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Article: Synthesis, optical and photoconducting properties of platinum poly-yne polymers functionalized with electron-donating and electron-withdrawing bithiazole units

TitleSynthesis, optical and photoconducting properties of platinum poly-yne polymers functionalized with electron-donating and electron-withdrawing bithiazole units
Authors
Issue Date2000
PublisherWiley - V C H Verlag GmbH & Co KGaA.
Citation
Macromolecular Rapid Communications, 2000, v. 21 n. 8, p. 453-457 How to Cite?
AbstractCommunication: By virtue of the electron-donating and electron-withdrawing properties of the thiazole ring, a new soluble rigid-rod organometallic polymer containing electron-donating and electron-withdrawing trans-[-Pt-(PBu 3) 2-C≡C-R-C≡C-] n (R = bithiazolediyl) groups is prepared by CuI-catalyzed dehydrohalogenation. The thermal properties and the optical absorption and photoluminescence spectra of the polymer are reported. The polymer is luminescent with a singlet emission peak at 539 nm and photoconducting in a single-layer sandwich structure photocell. The optical gap of the polymer is reduced compared to that for the oligothienyl analogue. © Wiley-VCH Verlag GmbH, 2000.
Persistent Identifierhttp://hdl.handle.net/10722/69469
ISSN
2023 Impact Factor: 4.2
2023 SCImago Journal Rankings: 1.056
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorWong, WYen_HK
dc.contributor.authorChan, SMen_HK
dc.contributor.authorChoi, KHen_HK
dc.contributor.authorCheah, KWen_HK
dc.contributor.authorChan, WKen_HK
dc.date.accessioned2010-09-06T06:13:56Z-
dc.date.available2010-09-06T06:13:56Z-
dc.date.issued2000en_HK
dc.identifier.citationMacromolecular Rapid Communications, 2000, v. 21 n. 8, p. 453-457en_HK
dc.identifier.issn1022-1336en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69469-
dc.description.abstractCommunication: By virtue of the electron-donating and electron-withdrawing properties of the thiazole ring, a new soluble rigid-rod organometallic polymer containing electron-donating and electron-withdrawing trans-[-Pt-(PBu 3) 2-C≡C-R-C≡C-] n (R = bithiazolediyl) groups is prepared by CuI-catalyzed dehydrohalogenation. The thermal properties and the optical absorption and photoluminescence spectra of the polymer are reported. The polymer is luminescent with a singlet emission peak at 539 nm and photoconducting in a single-layer sandwich structure photocell. The optical gap of the polymer is reduced compared to that for the oligothienyl analogue. © Wiley-VCH Verlag GmbH, 2000.en_HK
dc.languageengen_HK
dc.publisherWiley - V C H Verlag GmbH & Co KGaA.en_HK
dc.relation.ispartofMacromolecular Rapid Communicationsen_HK
dc.titleSynthesis, optical and photoconducting properties of platinum poly-yne polymers functionalized with electron-donating and electron-withdrawing bithiazole unitsen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1022-1336&volume=21&spage=453&epage=457&date=2000&atitle=Synthesis,+optical+and+photoconducting+properties+of+platinum+poly-yne+polymers+functionalized+with+electron-donating+and+electron-withdrawing+bithiazole+unitsen_HK
dc.identifier.emailChan, WK:waichan@hku.hken_HK
dc.identifier.authorityChan, WK=rp00667en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/(SICI)1521-3927(20000501)21:8<453::AID-MARC453>3.0.CO;2-7-
dc.identifier.scopuseid_2-s2.0-23044517625en_HK
dc.identifier.hkuros49871en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-23044517625&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume21en_HK
dc.identifier.issue8en_HK
dc.identifier.spage453en_HK
dc.identifier.epage457en_HK
dc.identifier.isiWOS:000087658700004-
dc.publisher.placeGermanyen_HK
dc.identifier.scopusauthoridWong, WY=7403972153en_HK
dc.identifier.scopusauthoridChan, SM=26661155100en_HK
dc.identifier.scopusauthoridChoi, KH=7403950094en_HK
dc.identifier.scopusauthoridCheah, KW=7102792922en_HK
dc.identifier.scopusauthoridChan, WK=13310083000en_HK
dc.identifier.issnl1022-1336-

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