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Article: Synthesis characterization, electrochemical properties and crystal and molecular structures of [HOs3(CO)10(O2CC5H4FeC5H 5)] and [{Os3H(CO)10}2(O2CC5H4FeC5H4CO2)]

TitleSynthesis characterization, electrochemical properties and crystal and molecular structures of [HOs3(CO)10(O2CC5H4FeC5H 5)] and [{Os3H(CO)10}2(O2CC5H4FeC5H4CO2)]
Authors
KeywordsOsmium
Carbonyls
Cluster
Ferrocenes
Crystal structure
Issue Date1996
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem
Citation
Journal of Organometallic Chemistry, 1996, v. 506 n. 1-2, p. 77-84 How to Cite?
AbstractTwo new air-stable triosmium clusters, [HOs3(CO)10(O2CC5H4FeC5H5)] (1) and [{Os3H(CO)10}2(O2 CC5H4FeC5H4CO2)] (2), were obtained from the reaction of the labilized cluster [Os3(CO)10(CH3CN)2] and the corresponding ferrocenecarboxylic acid and were characterized by spectroscopic methods and single-crystal X-ray diffraction studies. The redox properties of both complexes were studied by cyclic voltammetry at ambient temperature; both exhibit a reversible electron transfer process.
Persistent Identifierhttp://hdl.handle.net/10722/69577
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorLee, SMen_HK
dc.contributor.authorCheung, KKen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:14:57Z-
dc.date.available2010-09-06T06:14:57Z-
dc.date.issued1996en_HK
dc.identifier.citationJournal of Organometallic Chemistry, 1996, v. 506 n. 1-2, p. 77-84en_HK
dc.identifier.issn0022-328Xen_HK
dc.identifier.urihttp://hdl.handle.net/10722/69577-
dc.description.abstractTwo new air-stable triosmium clusters, [HOs3(CO)10(O2CC5H4FeC5H5)] (1) and [{Os3H(CO)10}2(O2 CC5H4FeC5H4CO2)] (2), were obtained from the reaction of the labilized cluster [Os3(CO)10(CH3CN)2] and the corresponding ferrocenecarboxylic acid and were characterized by spectroscopic methods and single-crystal X-ray diffraction studies. The redox properties of both complexes were studied by cyclic voltammetry at ambient temperature; both exhibit a reversible electron transfer process.-
dc.languageengen_HK
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchemen_HK
dc.relation.ispartofJournal of Organometallic Chemistryen_HK
dc.rightsNOTICE: this is the author’s version of a work that was accepted for publication in <Journal title>. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in PUBLICATION, [VOL#, ISSUE#, (DATE)] DOI#-
dc.subjectOsmium-
dc.subjectCarbonyls-
dc.subjectCluster-
dc.subjectFerrocenes-
dc.subjectCrystal structure-
dc.titleSynthesis characterization, electrochemical properties and crystal and molecular structures of [HOs3(CO)10(O2CC5H4FeC5H 5)] and [{Os3H(CO)10}2(O2CC5H4FeC5H4CO2)]en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-328X&volume=506 Nos1-2&spage=77&epage=84&date=1996&atitle=Synthesis+characterization,+electrochemical+properties+and+crystal+and+molecular+structures+of+[HOs3(CO)10(O2CC5H4FeC5H+5)]+and+[{Os3H(CO)10}2(O2CC5H4FeC5H4CO2)]en_HK
dc.identifier.emailCheung, KK: kkcheung@hkucc.hku.hken_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1016/0022-328X(95)05657-B-
dc.identifier.scopuseid_2-s2.0-0030525311-
dc.identifier.hkuros14637en_HK
dc.identifier.volume506-
dc.identifier.issue1-2-
dc.identifier.spage77-
dc.identifier.epage84-
dc.identifier.isiWOS:A1996TP33800010-
dc.publisher.placeSwitzerland-

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