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Article: Direct observation of the 4-methoxyphenylnitrene intersystem crossing from S1 to T1 using picosecond kerr-gated time-resolved resonance Raman spectroscopy

TitleDirect observation of the 4-methoxyphenylnitrene intersystem crossing from S1 to T1 using picosecond kerr-gated time-resolved resonance Raman spectroscopy
Authors
Issue Date2005
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/jpca
Citation
Journal Of Physical Chemistry A, 2005, v. 109 n. 10, p. 2394-2400 How to Cite?
AbstractA picosecond Kerr-gated time-resolved resonance Raman (ps-KTR3) study of the singlet 4-methoxyphenyl-nitrene intersystem crossing to produce the triplet 4-methoxyphenylnitrene species is reported. The experimental resonance Raman vibrational band frequencies observed for the singlet and triplet 4-methoxylphenylnitrene species in the time-resolved Raman experiments are compared to each other and to predictions from previously published density functional theory calculations. The structure, properties, and chemical reactivity of the singlet and triplet states of the 4-methoxyphenylnitrenes are briefly discussed. © 2005 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/69551
ISSN
2015 Impact Factor: 2.883
2015 SCImago Journal Rankings: 1.231
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorKwok, WMen_HK
dc.contributor.authorChan, PYen_HK
dc.contributor.authorPhillips, DLen_HK
dc.date.accessioned2010-09-06T06:14:42Z-
dc.date.available2010-09-06T06:14:42Z-
dc.date.issued2005en_HK
dc.identifier.citationJournal Of Physical Chemistry A, 2005, v. 109 n. 10, p. 2394-2400en_HK
dc.identifier.issn1089-5639en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69551-
dc.description.abstractA picosecond Kerr-gated time-resolved resonance Raman (ps-KTR3) study of the singlet 4-methoxyphenyl-nitrene intersystem crossing to produce the triplet 4-methoxyphenylnitrene species is reported. The experimental resonance Raman vibrational band frequencies observed for the singlet and triplet 4-methoxylphenylnitrene species in the time-resolved Raman experiments are compared to each other and to predictions from previously published density functional theory calculations. The structure, properties, and chemical reactivity of the singlet and triplet states of the 4-methoxyphenylnitrenes are briefly discussed. © 2005 American Chemical Society.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/jpcaen_HK
dc.relation.ispartofJournal of Physical Chemistry Aen_HK
dc.titleDirect observation of the 4-methoxyphenylnitrene intersystem crossing from S1 to T1 using picosecond kerr-gated time-resolved resonance Raman spectroscopyen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1089-5639&volume=109&issue=10&spage=2394&epage=2400&date=2005&atitle=Direct+observation+of+the+4-Methoxyphenylnitrene+intersystem+crossing+from+S1+to+T1+using+picosecond+Kerr-gated+time-resolved+resonance+Raman+spectroscopyen_HK
dc.identifier.emailPhillips, DL:phillips@hku.hken_HK
dc.identifier.authorityPhillips, DL=rp00770en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/jp044670ten_HK
dc.identifier.pmid16839010-
dc.identifier.scopuseid_2-s2.0-15944387667en_HK
dc.identifier.hkuros99139en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-15944387667&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume109en_HK
dc.identifier.issue10en_HK
dc.identifier.spage2394en_HK
dc.identifier.epage2400en_HK
dc.identifier.isiWOS:000227630200040-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridKwok, WM=7103129332en_HK
dc.identifier.scopusauthoridChan, PY=7403497922en_HK
dc.identifier.scopusauthoridPhillips, DL=7404519365en_HK

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