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Article: Forces between charged surfaces in a solvent primitive model electrolyte

TitleForces between charged surfaces in a solvent primitive model electrolyte
Authors
Issue Date2002
PublisherTaylor & Francis Ltd. The Journal's web site is located at http://www.tandf.co.uk/journals/titles/00268976.asp
Citation
Molecular Physics, 2002, v. 100 n. 14, p. 2201-2211 How to Cite?
AbstractGrand canonical Monte Carlo (GCMC) simulations have been performed to investigate the components of the force between parallel charged surfaces in an electrolyte. The solvent primitive model (SPM) was used to investigate the effect of neutral hard sphere solvent particles on the force between the surfaces. The effects of particle size, wall charge density, charge valency of the electrolyte, and the exclusion of neutral hard sphere are discussed. When solvent particles are considered, the total force between the charged surfaces is always repulsive, even for divalent counterions. This is different from the earlier conclusion reached with a restricted primitive model electrolyte. The repulsive force decreases in going from monovalent counterions to divalent counterions.
Persistent Identifierhttp://hdl.handle.net/10722/69541
ISSN
2015 Impact Factor: 1.837
2015 SCImago Journal Rankings: 0.781
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLee, Men_HK
dc.contributor.authorChan, KYen_HK
dc.contributor.authorTang, YWen_HK
dc.date.accessioned2010-09-06T06:14:37Z-
dc.date.available2010-09-06T06:14:37Z-
dc.date.issued2002en_HK
dc.identifier.citationMolecular Physics, 2002, v. 100 n. 14, p. 2201-2211en_HK
dc.identifier.issn0026-8976en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69541-
dc.description.abstractGrand canonical Monte Carlo (GCMC) simulations have been performed to investigate the components of the force between parallel charged surfaces in an electrolyte. The solvent primitive model (SPM) was used to investigate the effect of neutral hard sphere solvent particles on the force between the surfaces. The effects of particle size, wall charge density, charge valency of the electrolyte, and the exclusion of neutral hard sphere are discussed. When solvent particles are considered, the total force between the charged surfaces is always repulsive, even for divalent counterions. This is different from the earlier conclusion reached with a restricted primitive model electrolyte. The repulsive force decreases in going from monovalent counterions to divalent counterions.en_HK
dc.languageengen_HK
dc.publisherTaylor & Francis Ltd. The Journal's web site is located at http://www.tandf.co.uk/journals/titles/00268976.aspen_HK
dc.relation.ispartofMolecular Physicsen_HK
dc.titleForces between charged surfaces in a solvent primitive model electrolyteen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0026-8976&volume=100&issue=14&spage=2201&epage=2211&date=2002&atitle=Forces+between+charged+surfaces+in+a+solvent+primitive+model+electrolyteen_HK
dc.identifier.emailChan, KY:hrsccky@hku.hken_HK
dc.identifier.authorityChan, KY=rp00662en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1080/00268970210125322en_HK
dc.identifier.scopuseid_2-s2.0-0037143361en_HK
dc.identifier.hkuros76755en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0037143361&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume100en_HK
dc.identifier.issue14en_HK
dc.identifier.spage2201en_HK
dc.identifier.epage2211en_HK
dc.identifier.isiWOS:000177172800003-
dc.publisher.placeUnited Kingdomen_HK
dc.identifier.scopusauthoridLee, M=26661734100en_HK
dc.identifier.scopusauthoridChan, KY=7406034142en_HK
dc.identifier.scopusauthoridTang, YW=7404591157en_HK

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