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Article: Ruthenium-mediated amidation of saturated C-H bonds and crystal structure of a bis(tosyl)amidoruthenium(III) complex of 1,4,7-trimethyl-1,4,7-triazacyclononane

TitleRuthenium-mediated amidation of saturated C-H bonds and crystal structure of a bis(tosyl)amidoruthenium(III) complex of 1,4,7-trimethyl-1,4,7-triazacyclononane
Authors
Issue Date1998
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Chemical Communications, 1998 n. 24, p. 2677-2678 How to Cite?
AbstractA bis(tosyl)amidoruthenium(III) complex of 1,4,7-trimethyl-1,4,7-triazacyclononane (Me3tacn) is prepared, and its crystal structure revealed the two tosylamido ligands in a cis configuration; the '[Ru(III)(Me3tacn)(NHTs)2(OH)] + Ag(I) or PhINTs' protocol can effect amidation of saturated C-H bonds, and an electrophilic tosylimidoruthenium intermediate is implicated based on Hammett correlation studies and trapping experiments.
Persistent Identifierhttp://hdl.handle.net/10722/69614
ISSN
2015 Impact Factor: 6.567
2015 SCImago Journal Rankings: 2.771
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorAu, SMen_HK
dc.contributor.authorZhang, SBen_HK
dc.contributor.authorFung, WHen_HK
dc.contributor.authorYu, WYen_HK
dc.contributor.authorChe, CMen_HK
dc.contributor.authorCheung, KKen_HK
dc.date.accessioned2010-09-06T06:15:16Z-
dc.date.available2010-09-06T06:15:16Z-
dc.date.issued1998en_HK
dc.identifier.citationChemical Communications, 1998 n. 24, p. 2677-2678en_HK
dc.identifier.issn1359-7345en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69614-
dc.description.abstractA bis(tosyl)amidoruthenium(III) complex of 1,4,7-trimethyl-1,4,7-triazacyclononane (Me3tacn) is prepared, and its crystal structure revealed the two tosylamido ligands in a cis configuration; the '[Ru(III)(Me3tacn)(NHTs)2(OH)] + Ag(I) or PhINTs' protocol can effect amidation of saturated C-H bonds, and an electrophilic tosylimidoruthenium intermediate is implicated based on Hammett correlation studies and trapping experiments.en_HK
dc.languageengen_HK
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_HK
dc.relation.ispartofChemical Communicationsen_HK
dc.titleRuthenium-mediated amidation of saturated C-H bonds and crystal structure of a bis(tosyl)amidoruthenium(III) complex of 1,4,7-trimethyl-1,4,7-triazacyclononaneen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1359-7345&volume=&spage=2677&epage=2678&date=1998&atitle=Ruthenium-mediated+amidation+of+saturated+C-H+bonds+and+crystal+structure+of+a+bis(tosyl)amidoruthenium(III)+complex+of+1,4,7-trimethyl-1,4,7-triazacyclononaneen_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/A808048H-
dc.identifier.scopuseid_2-s2.0-0032556803en_HK
dc.identifier.hkuros40281en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0032556803&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.issue24en_HK
dc.identifier.spage2677en_HK
dc.identifier.epage2678en_HK
dc.identifier.isiWOS:000077611400002-
dc.publisher.placeUnited Kingdomen_HK
dc.identifier.scopusauthoridAu, SM=7005457811en_HK
dc.identifier.scopusauthoridZhang, SB=7409376552en_HK
dc.identifier.scopusauthoridFung, WH=7102150303en_HK
dc.identifier.scopusauthoridYu, WY=7403913673en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.scopusauthoridCheung, KK=7402406613en_HK

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