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Article: Copper complexes of chiral tetradentate binaphthyl Schiff-base ligands: Syntheses, X-ray crystal structures and activity in catalytic asymmetric cyclopropanation of alkenes

TitleCopper complexes of chiral tetradentate binaphthyl Schiff-base ligands: Syntheses, X-ray crystal structures and activity in catalytic asymmetric cyclopropanation of alkenes
Authors
Che, CMKwong, HLChu, WCCheng, KFLee, WSYu, HSYeung, CTCheung, KK
KeywordsAsymmetric catalysis
Copper
Cyclopropanation
Schiff bases
Structure elucidation
Issue Date2002
PublisherWiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.eurjic.org
Citation
European Journal Of Inorganic Chemistry, 2002 n. 6, p. 1456-1463 How to Cite?
DOI: http://dx.doi.org/10.1002/1099-0682(200206)2002:6<1456::AID-EJIC1456>3.0.CO;2-H
AbstractA number of new chiral monomeric binaphthyl Schiff-base ligands H2L [where H2L = 2,2′-bis(3-R1-5-R2-2-hydroxybenzylideneamino) -1,1′-binaphthyl] and a series of chiral copper(II) complexes [CuL] were prepared in good or nearly quantitative yields. Some of the free ligands and the [CuL] complexes were structurally characterized by X-ray crystallography. Almost all the [CuL] complexes were found to be active catalysts for the asymmetric cyclopropanation of alkenes with ethyl or tert-butyl diazoacetate. Enantioselectivities of up to 77% ee were observed. © Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.
Persistent Identifierhttp://hdl.handle.net/10722/69576
ISSN
1434-1948
2023 Impact Factor: 2.2
2023 SCImago Journal Rankings: 0.481
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_HK
dc.contributor.authorKwong, HLen_HK
dc.contributor.authorChu, WCen_HK
dc.contributor.authorCheng, KFen_HK
dc.contributor.authorLee, WSen_HK
dc.contributor.authorYu, HSen_HK
dc.contributor.authorYeung, CTen_HK
dc.contributor.authorCheung, KKen_HK
dc.date.accessioned2010-09-06T06:14:56Z-
dc.date.available2010-09-06T06:14:56Z-
dc.date.issued2002en_HK
dc.identifier.citationEuropean Journal Of Inorganic Chemistry, 2002 n. 6, p. 1456-1463en_HK
dc.identifier.issn1434-1948en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69576-
dc.description.abstractA number of new chiral monomeric binaphthyl Schiff-base ligands H2L [where H2L = 2,2′-bis(3-R1-5-R2-2-hydroxybenzylideneamino) -1,1′-binaphthyl] and a series of chiral copper(II) complexes [CuL] were prepared in good or nearly quantitative yields. Some of the free ligands and the [CuL] complexes were structurally characterized by X-ray crystallography. Almost all the [CuL] complexes were found to be active catalysts for the asymmetric cyclopropanation of alkenes with ethyl or tert-butyl diazoacetate. Enantioselectivities of up to 77% ee were observed. © Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.en_HK
dc.languageengen_HK
dc.publisherWiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.eurjic.orgen_HK
dc.relation.ispartofEuropean Journal of Inorganic Chemistryen_HK
dc.subjectAsymmetric catalysisen_HK
dc.subjectCopperen_HK
dc.subjectCyclopropanationen_HK
dc.subjectSchiff basesen_HK
dc.subjectStructure elucidationen_HK
dc.titleCopper complexes of chiral tetradentate binaphthyl Schiff-base ligands: Syntheses, X-ray crystal structures and activity in catalytic asymmetric cyclopropanation of alkenesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1434-1948&volume=&spage=1456&epage=1463&date=2002&atitle=Copper+complexes+of+chiral+tetradentate+binaphthyl+Schiff-base+ligands:++syntheses,+X-ray+crystal+structures+and+activity+in+catalytic+asymmetric+cyclopropanation+of+alkenesen_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/1099-0682(200206)2002:6<1456::AID-EJIC1456>3.0.CO;2-H-
dc.identifier.scopuseid_2-s2.0-0036262856en_HK
dc.identifier.hkuros76376en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0036262856&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.issue6en_HK
dc.identifier.spage1456en_HK
dc.identifier.epage1463en_HK
dc.publisher.placeGermanyen_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.scopusauthoridKwong, HL=35569416300en_HK
dc.identifier.scopusauthoridChu, WC=7402227725en_HK
dc.identifier.scopusauthoridCheng, KF=7402997838en_HK
dc.identifier.scopusauthoridLee, WS=7407089119en_HK
dc.identifier.scopusauthoridYu, HS=37062812400en_HK
dc.identifier.scopusauthoridYeung, CT=7201354137en_HK
dc.identifier.scopusauthoridCheung, KK=36893099900en_HK
dc.identifier.issnl1434-1948-

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