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Article: Syntheses, crystal structures, and luminescent properties of three novel zinc coordination polymers with tetrazolyl ligands

TitleSyntheses, crystal structures, and luminescent properties of three novel zinc coordination polymers with tetrazolyl ligands
Authors
Issue Date2005
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 2005, v. 44 n. 15, p. 5278-5285 How to Cite?
AbstractThe syntheses and luminescent properties of three novel zinc coordination polymers containing tetrazolyl ligands are described. In situ [2+3] cycloaddition reactions of acetonitrile or p-tolylnitrile with sodium azide in the presence of Zn(ClO4)2 as a Lewis acid (Demko-Sharpless tetrazole synthesis method) under hydrothermal (solvothermal) reaction conditions gave [Zn(CH3CN4)2] 3(H2O) (1) and [Zn(4-MPTZ)2] (3) [4-MPTZ = 5-(4-methylphenyl)tetrazole], respectively. On the other hand, [Zn(HCN 4)2] (2) was obtained by directly reacting tetrazole with Zn(OAc)2 under hydrothermal reaction conditions. The structure of 1 shows a super-diamond-like topological network with a diamond subunit as a connecting node. For 2, a diamond-like topological network is also found, but it is 2-fold interpenetrated. The structure of 3 reveals a 2D layered network with a hexagonal net, with the adjacent layers in the network stacked in an ABAB sequence. Photoluminescence studies revealed coordination polymers 1, 2, and 3 exhibit strong blue fluorescent emissions at λmax = 396, 418, and 397 nm, respectively, in the solid state at room temperature. © 2005 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/69549
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorWang, XSen_HK
dc.contributor.authorTang, YZen_HK
dc.contributor.authorHuang, XFen_HK
dc.contributor.authorQu, ZRen_HK
dc.contributor.authorChe, CMen_HK
dc.contributor.authorChan, PWHen_HK
dc.contributor.authorXiong, RGen_HK
dc.date.accessioned2010-09-06T06:14:41Z-
dc.date.available2010-09-06T06:14:41Z-
dc.date.issued2005en_HK
dc.identifier.citationInorganic Chemistry, 2005, v. 44 n. 15, p. 5278-5285en_HK
dc.identifier.issn0020-1669en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69549-
dc.description.abstractThe syntheses and luminescent properties of three novel zinc coordination polymers containing tetrazolyl ligands are described. In situ [2+3] cycloaddition reactions of acetonitrile or p-tolylnitrile with sodium azide in the presence of Zn(ClO4)2 as a Lewis acid (Demko-Sharpless tetrazole synthesis method) under hydrothermal (solvothermal) reaction conditions gave [Zn(CH3CN4)2] 3(H2O) (1) and [Zn(4-MPTZ)2] (3) [4-MPTZ = 5-(4-methylphenyl)tetrazole], respectively. On the other hand, [Zn(HCN 4)2] (2) was obtained by directly reacting tetrazole with Zn(OAc)2 under hydrothermal reaction conditions. The structure of 1 shows a super-diamond-like topological network with a diamond subunit as a connecting node. For 2, a diamond-like topological network is also found, but it is 2-fold interpenetrated. The structure of 3 reveals a 2D layered network with a hexagonal net, with the adjacent layers in the network stacked in an ABAB sequence. Photoluminescence studies revealed coordination polymers 1, 2, and 3 exhibit strong blue fluorescent emissions at λmax = 396, 418, and 397 nm, respectively, in the solid state at room temperature. © 2005 American Chemical Society.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/icen_HK
dc.relation.ispartofInorganic Chemistryen_HK
dc.titleSyntheses, crystal structures, and luminescent properties of three novel zinc coordination polymers with tetrazolyl ligandsen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0020-1669&volume=44&spage=5278&epage=5285&date=2005&atitle=Syntheses,+crystal+structures,+and+luminescent+properties+of+three+novel+zinc+coordination+polymers+with+tetrazolyl+ligandsen_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ic050354xen_HK
dc.identifier.pmid16022526-
dc.identifier.scopuseid_2-s2.0-23244461206en_HK
dc.identifier.hkuros117768en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-23244461206&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume44en_HK
dc.identifier.issue15en_HK
dc.identifier.spage5278en_HK
dc.identifier.epage5285en_HK
dc.identifier.isiWOS:000230629900015-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridWang, XS=36026222800en_HK
dc.identifier.scopusauthoridTang, YZ=35590849100en_HK
dc.identifier.scopusauthoridHuang, XF=26021248500en_HK
dc.identifier.scopusauthoridQu, ZR=7202671281en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.scopusauthoridChan, PWH=13607033800en_HK
dc.identifier.scopusauthoridXiong, RG=7102951372en_HK

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