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Article: Synthesis, X-ray crystal structure and magnetic properties of a new binuclear complex derived from a pentadentate Schiff base ligand

TitleSynthesis, X-ray crystal structure and magnetic properties of a new binuclear complex derived from a pentadentate Schiff base ligand
Authors
Issue Date2003
PublisherNISCAIR. The Journal's web site is located at http://www.niscair.res.in/sciencecommunication/researchjournals/rejour/ijca/ijca0.asp
Citation
Indian Journal Of Chemistry - Section A Inorganic, Physical, Theoretical And Analytical Chemistry, 2003, v. 42 n. 5, p. 1004-1007 How to Cite?
AbstractA new binuclear nickel(II) complex [Ni2L2(N3)2](ClO4)2 1 has been synthesized and characterized. The structure of 1 has been determined by single crystal X-ray diffraction studies. The structure analysis indicates that each nickel(II) centre is in a distorted octahedral (NiN6) coordination environment with three nitrogen atoms from one and two nitrogen atoms from other pentadentate ligand and the last one from terminal azido ion. Variable-temperature magnetic susceptibility measurements of the compound 1 showed no evidence of magnetic exchange between two nickel(II) centres. This is consistent with the structure with large Ni...Ni distance (5.865(1) Å) and absence of any suitable bridging ligand capable of transmitting this type of interactions.
Persistent Identifierhttp://hdl.handle.net/10722/69494
ISSN
2015 Impact Factor: 0.729
2015 SCImago Journal Rankings: 0.278
References

 

DC FieldValueLanguage
dc.contributor.authorDeoghoria, Sen_HK
dc.contributor.authorWong, WTen_HK
dc.contributor.authorChandra, SKen_HK
dc.date.accessioned2010-09-06T06:14:10Z-
dc.date.available2010-09-06T06:14:10Z-
dc.date.issued2003en_HK
dc.identifier.citationIndian Journal Of Chemistry - Section A Inorganic, Physical, Theoretical And Analytical Chemistry, 2003, v. 42 n. 5, p. 1004-1007en_HK
dc.identifier.issn0376-4710en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69494-
dc.description.abstractA new binuclear nickel(II) complex [Ni2L2(N3)2](ClO4)2 1 has been synthesized and characterized. The structure of 1 has been determined by single crystal X-ray diffraction studies. The structure analysis indicates that each nickel(II) centre is in a distorted octahedral (NiN6) coordination environment with three nitrogen atoms from one and two nitrogen atoms from other pentadentate ligand and the last one from terminal azido ion. Variable-temperature magnetic susceptibility measurements of the compound 1 showed no evidence of magnetic exchange between two nickel(II) centres. This is consistent with the structure with large Ni...Ni distance (5.865(1) Å) and absence of any suitable bridging ligand capable of transmitting this type of interactions.en_HK
dc.languageengen_HK
dc.publisherNISCAIR. The Journal's web site is located at http://www.niscair.res.in/sciencecommunication/researchjournals/rejour/ijca/ijca0.aspen_HK
dc.relation.ispartofIndian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistryen_HK
dc.rightsCreative Commons: Attribution 3.0 Hong Kong License-
dc.titleSynthesis, X-ray crystal structure and magnetic properties of a new binuclear complex derived from a pentadentate Schiff base liganden_HK
dc.typeArticleen_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturepublished_or_final_version-
dc.identifier.scopuseid_2-s2.0-0038110715en_HK
dc.identifier.hkuros82661en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0038110715&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume42en_HK
dc.identifier.issue5en_HK
dc.identifier.spage1004en_HK
dc.identifier.epage1007en_HK
dc.publisher.placeIndiaen_HK
dc.identifier.scopusauthoridDeoghoria, S=6506275529en_HK
dc.identifier.scopusauthoridWong, WT=7403973084en_HK
dc.identifier.scopusauthoridChandra, SK=7401671646en_HK

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