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Article: Biomimetic synthesis of arteannuin H and the 3,2- rearrangement of allylic hydroperoxides

TitleBiomimetic synthesis of arteannuin H and the 3,2- rearrangement of allylic hydroperoxides
Authors
Sy, LKNgo, KSBrown, GD
Issue Date1999
PublisherPergamon. The Journal's web site is located at http://www.elsevier.com/locate/tet
Citation
Tetrahedron, 1999, v. 55 n. 52, p. 15127-15140 How to Cite?
DOI: http://dx.doi.org/10.1016/S0040-4020(99)00987-4
AbstractThe acyl endoperoxide arteannuin H, recently reported as a novel natural product from Artemisia annua, has been obtained in two steps from the photooxidation of dihydroartemisinic acid, thereby confirming biogenetic speculation regarding its derivation from a secondary allylic hydroperoxide. The little studied 3,2-rearrangement reaction of such allylic hydroperoxides is also discussed.
Persistent Identifierhttp://hdl.handle.net/10722/69589
ISSN
0040-4020
2023 Impact Factor: 2.1
2023 SCImago Journal Rankings: 0.406
ISI Accession Number ID
WOS:000084108200028
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorSy, LKen_HK
dc.contributor.authorNgo, KSen_HK
dc.contributor.authorBrown, GDen_HK
dc.date.accessioned2010-09-06T06:15:03Z-
dc.date.available2010-09-06T06:15:03Z-
dc.date.issued1999en_HK
dc.identifier.citationTetrahedron, 1999, v. 55 n. 52, p. 15127-15140en_HK
dc.identifier.issn0040-4020en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69589-
dc.description.abstractThe acyl endoperoxide arteannuin H, recently reported as a novel natural product from Artemisia annua, has been obtained in two steps from the photooxidation of dihydroartemisinic acid, thereby confirming biogenetic speculation regarding its derivation from a secondary allylic hydroperoxide. The little studied 3,2-rearrangement reaction of such allylic hydroperoxides is also discussed.en_HK
dc.languageengen_HK
dc.publisherPergamon. The Journal's web site is located at http://www.elsevier.com/locate/teten_HK
dc.relation.ispartofTetrahedronen_HK
dc.titleBiomimetic synthesis of arteannuin H and the 3,2- rearrangement of allylic hydroperoxidesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0040-4020&volume=55&spage=15127&epage=15140&date=1999&atitle=Biomimetic+Synthesis+of+Arteannuin+H+and+the+3,2-Rearrangement+of+allylic+Hydroperoxidesen_HK
dc.identifier.emailSy, LK:sylk@hkucc.hku.hken_HK
dc.identifier.authoritySy, LK=rp00784en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0040-4020(99)00987-4-
dc.identifier.scopuseid_2-s2.0-0033601429en_HK
dc.identifier.hkuros50059en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0033601429&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume55en_HK
dc.identifier.issue52en_HK
dc.identifier.spage15127en_HK
dc.identifier.epage15140en_HK
dc.identifier.isiWOS:000084108200028-
dc.publisher.placeUnited Kingdomen_HK
dc.identifier.scopusauthoridSy, LK=35874602700en_HK
dc.identifier.scopusauthoridNgo, KS=7005435631en_HK
dc.identifier.scopusauthoridBrown, GD=7406468149en_HK
dc.identifier.issnl0040-4020-

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