | en_HK |
dc.contributor.author | Chan, KY | en_HK |
dc.contributor.author | Ren, J | en_HK |
dc.contributor.author | Xiao, FS | en_HK |
dc.date.accessioned | 2010-09-06T06:15:27Z | - |
dc.date.available | 2010-09-06T06:15:27Z | - |
dc.date.issued | 2005 | en_HK |
dc.identifier.citation | Electrochimica Acta, 2005, v. 50 n. 15, p. 3131-3141 | en_HK |
dc.identifier.issn | 0013-4686 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/69634 | - |
dc.description.abstract | Highly ordered meso-porous carbon, denoted CMK-3 was synthesized by using mesoporous silicates, SBA-15 as the starting templating materials. The ordered mesoporous carbon was loaded with platinum and platinum-ruthenium nanoparticles using alternative synthesis techniques. The metal loaded ordered mesoporous carbon powders were characterized by transmission electron microscopy (HRTEM), energy dispersive X-ray analysis (EDX), X-ray diffraction, and nitrogen adsorption isotherm experiments. Micrometer-scale and centimeter-scale electrodes containing the mesocarbon/nanometal electrocatalysts were tested for some typical fuel cell reactions. While the nanometal/mesocarbon catalysts have well-defined and uniform properties in the nanometer scale, they have mixed electrocatalytic performance. A synthesized Pt/mesocarbon electrocatalyst outperformed a commercial electrocatalyst for oxygen reduction on a gas-diffusion electrode. The Pt-Ru/mesocarbon electrocatalyst synthesized, however, was not as effective for methanol oxidation. © 2005 Elsevier Ltd. All rights reserved. | en_HK |
dc.language | eng | en_HK |
dc.publisher | Pergamon. The Journal's web site is located at http://www.elsevier.com/locate/electacta | en_HK |
dc.relation.ispartof | Electrochimica Acta | en_HK |
dc.subject | CMK-3 | en_HK |
dc.subject | Methanol oxidation | en_HK |
dc.subject | Ordered mesoporous carbon | en_HK |
dc.subject | Oxygen reduction | en_HK |
dc.subject | Platinum nanoparticles | en_HK |
dc.subject | Platinum-ruthenium nanoparticles | en_HK |
dc.subject | SBA-15 | en_HK |
dc.title | Platinum and platinum-ruthenium nanoparticles supported on ordered mesoporous carbon and their electrocatalytic performance for fuel cell reactions | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0013-4686&volume=50&spage=3131&epage=3141&date=2005&atitle=Platinum+and+platinum-ruthenium+nanoparticles+supported+on+ordered+mesoporous+carbon+and+their+electrocatalytic+performance+for+fuel+cell+reactions | en_HK |
dc.identifier.email | Chan, KY:hrsccky@hku.hk | en_HK |
dc.identifier.authority | Chan, KY=rp00662 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/j.electacta.2004.11.064 | en_HK |
dc.identifier.scopus | eid_2-s2.0-17744371130 | en_HK |
dc.identifier.hkuros | 106440 | en_HK |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-17744371130&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 50 | en_HK |
dc.identifier.issue | 15 | en_HK |
dc.identifier.spage | 3131 | en_HK |
dc.identifier.epage | 3141 | en_HK |
dc.identifier.isi | WOS:000229364600017 | - |
dc.publisher.place | United Kingdom | en_HK |
dc.identifier.scopusauthorid | Ding, J=55244057600 | en_HK |
dc.identifier.scopusauthorid | Chan, KY=7406034142 | en_HK |
dc.identifier.scopusauthorid | Ren, J=35254633000 | en_HK |
dc.identifier.scopusauthorid | Xiao, FS=7201709636 | en_HK |
dc.identifier.issnl | 0013-4686 | - |