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- Publisher Website: 10.1016/0022-328X(95)05657-B
- Scopus: eid_2-s2.0-0030525311
- WOS: WOS:A1996TP33800010
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Article: Synthesis characterization, electrochemical properties and crystal and molecular structures of [HOs3(CO)10(O2CC5H4FeC5H 5)] and [{Os3H(CO)10}2(O2CC5H4FeC5H4CO2)]
| Title | Synthesis characterization, electrochemical properties and crystal and molecular structures of [HOs3(CO)10(O2CC5H4FeC5H 5)] and [{Os3H(CO)10}2(O2CC5H4FeC5H4CO2)] |
|---|---|
| Authors | |
| Keywords | Osmium Carbonyls Cluster Ferrocenes Crystal structure |
| Issue Date | 1996 |
| Publisher | Elsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem |
| Citation | Journal of Organometallic Chemistry, 1996, v. 506 n. 1-2, p. 77-84 How to Cite? |
| Abstract | Two new air-stable triosmium clusters, [HOs3(CO)10(O2CC5H4FeC5H5)] (1) and [{Os3H(CO)10}2(O2 CC5H4FeC5H4CO2)] (2), were obtained from the reaction of the labilized cluster [Os3(CO)10(CH3CN)2] and the corresponding ferrocenecarboxylic acid and were characterized by spectroscopic methods and single-crystal X-ray diffraction studies. The redox properties of both complexes were studied by cyclic voltammetry at ambient temperature; both exhibit a reversible electron transfer process. |
| Persistent Identifier | http://hdl.handle.net/10722/69577 |
| ISSN | 2023 Impact Factor: 2.1 2023 SCImago Journal Rankings: 0.359 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Lee, SM | en_HK |
| dc.contributor.author | Cheung, KK | en_HK |
| dc.contributor.author | Wong, WT | en_HK |
| dc.date.accessioned | 2010-09-06T06:14:57Z | - |
| dc.date.available | 2010-09-06T06:14:57Z | - |
| dc.date.issued | 1996 | en_HK |
| dc.identifier.citation | Journal of Organometallic Chemistry, 1996, v. 506 n. 1-2, p. 77-84 | en_HK |
| dc.identifier.issn | 0022-328X | en_HK |
| dc.identifier.uri | http://hdl.handle.net/10722/69577 | - |
| dc.description.abstract | Two new air-stable triosmium clusters, [HOs3(CO)10(O2CC5H4FeC5H5)] (1) and [{Os3H(CO)10}2(O2 CC5H4FeC5H4CO2)] (2), were obtained from the reaction of the labilized cluster [Os3(CO)10(CH3CN)2] and the corresponding ferrocenecarboxylic acid and were characterized by spectroscopic methods and single-crystal X-ray diffraction studies. The redox properties of both complexes were studied by cyclic voltammetry at ambient temperature; both exhibit a reversible electron transfer process. | - |
| dc.language | eng | en_HK |
| dc.publisher | Elsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem | en_HK |
| dc.relation.ispartof | Journal of Organometallic Chemistry | en_HK |
| dc.rights | NOTICE: this is the author’s version of a work that was accepted for publication in <Journal title>. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in PUBLICATION, [VOL#, ISSUE#, (DATE)] DOI# | - |
| dc.subject | Osmium | - |
| dc.subject | Carbonyls | - |
| dc.subject | Cluster | - |
| dc.subject | Ferrocenes | - |
| dc.subject | Crystal structure | - |
| dc.title | Synthesis characterization, electrochemical properties and crystal and molecular structures of [HOs3(CO)10(O2CC5H4FeC5H 5)] and [{Os3H(CO)10}2(O2CC5H4FeC5H4CO2)] | en_HK |
| dc.type | Article | en_HK |
| dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-328X&volume=506 Nos1-2&spage=77&epage=84&date=1996&atitle=Synthesis+characterization,+electrochemical+properties+and+crystal+and+molecular+structures+of+[HOs3(CO)10(O2CC5H4FeC5H+5)]+and+[{Os3H(CO)10}2(O2CC5H4FeC5H4CO2)] | en_HK |
| dc.identifier.email | Cheung, KK: kkcheung@hkucc.hku.hk | en_HK |
| dc.identifier.email | Wong, WT: wtwong@hku.hk | en_HK |
| dc.identifier.authority | Wong, WT=rp00811 | en_HK |
| dc.identifier.doi | 10.1016/0022-328X(95)05657-B | - |
| dc.identifier.scopus | eid_2-s2.0-0030525311 | - |
| dc.identifier.hkuros | 14637 | en_HK |
| dc.identifier.volume | 506 | - |
| dc.identifier.issue | 1-2 | - |
| dc.identifier.spage | 77 | - |
| dc.identifier.epage | 84 | - |
| dc.identifier.isi | WOS:A1996TP33800010 | - |
| dc.publisher.place | Switzerland | - |
| dc.identifier.issnl | 0022-328X | - |