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- Publisher Website: 10.1002/anie.200600139
- Scopus: eid_2-s2.0-33746211345
- PMID: 16586520
- WOS: WOS:000237155200004
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Article: A bis(pyridyl)allenylidene complex of ruthenium: A "molecular clip" that displays intense near-infrared absorption upon coordination to a ruthenium(II) center
Title | A bis(pyridyl)allenylidene complex of ruthenium: A "molecular clip" that displays intense near-infrared absorption upon coordination to a ruthenium(II) center |
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Authors | |
Keywords | Cyclic voltammetry Density functional calculations pi interactions Ruthenium UV/Vis spectroscopy |
Issue Date | 2006 |
Publisher | Wiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home |
Citation | Angewandte Chemie - International Edition, 2006, v. 45 n. 17, p. 2694-2698 How to Cite? |
Abstract | Making the band: A bis(pyridyl)allenylidene-ruthenium complex acts as a metalloligand for the binding of metal ions. The dinuclear complex [(16-TMC)ClRu=C=C=C(2-py)2Ru(acac)2]+ (16-TMC = 1,5,9,13-tetramethyl-1,5,9,13-tetraazacyclohexadecane) features an intense low-energy metal-to-ligand charge transfer in an excited state delocalized over both Ru ions and the allenylidene bridge (see plot of the LUMO). (Figure Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA. |
Persistent Identifier | http://hdl.handle.net/10722/69561 |
ISSN | 2023 Impact Factor: 16.1 2023 SCImago Journal Rankings: 5.300 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Wong, CY | en_HK |
dc.contributor.author | Tong, GSM | en_HK |
dc.contributor.author | Che, CM | en_HK |
dc.contributor.author | Zhu, N | en_HK |
dc.date.accessioned | 2010-09-06T06:14:48Z | - |
dc.date.available | 2010-09-06T06:14:48Z | - |
dc.date.issued | 2006 | en_HK |
dc.identifier.citation | Angewandte Chemie - International Edition, 2006, v. 45 n. 17, p. 2694-2698 | en_HK |
dc.identifier.issn | 1433-7851 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/69561 | - |
dc.description.abstract | Making the band: A bis(pyridyl)allenylidene-ruthenium complex acts as a metalloligand for the binding of metal ions. The dinuclear complex [(16-TMC)ClRu=C=C=C(2-py)2Ru(acac)2]+ (16-TMC = 1,5,9,13-tetramethyl-1,5,9,13-tetraazacyclohexadecane) features an intense low-energy metal-to-ligand charge transfer in an excited state delocalized over both Ru ions and the allenylidene bridge (see plot of the LUMO). (Figure Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA. | en_HK |
dc.language | eng | en_HK |
dc.publisher | Wiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home | en_HK |
dc.relation.ispartof | Angewandte Chemie - International Edition | en_HK |
dc.subject | Cyclic voltammetry | en_HK |
dc.subject | Density functional calculations | en_HK |
dc.subject | pi interactions | en_HK |
dc.subject | Ruthenium | en_HK |
dc.subject | UV/Vis spectroscopy | en_HK |
dc.title | A bis(pyridyl)allenylidene complex of ruthenium: A "molecular clip" that displays intense near-infrared absorption upon coordination to a ruthenium(II) center | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1433-7851&volume=45&spage=2694&epage=2698&date=2006&atitle=A+Bis(Pyridyl)+Allenylidene+Complex+of+Ruthenium:+A+%27Molecular+Clip%27+That+Displays+Intense+Near-Infrared+Absorption+Upon+Coordination+to+a+Ruthenium(II)+Center | en_HK |
dc.identifier.email | Tong, GSM: tongsm@hku.hk | en_HK |
dc.identifier.email | Che, CM: cmche@hku.hk | en_HK |
dc.identifier.email | Zhu, N: nzhu@hkucc.hku.hk | en_HK |
dc.identifier.authority | Tong, GSM=rp00790 | en_HK |
dc.identifier.authority | Che, CM=rp00670 | en_HK |
dc.identifier.authority | Zhu, N=rp00845 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1002/anie.200600139 | en_HK |
dc.identifier.pmid | 16586520 | - |
dc.identifier.scopus | eid_2-s2.0-33746211345 | en_HK |
dc.identifier.hkuros | 133108 | en_HK |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-33746211345&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 45 | en_HK |
dc.identifier.issue | 17 | en_HK |
dc.identifier.spage | 2694 | en_HK |
dc.identifier.epage | 2698 | en_HK |
dc.identifier.isi | WOS:000237155200004 | - |
dc.publisher.place | Germany | en_HK |
dc.identifier.scopusauthorid | Wong, CY=7404954160 | en_HK |
dc.identifier.scopusauthorid | Tong, GSM=7102328656 | en_HK |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_HK |
dc.identifier.scopusauthorid | Zhu, N=7201449530 | en_HK |
dc.identifier.issnl | 1433-7851 | - |