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Article: Biomimetic synthesis of arteannuin H and the 3,2- rearrangement of allylic hydroperoxides
Title | Biomimetic synthesis of arteannuin H and the 3,2- rearrangement of allylic hydroperoxides |
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Authors | |
Issue Date | 1999 |
Publisher | Pergamon. The Journal's web site is located at http://www.elsevier.com/locate/tet |
Citation | Tetrahedron, 1999, v. 55 n. 52, p. 15127-15140 How to Cite? |
Abstract | The acyl endoperoxide arteannuin H, recently reported as a novel natural product from Artemisia annua, has been obtained in two steps from the photooxidation of dihydroartemisinic acid, thereby confirming biogenetic speculation regarding its derivation from a secondary allylic hydroperoxide. The little studied 3,2-rearrangement reaction of such allylic hydroperoxides is also discussed. |
Persistent Identifier | http://hdl.handle.net/10722/69589 |
ISSN | 2023 Impact Factor: 2.1 2023 SCImago Journal Rankings: 0.406 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Sy, LK | en_HK |
dc.contributor.author | Ngo, KS | en_HK |
dc.contributor.author | Brown, GD | en_HK |
dc.date.accessioned | 2010-09-06T06:15:03Z | - |
dc.date.available | 2010-09-06T06:15:03Z | - |
dc.date.issued | 1999 | en_HK |
dc.identifier.citation | Tetrahedron, 1999, v. 55 n. 52, p. 15127-15140 | en_HK |
dc.identifier.issn | 0040-4020 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/69589 | - |
dc.description.abstract | The acyl endoperoxide arteannuin H, recently reported as a novel natural product from Artemisia annua, has been obtained in two steps from the photooxidation of dihydroartemisinic acid, thereby confirming biogenetic speculation regarding its derivation from a secondary allylic hydroperoxide. The little studied 3,2-rearrangement reaction of such allylic hydroperoxides is also discussed. | en_HK |
dc.language | eng | en_HK |
dc.publisher | Pergamon. The Journal's web site is located at http://www.elsevier.com/locate/tet | en_HK |
dc.relation.ispartof | Tetrahedron | en_HK |
dc.title | Biomimetic synthesis of arteannuin H and the 3,2- rearrangement of allylic hydroperoxides | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0040-4020&volume=55&spage=15127&epage=15140&date=1999&atitle=Biomimetic+Synthesis+of+Arteannuin+H+and+the+3,2-Rearrangement+of+allylic+Hydroperoxides | en_HK |
dc.identifier.email | Sy, LK:sylk@hkucc.hku.hk | en_HK |
dc.identifier.authority | Sy, LK=rp00784 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/S0040-4020(99)00987-4 | - |
dc.identifier.scopus | eid_2-s2.0-0033601429 | en_HK |
dc.identifier.hkuros | 50059 | en_HK |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0033601429&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 55 | en_HK |
dc.identifier.issue | 52 | en_HK |
dc.identifier.spage | 15127 | en_HK |
dc.identifier.epage | 15140 | en_HK |
dc.identifier.isi | WOS:000084108200028 | - |
dc.publisher.place | United Kingdom | en_HK |
dc.identifier.scopusauthorid | Sy, LK=35874602700 | en_HK |
dc.identifier.scopusauthorid | Ngo, KS=7005435631 | en_HK |
dc.identifier.scopusauthorid | Brown, GD=7406468149 | en_HK |
dc.identifier.issnl | 0040-4020 | - |