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Article: A bis(pyridyl)allenylidene complex of ruthenium: A "molecular clip" that displays intense near-infrared absorption upon coordination to a ruthenium(II) center

TitleA bis(pyridyl)allenylidene complex of ruthenium: A "molecular clip" that displays intense near-infrared absorption upon coordination to a ruthenium(II) center
Authors
KeywordsCyclic voltammetry
Density functional calculations
pi interactions
Ruthenium
UV/Vis spectroscopy
Issue Date2006
PublisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home
Citation
Angewandte Chemie - International Edition, 2006, v. 45 n. 17, p. 2694-2698 How to Cite?
AbstractMaking the band: A bis(pyridyl)allenylidene-ruthenium complex acts as a metalloligand for the binding of metal ions. The dinuclear complex [(16-TMC)ClRu=C=C=C(2-py)2Ru(acac)2]+ (16-TMC = 1,5,9,13-tetramethyl-1,5,9,13-tetraazacyclohexadecane) features an intense low-energy metal-to-ligand charge transfer in an excited state delocalized over both Ru ions and the allenylidene bridge (see plot of the LUMO). (Figure Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
Persistent Identifierhttp://hdl.handle.net/10722/69561
ISSN
2015 Impact Factor: 11.709
2015 SCImago Journal Rankings: 6.229
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorWong, CYen_HK
dc.contributor.authorTong, GSMen_HK
dc.contributor.authorChe, CMen_HK
dc.contributor.authorZhu, Nen_HK
dc.date.accessioned2010-09-06T06:14:48Z-
dc.date.available2010-09-06T06:14:48Z-
dc.date.issued2006en_HK
dc.identifier.citationAngewandte Chemie - International Edition, 2006, v. 45 n. 17, p. 2694-2698en_HK
dc.identifier.issn1433-7851en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69561-
dc.description.abstractMaking the band: A bis(pyridyl)allenylidene-ruthenium complex acts as a metalloligand for the binding of metal ions. The dinuclear complex [(16-TMC)ClRu=C=C=C(2-py)2Ru(acac)2]+ (16-TMC = 1,5,9,13-tetramethyl-1,5,9,13-tetraazacyclohexadecane) features an intense low-energy metal-to-ligand charge transfer in an excited state delocalized over both Ru ions and the allenylidene bridge (see plot of the LUMO). (Figure Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.en_HK
dc.languageengen_HK
dc.publisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/homeen_HK
dc.relation.ispartofAngewandte Chemie - International Editionen_HK
dc.subjectCyclic voltammetryen_HK
dc.subjectDensity functional calculationsen_HK
dc.subjectpi interactionsen_HK
dc.subjectRutheniumen_HK
dc.subjectUV/Vis spectroscopyen_HK
dc.titleA bis(pyridyl)allenylidene complex of ruthenium: A "molecular clip" that displays intense near-infrared absorption upon coordination to a ruthenium(II) centeren_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1433-7851&volume=45&spage=2694&epage=2698&date=2006&atitle=A+Bis(Pyridyl)+Allenylidene+Complex+of+Ruthenium:+A+%27Molecular+Clip%27+That+Displays+Intense+Near-Infrared+Absorption+Upon+Coordination+to+a+Ruthenium(II)+Centeren_HK
dc.identifier.emailTong, GSM: tongsm@hku.hken_HK
dc.identifier.emailChe, CM: cmche@hku.hken_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.authorityTong, GSM=rp00790en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.200600139en_HK
dc.identifier.pmid16586520-
dc.identifier.scopuseid_2-s2.0-33746211345en_HK
dc.identifier.hkuros133108en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-33746211345&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume45en_HK
dc.identifier.issue17en_HK
dc.identifier.spage2694en_HK
dc.identifier.epage2698en_HK
dc.identifier.isiWOS:000237155200004-
dc.publisher.placeGermanyen_HK
dc.identifier.scopusauthoridWong, CY=7404954160en_HK
dc.identifier.scopusauthoridTong, GSM=7102328656en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK

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